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A novel system of biomass-based hydrogen production by combining steam bio-oil reforming and chemical looping process

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  • Situmorang, Yohanes Andre
  • Zhao, Zhongkai
  • An, Ping
  • Yu, Tao
  • Rizkiana, Jenny
  • Abudula, Abuliti
  • Guan, Guoqing

Abstract

Biomass to hydrogen is becoming a promising way to produce clean energy with zero or even negative carbon emission. In this study, a novel system containing a biomass pyrolysis process, a catalytic steam reforming of bio-oil process, a chemical looping unit using biochar as the reducing agent and other auxiliary processes including H2 separation and thermal energy circulation processes for hydrogen production is proposed and simulated based on the previous studies. While, a waste heat recovery system is recommended for energy recuperation to make the entire system become auto-thermal. The effects of steam to carbon ratio in the catalytic steam reforming reaction and temperatures at reducing and steam reactors in the chemical looping unit on the system performance are analyzed in details. Under the optimum condition in the proposed system, about 6.9 kg/h of hydrogen could be produced from 100 kg/h of wood biomass with 58.3 kW of net power. Compared with the biomass direct chemical looping process for H2 production, separating the bio-oil and biochar after the pyrolysis process and combining the steam bio-oil reforming process with the chemical looping unit using biochar for H2 production can increase H2 production efficiency from biomass by more than 50%. It is expected that this proposed system could be implemented in a practical application.

Suggested Citation

  • Situmorang, Yohanes Andre & Zhao, Zhongkai & An, Ping & Yu, Tao & Rizkiana, Jenny & Abudula, Abuliti & Guan, Guoqing, 2020. "A novel system of biomass-based hydrogen production by combining steam bio-oil reforming and chemical looping process," Applied Energy, Elsevier, vol. 268(C).
    • Handle: RePEc:eee:appene:v:268:y:2020:i:c:s0306261920306346
    DOI: 10.1016/j.apenergy.2020.115122
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    Cited by:

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    2. Su, Hongcai & Yan, Mi & Wang, Shurong, 2022. "Recent advances in supercritical water gasification of biowaste catalyzed by transition metal-based catalysts for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    3. Zheng Lian & Yixiao Wang & Xiyue Zhang & Abubakar Yusuf & Lord Famiyeh & David Murindababisha & Huan Jin & Yiyang Liu & Jun He & Yunshan Wang & Gang Yang & Yong Sun, 2021. "Hydrogen Production by Fluidized Bed Reactors: A Quantitative Perspective Using the Supervised Machine Learning Approach," J, MDPI, vol. 4(3), pages 1-22, July.
    4. Teresa Mendiara & Alberto Navajas & Alberto Abad & Tobias Pröll & Mikel Munárriz & Luis M. Gandía & Francisco García-Labiano & Luis F. de Diego, 2024. "Life Cycle Assessment of Wheat Straw Pyrolysis with Volatile Fractions Chemical Looping Combustion," Sustainability, MDPI, vol. 16(10), pages 1-14, May.
    5. Liu, Li & Jiang, Peng & Qian, Hongliang & Mu, Liwen & Lu, Xiaohua & Zhu, Jiahua, 2022. "CO2-negative biomass conversion: An economic route with co-production of green hydrogen and highly porous carbon," Applied Energy, Elsevier, vol. 311(C).
    6. Li, Xianglin & Jiang, Yuchen & Zhang, Lijun & Li, Qingyin & Zhang, Shu & Wang, Yi & Hu, Xun, 2023. "Pyrolysis-reforming of cellulose to simultaneously produce hydrogen and heavy organics," Energy, Elsevier, vol. 265(C).

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