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Comparison of off-gas utilization modes for solid oxide fuel cell stacks based on a semi-empirical parametric model

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  • Lyu, Zewei
  • Meng, Hao
  • Zhu, Jianzhong
  • Han, Minfang
  • Sun, Zaihong
  • Xue, Huaqing
  • Zhao, Yongming
  • Zhang, Fudong

Abstract

Solid oxide fuel cells (SOFCs) provide a clean and efficient pathway to use a variety of carbon containing fuels for power generation. Reuse or recycle of the high-temperature off-gas can help to improve the fuel or air utilization of SOFC stacks, as well as to improve system efficiency and reduce operating costs. The off-gas utilization mode and its effect on the stack performance need to be further clarified. In this study, a novel semi-empirical parametric stack model was established based on the experimental data of a 3-cell SOFC stack. This parametric model can accurately predict the output performance of real stacks, which was verified by multi-condition experiments. Based on this stack model, one basic process and four off-gas utilization modes were designed and constructed. Comparative analysis of these modes under different operation parameters was carried out. The effects of key operation parameters, including fuel flow rate, operating current, stack temperature, pre-reformer temperature, split ratio and recycle ratio on the stack performance were studied, which were characterized by the electrical efficiency and exergy efficiency of the power module. It was found that the mode with two-stage stacks can get the maximum electrical efficiency (>45%) with the operating current less than 20 A, while the mode with anode off-gas recycled to the pre-reformer instead obtained the maximum electrical efficiency (>35%) when the specified current was larger than 25 A. A comprehensive and in-depth perspective on different stack off-gas utilization modes is provided, which can supply feasible guidance for the next-step overall system design. Besides, the stack modeling and process simulation method developed in this study can provide reference for related research.

