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Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions

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  • Thomas, Sobi
  • Vang, Jakob Rabjerg
  • Araya, Samuel Simon
  • Kær, Søren Knudsen

Abstract

The objective of this paper is to separate out the effects of methanol and water vapour on a high temperature polymer electrolyte membrane fuel cell under different temperatures (160°C and 180°C) and current densities (0.2Acm−2, 0.4Acm−2 and 0.6Acm−2). The degradation rates at the different current densities and temperatures are analysed and discussed. The results are supported by IV curves and impedance spectroscopy. The individual resistance variations are extracted by equivalent circuit model fitting of the impedance spectra. The presence of water in the anode feed enhances the performance while the presence of 5% methanol tends to degrade the cell performance. However, the presence of H2O mitigates some of the adverse effects of methanol. The effect of varying fuel compositions was found to be more prominent at lower current densities. The voltage improves significantly when adding water vapour to the anode after pure hydrogen operation at 180°C. A decrease in the total resistance corresponding to the voltage improvement is observed from the impedance spectra. There is minimal variation in performance with the introduction of 3% and 5% methanol along with water vapour in the anode feed at all current densities and operating temperatures. The overall degradation over a period of 1915h is −44μVh−1. The test time includes 595h of test with pure H2 and 300h test each with 15% H2O, 3% CH3OH+15% H2O and 5% CH3OH+15% H2O at varying current densities and temperatures.

Suggested Citation

  • Thomas, Sobi & Vang, Jakob Rabjerg & Araya, Samuel Simon & Kær, Søren Knudsen, 2017. "Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions," Applied Energy, Elsevier, vol. 192(C), pages 422-436.
    • Handle: RePEc:eee:appene:v:192:y:2017:i:c:p:422-436
    DOI: 10.1016/j.apenergy.2016.11.063
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    References listed on IDEAS

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    Cited by:

    1. Xu, Jiawei & Wu, Yuhua & Xiao, Shengying & Wang, Yifei & Xu, Xinhai, 2023. "Synergic effect investigation of carbon monoxide and other compositions on the high temperature proton exchange membrane fuel cell," Renewable Energy, Elsevier, vol. 211(C), pages 669-680.
    2. Li, Na & Cui, Xiaoti & Zhu, Jimin & Zhou, Mengfan & Liso, Vincenzo & Cinti, Giovanni & Sahlin, Simon Lennart & Araya, Samuel Simon, 2023. "A review of reformed methanol-high temperature proton exchange membrane fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    3. Akira Nishimura & Tatsuya Okado & Yuya Kojima & Masafumi Hirota & Eric Hu, 2020. "Impact of MPL on Temperature Distribution in Single Polymer Electrolyte Fuel Cell with Various Thicknesses of Polymer Electrolyte Membrane," Energies, MDPI, vol. 13(10), pages 1-17, May.
    4. Giovanni Cinti & Vincenzo Liso & Simon Lennart Sahlin & Samuel Simon Araya, 2020. "System Design and Modeling of a High Temperature PEM Fuel Cell Operated with Ammonia as a Fuel," Energies, MDPI, vol. 13(18), pages 1-17, September.
    5. Hu, Zunyan & Xu, Liangfei & Huang, Yiyuan & Li, Jianqiu & Ouyang, Minggao & Du, Xiaoli & Jiang, Hongliang, 2018. "Comprehensive analysis of galvanostatic charge method for fuel cell degradation diagnosis," Applied Energy, Elsevier, vol. 212(C), pages 1321-1332.
    6. Nishimura, Akira & Yamamoto, Kohei & Okado, Tatsuya & Kojima, Yuya & Hirota, Masafumi & Kolhe, Mohan Lal, 2020. "Impact analysis of MPL and PEM thickness on temperature distribution within PEFC operating at relatively higher temperature," Energy, Elsevier, vol. 205(C).

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