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The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems

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  • Yan, J.
  • Zhao, C.Y.
  • Pan, Z.H.

Abstract

Cyclic stability is a key factor in the design of thermochemical heat storage systems. Because carbon dioxide (CO2) may react with heat storage materials and lead to a decrease in energy storage efficiency, the effect of CO2 on Ca(OH)2/CaO and Mg(OH)2/MgO systems is investigated in this study. The experimental results show that CO2 reacts with CaO in the water vapor that appears during the heat release process. Therefore, in the design of Ca(OH)2/CaO systems, CO2 should be cleared from the system. The results from Mg(OH)2/MgO systems show that CO2 only slightly reacts with MgO and Mg(OH)2 during heat storage and release processes. This study indicates that carbonic acid (H2CO3) could easily react with CaO/Ca(OH)2 to form CaCO3 during heat release processes. Generally, the remaining CO2 reduces the reversibility of Ca(OH)2/CaO systems but has only a slight influence on Mg(OH)2/MgO systems. In addition, the experimental results show that carbonate shell does not exist in rehydration for both of the CaO/MgO samples, but the influence of CO2 on the entire process increases after each cycle.

Suggested Citation

  • Yan, J. & Zhao, C.Y. & Pan, Z.H., 2017. "The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems," Energy, Elsevier, vol. 124(C), pages 114-123.
    • Handle: RePEc:eee:energy:v:124:y:2017:i:c:p:114-123
    DOI: 10.1016/j.energy.2017.02.034
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    Cited by:

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    3. Feng, Yupeng & Hu, Xiannan & Li, Xuhan & Zhang, Man & Zhu, Shahong & Yang, Hairui, 2023. "Self-compensation and attenuation mechanisms of carbide slag in multicycle thermochemical heat storage," Renewable Energy, Elsevier, vol. 218(C).
    4. Wang, Mengyi & Chen, Li & Zhou, Yuhao & Tao, Wen-Quan, 2022. "Numerical simulation of the calcium hydroxide/calcium oxide system dehydration reaction in a shell-tube reactor," Applied Energy, Elsevier, vol. 312(C).
    5. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    6. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    7. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).

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