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More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid

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  • Li, Yan
  • Shi, Yan
  • Mehio, Nada
  • Tan, Mingsheng
  • Wang, Zhiyong
  • Hu, Xiaohong
  • Chen, George Z.
  • Dai, Sheng
  • Jin, Xianbo

Abstract

A new hybrid proton exchange membrane (PEM) has been prepared from hydroxyl functionalized imidazolium ionic liquid (IL-OH), Nafion and nano-SiO2. The IL-OH, with a hydroxyl group that acts as both a proton acceptor and donor, forms strong hydrogen bonds with both Nafion and nano-SiO2, resulting in an effective hydrogen bond network in the ternary membrane. Such an anhydrous hydrogen-bond network, which is unknown previously, endows the PEMs with higher proton conductivity, greater thermal stability and surprisingly a more robust mechanical performance than PEMs consisting of conventional ionic liquids. The resulting PEMs have a tensile strength that is more than twice as strong as recast Nafion and an anhydrous ionic conductivity of ∼55mScm−1 at temperatures above 160°C, with a proton transfer number of ∼0.9. A laboratory assembled H2–O2 fuel cell employing this new PEM delivered a power density of 340 and 420mWcm−2 at 160 and 180°C, respectively.

Suggested Citation

  • Li, Yan & Shi, Yan & Mehio, Nada & Tan, Mingsheng & Wang, Zhiyong & Hu, Xiaohong & Chen, George Z. & Dai, Sheng & Jin, Xianbo, 2016. "More sustainable electricity generation in hot and dry fuel cells with a novel hybrid membrane of Nafion/nano-silica/hydroxyl ionic liquid," Applied Energy, Elsevier, vol. 175(C), pages 451-458.
    • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:451-458
    DOI: 10.1016/j.apenergy.2016.03.075
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    References listed on IDEAS

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