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Adiabatic magnesium hydride system for hydrogen storage based on thermochemical heat storage: Numerical analysis of the dehydrogenation

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  • Lutz, Michael
  • Bhouri, Maha
  • Linder, Marc
  • Bürger, Inga

Abstract

With hydrogen becoming more and more important as storage and carrier for renewable energy, there is an increasing need for flexible and efficient storage technologies. However, existing technologies, such as liquefaction or compression, often require a significant share of the hydrogens lower heating value. High-temperature metal hydrides (HT-MHs), such as magnesium hydride, are a promising alternative. Due to high operation temperatures, their application is challenging. A novel adiabatic hydrogen storage reactor based on the combination of a HT-MH with a thermochemical energy storage system (TCSS), such as Mg(OH)2/MgO + H2O, can be a solution. In this work, the previously published numerical simulations for hydrogen absorption are extended to the desorption process. A two-dimensional model for the hydrogen release was set up. The performance of the storage reactor is strongly dependent on the thermodynamic equilibrium of the reactions involved and less dependent on the reaction kinetics. Dehydrogenation is possible within 132 min, which is in the vicinity of the hydrogenation time. To enhance the dehydrogenation process, the water vapor pressure can be adjusted aiming for higher temperatures during the MgO hydration. Hydrogen can either be provided at constant pressure or constant mass flow rate.

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  • Lutz, Michael & Bhouri, Maha & Linder, Marc & Bürger, Inga, 2019. "Adiabatic magnesium hydride system for hydrogen storage based on thermochemical heat storage: Numerical analysis of the dehydrogenation," Applied Energy, Elsevier, vol. 236(C), pages 1034-1048.
    • Handle: RePEc:eee:appene:v:236:y:2019:i:c:p:1034-1048
    DOI: 10.1016/j.apenergy.2018.12.038
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    Cited by:

    1. Tsai, Yun-Ting & Yang, Yi & Pan, Yong & Shu, Chi-Min, 2023. "Catalytic effects of magnesium-transition metal (Fe and Ni) hydrides on oxygen and nitrogen reduction: A case study of explosive characteristics and their environmental contaminants," Energy, Elsevier, vol. 280(C).
    2. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    3. Seon Tae Kim & Haruka Miura & Hiroki Takasu & Yukitaka Kato & Alexandr Shkatulov & Yuri Aristov, 2019. "Adapting the MgO-CO 2 Working Pair for Thermochemical Energy Storage by Doping with Salts: Effect of the (LiK)NO 3 Content," Energies, MDPI, vol. 12(12), pages 1-13, June.
    4. Bai, Xiao-Shuai & Rong, Long & Yang, Wei-Wei & Yang, Fu-Sheng, 2023. "Effective thermal conductivity of metal hydride particle bed: Theoretical model and experimental validation," Energy, Elsevier, vol. 271(C).
    5. Lutz, Michael & Linder, Marc & Bürger, Inga, 2020. "High capacity, low pressure hydrogen storage based on magnesium hydride and thermochemical heat storage: Experimental proof of concept," Applied Energy, Elsevier, vol. 271(C).
    6. Shi, Tao & Xu, Huijin, 2022. "Integration of hydrogen storage and heat storage in thermochemical reactors enhanced with optimized topological structures: Charging process," Applied Energy, Elsevier, vol. 327(C).
    7. Hassan, I.A. & Ramadan, Haitham S. & Saleh, Mohamed A. & Hissel, Daniel, 2021. "Hydrogen storage technologies for stationary and mobile applications: Review, analysis and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).

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    More about this item

    Keywords

    H2 storage; Thermochemical heat storage; Magnesium hydride; Magnesium oxide; Dehydrogenation; Numerical study;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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