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Modelling of sorption-enhanced steam methane reforming in a fixed bed reactor network integrated with fuel cell

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  • Diglio, Giuseppe
  • Hanak, Dawid P.
  • Bareschino, Piero
  • Pepe, Francesco
  • Montagnaro, Fabio
  • Manovic, Vasilije

Abstract

In this study sorption-enhanced steam methane reforming (SE-SMR) in fixed beds is investigated by means of 1D numerical modelling, and the model is validated with the data reported in the literature. Isothermal conditions (973 K) are considered, and the equilibrium between the carbonation and calcination stages is shifted by a pressure swing: 3.5 · 106 Pa and 1013 Pa, respectively. The results showed that under these operating conditions at least 8 reactors in parallel are required to continuously produce a high-purity stream of H2, and a separated stream of concentrated CO2. The average H2 purity is 0.92, whilst the average H2 yield and selectivity are 2.9 molH2 molCH4−1 and 90%, respectively. A thermodynamic analysis was performed, which highlighted that, by using a portion of the produced H2 (about 0.4 molH2 molCH4−1), it is possible to fully cover heat and power demands of the process, making it completely energy self-sufficient. In the case when the proposed SE-SMR is integrated with a solid oxide fuel cell, net power generation at the scale of ∼950 kWel can be achieved with a net efficiency of the entire system of 51%, with the important feature that CO2 is concentrated.

Suggested Citation

  • Diglio, Giuseppe & Hanak, Dawid P. & Bareschino, Piero & Pepe, Francesco & Montagnaro, Fabio & Manovic, Vasilije, 2018. "Modelling of sorption-enhanced steam methane reforming in a fixed bed reactor network integrated with fuel cell," Applied Energy, Elsevier, vol. 210(C), pages 1-15.
  • Handle: RePEc:eee:appene:v:210:y:2018:i:c:p:1-15
    DOI: 10.1016/j.apenergy.2017.10.101
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    1. Kavosh, Masoud & Patchigolla, Kumar & Anthony, Edward J. & Oakey, John E., 2014. "Carbonation performance of lime for cyclic CO2 capture following limestone calcination in steam/CO2 atmosphere," Applied Energy, Elsevier, vol. 131(C), pages 499-507.
    2. Coppola, Antonio & Solimene, Roberto & Bareschino, Piero & Salatino, Piero, 2015. "Mathematical modeling of a two-stage fuel reactor for chemical looping combustion with oxygen uncoupling of solid fuels," Applied Energy, Elsevier, vol. 157(C), pages 449-461.
    3. Antzara, Andy & Heracleous, Eleni & Lemonidou, Angeliki A., 2016. "Energy efficient sorption enhanced-chemical looping methane reforming process for high-purity H2 production: Experimental proof-of-concept," Applied Energy, Elsevier, vol. 180(C), pages 457-471.
    4. Barelli, L. & Bidini, G. & Gallorini, F., 2015. "SE-SR with sorbents based on calcium aluminates: Process optimization," Applied Energy, Elsevier, vol. 143(C), pages 110-118.
    5. Barelli, L. & Bidini, G. & Cinti, G. & Gallorini, F. & Pöniz, M., 2017. "SOFC stack coupled with dry reforming," Applied Energy, Elsevier, vol. 192(C), pages 498-507.
    6. Perejón, Antonio & Romeo, Luis M. & Lara, Yolanda & Lisbona, Pilar & Martínez, Ana & Valverde, Jose Manuel, 2016. "The Calcium-Looping technology for CO2 capture: On the important roles of energy integration and sorbent behavior," Applied Energy, Elsevier, vol. 162(C), pages 787-807.
    7. Esteban-Díez, G. & Gil, María V. & Pevida, C. & Chen, D. & Rubiera, F., 2016. "Effect of operating conditions on the sorption enhanced steam reforming of blends of acetic acid and acetone as bio-oil model compounds," Applied Energy, Elsevier, vol. 177(C), pages 579-590.
    8. Franzoni, A. & Magistri, L. & Traverso, A. & Massardo, A.F., 2008. "Thermoeconomic analysis of pressurized hybrid SOFC systems with CO2 separation," Energy, Elsevier, vol. 33(2), pages 311-320.
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    5. Lu, Yi Ran & Nikrityuk, Petr, 2018. "A fixed-bed reactor for energy storage in chemicals (E2C): Proof of concept," Applied Energy, Elsevier, vol. 228(C), pages 593-607.
    6. Gu, Rong & Ding, Jing & Wang, Yarong & Yuan, Qinquan & Wang, Weilong & Lu, Jianfeng, 2019. "Heat transfer and storage performance of steam methane reforming in tubular reactor with focused solar simulator," Applied Energy, Elsevier, vol. 233, pages 789-801.
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