Suggested Citation

  • Lyu, Zewei & Meng, Hao & Zhu, Jianzhong & Han, Minfang & Sun, Zaihong & Xue, Huaqing & Zhao, Yongming & Zhang, Fudong, 2020. "Comparison of off-gas utilization modes for solid oxide fuel cell stacks based on a semi-empirical parametric model," Applied Energy, Elsevier, vol. 270(C).
    • Handle: RePEc:eee:appene:v:270:y:2020:i:c:s0306261920307327
    DOI: 10.1016/j.apenergy.2020.115220
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    1. Lyu, Zewei & Shi, Wangying & Han, Minfang, 2018. "Electrochemical characteristics and carbon tolerance of solid oxide fuel cells with direct internal dry reforming of methane," Applied Energy, Elsevier, vol. 228(C), pages 556-567.
    2. Chitsaz, Ata & Hosseinpour, Javad & Assadi, Mohsen, 2017. "Effect of recycling on the thermodynamic and thermoeconomic performances of SOFC based on trigeneration systems; A comparative study," Energy, Elsevier, vol. 124(C), pages 613-624.
    3. Cinti, G. & Bidini, G. & Hemmes, K., 2019. "Comparison of the solid oxide fuel cell system for micro CHP using natural gas with a system using a mixture of natural gas and hydrogen," Applied Energy, Elsevier, vol. 238(C), pages 69-77.
    4. Jia, Junxi & Li, Qiang & Luo, Ming & Wei, Liming & Abudula, Abuliti, 2011. "Effects of gas recycle on performance of solid oxide fuel cell power systems," Energy, Elsevier, vol. 36(2), pages 1068-1075.
    5. Silva-Mosqueda, Dulce María & Elizalde-Blancas, Francisco & Pumiglia, Davide & Santoni, Francesca & Boigues-Muñoz, Carlos & McPhail, Stephen J., 2019. "Intermediate temperature solid oxide fuel cell under internal reforming: Critical operating conditions, associated problems and their impact on the performance," Applied Energy, Elsevier, vol. 235(C), pages 625-640.
    6. Cho, Heejin & Smith, Amanda D. & Mago, Pedro, 2014. "Combined cooling, heating and power: A review of performance improvement and optimization," Applied Energy, Elsevier, vol. 136(C), pages 168-185.
    7. Alanne, Kari & Cao, Sunliang, 2019. "An overview of the concept and technology of ubiquitous energy," Applied Energy, Elsevier, vol. 238(C), pages 284-302.
    8. Lee, Kwang Ho & Strand, Richard K., 2009. "SOFC cogeneration system for building applications, part 1: Development of SOFC system-level model and the parametric study," Renewable Energy, Elsevier, vol. 34(12), pages 2831-2838.
    9. Abdelkareem, Mohammad Ali & Tanveer, Waqas Hassan & Sayed, Enas Taha & Assad, M. El Haj & Allagui, Anis & Cha, S.W., 2019. "On the technical challenges affecting the performance of direct internal reforming biogas solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 361-375.
    10. Calise, F. & Dentice d’Accadia, M. & Palombo, A. & Vanoli, L., 2006. "Simulation and exergy analysis of a hybrid Solid Oxide Fuel Cell (SOFC)–Gas Turbine System," Energy, Elsevier, vol. 31(15), pages 3278-3299.
    11. Chatrattanawet, Narissara & Saebea, Dang & Authayanun, Suthida & Arpornwichanop, Amornchai & Patcharavorachot, Yaneeporn, 2018. "Performance and environmental study of a biogas-fuelled solid oxide fuel cell with different reforming approaches," Energy, Elsevier, vol. 146(C), pages 131-140.
    12. Badur, Janusz & Lemański, Marcin & Kowalczyk, Tomasz & Ziółkowski, Paweł & Kornet, Sebastian, 2018. "Zero-dimensional robust model of an SOFC with internal reforming for hybrid energy cycles," Energy, Elsevier, vol. 158(C), pages 128-138.
    13. Wagner, Patrick Hubert & Wuillemin, Zacharie & Constantin, David & Diethelm, Stefan & Van herle, Jan & Schiffmann, Jürg, 2020. "Experimental characterization of a solid oxide fuel cell coupled to a steam-driven micro anode off-gas recirculation fan," Applied Energy, Elsevier, vol. 262(C).
    14. Barelli, L. & Bidini, G. & Cinti, G. & Gallorini, F. & Pöniz, M., 2017. "SOFC stack coupled with dry reforming," Applied Energy, Elsevier, vol. 192(C), pages 498-507.
    15. Guk, Erdogan & Venkatesan, Vijay & Babar, Shumaila & Jackson, Lisa & Kim, Jung-Sik, 2019. "Parameters and their impacts on the temperature distribution and thermal gradient of solid oxide fuel cell," Applied Energy, Elsevier, vol. 241(C), pages 164-173.
    16. van Biert, L. & Godjevac, M. & Visser, K. & Aravind, P.V., 2019. "Dynamic modelling of a direct internal reforming solid oxide fuel cell stack based on single cell experiments," Applied Energy, Elsevier, vol. 250(C), pages 976-990.
    Full references (including those not matched with items on IDEAS)

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    2. Subotić, Vanja & Menzler, Norbert H. & Lawlor, Vincent & Fang, Qingping & Pofahl, Stefan & Harter, Philipp & Schroettner, Hartmuth & Hochenauer, Christoph, 2020. "On the origin of degradation in fuel cells and its fast identification by applying unconventional online-monitoring tools," Applied Energy, Elsevier, vol. 277(C).
    3. Habibollahzade, Ali & Rosen, Marc A., 2021. "Syngas-fueled solid oxide fuel cell functionality improvement through appropriate feedstock selection and multi-criteria optimization using Air/O2-enriched-air gasification agents," Applied Energy, Elsevier, vol. 286(C).
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    6. Baccioli, Andrea & Liponi, Angelica & Milewski, Jarosław & Szczęśniak, Arkadiusz & Desideri, Umberto, 2021. "Hybridization of an internal combustion engine with a molten carbonate fuel cell for marine applications," Applied Energy, Elsevier, vol. 298(C).
    7. Li, Hui & Eghbalian, Nasrin, 2021. "Numerical studies of effect of integrated through-plane array flow field on novel PEFC performance using BWO algorithm under uncertainties," Energy, Elsevier, vol. 231(C).

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