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SOFC stack coupled with dry reforming

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  • Barelli, L.
  • Bidini, G.
  • Cinti, G.
  • Gallorini, F.
  • Pöniz, M.

Abstract

The study proposes an innovative CHP system based on the coupling of carbon dioxide dry reforming (CDR) and solid oxide fuel cell (SOFC) technology. To supply CO2 at the CDR unit, increasing at the same time the overall utilization factor, SOFC anode off-gases are recycled for fuel reforming. In the CDR unit, in fact, the CO2 in the anodic exhausts reacts with feeding low carbon fuels (in this case natural gas) producing hydrogen and carbon monoxide for the SOFC feeding, thus allowing an internal CO2 reuse. In particular, the SOFC, characterized by high operating temperatures and significant recoverable heat, guarantees suitable temperature of the CDR process, highly endothermic. Moreover, compared to traditional CDR applications, lower temperatures are acceptable because SOFC tolerates feeding gas containing limited amounts of CO and CH4. According to this concept, the SOFC stack can be conveniently fed by a dry reformer reactor. The present study addresses the experimental characterization of SOFC short-stacks performance, in terms of produced power and thermal behavior, when fed by different fuel mixtures produced through dry reforming.

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  • Barelli, L. & Bidini, G. & Cinti, G. & Gallorini, F. & Pöniz, M., 2017. "SOFC stack coupled with dry reforming," Applied Energy, Elsevier, vol. 192(C), pages 498-507.
    • Handle: RePEc:eee:appene:v:192:y:2017:i:c:p:498-507
    DOI: 10.1016/j.apenergy.2016.08.167
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    5. Diglio, Giuseppe & Bareschino, Piero & Mancusi, Erasmo & Pepe, Francesco & Montagnaro, Fabio & Hanak, Dawid P. & Manovic, Vasilije, 2018. "Feasibility of CaO/CuO/NiO sorption-enhanced steam methane reforming integrated with solid-oxide fuel cell for near-zero-CO2 emissions cogeneration system," Applied Energy, Elsevier, vol. 230(C), pages 241-256.
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    7. Cinti, G. & Bidini, G. & Hemmes, K., 2019. "Comparison of the solid oxide fuel cell system for micro CHP using natural gas with a system using a mixture of natural gas and hydrogen," Applied Energy, Elsevier, vol. 238(C), pages 69-77.
    8. Diglio, Giuseppe & Hanak, Dawid P. & Bareschino, Piero & Pepe, Francesco & Montagnaro, Fabio & Manovic, Vasilije, 2018. "Modelling of sorption-enhanced steam methane reforming in a fixed bed reactor network integrated with fuel cell," Applied Energy, Elsevier, vol. 210(C), pages 1-15.
    9. Liao, Mingzheng & Chen, Ying & Cheng, Zhengdong & Wang, Chao & Luo, Xianglong & Bu, Enqi & Jiang, Zhiqiang & Liang, Bo & Shu, Riyang & Song, Qingbin, 2019. "Hydrogen production from partial oxidation of propane: Effect of SiC addition on Ni/Al2O3 catalyst," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    10. Subotić, Vanja & Menzler, Norbert H. & Lawlor, Vincent & Fang, Qingping & Pofahl, Stefan & Harter, Philipp & Schroettner, Hartmuth & Hochenauer, Christoph, 2020. "On the origin of degradation in fuel cells and its fast identification by applying unconventional online-monitoring tools," Applied Energy, Elsevier, vol. 277(C).
    11. Luca Del Zotto & Andrea Monforti Ferrario & Arda Hatunoglu & Alessandro Dell’Era & Stephen McPhail & Enrico Bocci, 2021. "Experimental Procedures & First Results of an Innovative Solid Oxide Fuel Cell Test Rig: Parametric Analysis and Stability Test," Energies, MDPI, vol. 14(8), pages 1-19, April.
    12. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    13. Rashid, Kashif & Dong, Sang Keun & Mehran, Muhammad Taqi & Lee, Dong Won, 2017. "Design and analysis of compact hotbox for solid oxide fuel cell based 1kW-class power generation system," Applied Energy, Elsevier, vol. 208(C), pages 620-636.
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