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High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent

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  • Hafizi, A.
  • Rahimpour, M.R.
  • Hassanajili, S.

Abstract

High purity hydrogen can be produced using sorption enhanced chemical looping reforming (SE–CLR) in which an oxygen carrier and an in situ CO2 sorbent are involved. In this study, the effectiveness of alumina modification with Mg as the support of Fe2O3 based oxygen carriers is investigated in CLR and SE–CLR processes for clean hydrogen production. The 22Fe2O3/Al2O3 and 22Fe2O3/MgAl2O4 oxygen carriers are synthesized with impregnation and sequential impregnation methods, respectively. Prior to SE–CLR process, the performance of three different calcium based sorbents including industrial CaO, synthesized CaO and cerium promoted CaO are investigated for CO2 sorption in calcium loop. The characterization of the oxygen carriers and sorbent samples is performed by XRD, BET, FESEM and TEM. It is found that the addition of cerium to the calcium-based sorbent effectively improves its structural properties and CO2 sorption performance. The obtained results reveal that the sorbent surface area is a significant parameter affecting its CO2 removal efficiency at high temperatures. In addition, the presence of Mg in oxygen carrier structure successfully prevents the formation of Fe–Al spinel by MgAl2O4 formation. An excessive H2/CO molar ratio of 16.7 is also achieved using Fe2O3/MgAl2O4 oxygen carrier and synthesized Ce/Ca=0.2 sorbent at 600°C in SE–CLR process.

Suggested Citation

  • Hafizi, A. & Rahimpour, M.R. & Hassanajili, S., 2016. "High purity hydrogen production via sorption enhanced chemical looping reforming: Application of 22Fe2O3/MgAl2O4 and 22Fe2O3/Al2O3 as oxygen carriers and cerium promoted CaO as CO2 sorbent," Applied Energy, Elsevier, vol. 169(C), pages 629-641.
    • Handle: RePEc:eee:appene:v:169:y:2016:i:c:p:629-641
    DOI: 10.1016/j.apenergy.2016.02.068
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    4. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2017. "A reduced fidelity model for the rotary chemical looping combustion reactor," Applied Energy, Elsevier, vol. 190(C), pages 725-739.
    5. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    6. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2018. "Design and techno-economic optimization of a rotary chemical looping combustion power plant with CO2 capture," Applied Energy, Elsevier, vol. 231(C), pages 1179-1190.
    7. Zeng, Jimin & Hu, Jiawei & Qiu, Yu & Zhang, Shuai & Zeng, Dewang & Xiao, Rui, 2019. "Multi-function of oxygen carrier for in-situ tar removal in chemical looping gasification: Naphthalene as a model compound," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    8. Živković, Luka A. & Pohar, Andrej & Likozar, Blaž & Nikačević, Nikola M., 2016. "Kinetics and reactor modeling for CaO sorption-enhanced high-temperature water–gas shift (SE–WGS) reaction for hydrogen production," Applied Energy, Elsevier, vol. 178(C), pages 844-855.
    9. Gil, María V. & Rout, Kumar R. & Chen, De, 2018. "Production of high pressure pure H2 by pressure swing sorption enhanced steam reforming (PS-SESR) of byproducts in biorefinery," Applied Energy, Elsevier, vol. 222(C), pages 595-607.
    10. Shi, Jiewen & Li, Yingjie & Zhang, Qing & Ma, Xiaotong & Duan, Lunbo & Zhou, Xingang, 2017. "CO2 capture performance of a novel synthetic CaO/sepiolite sorbent at calcium looping conditions," Applied Energy, Elsevier, vol. 203(C), pages 412-421.
    11. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    12. Zhao, Yunlei & Jin, Bo & Luo, Xiao & Liang, Zhiwu, 2021. "Thermodynamic evaluation and experimental investigation of CaO-assisted Fe-based chemical looping reforming process for syngas production," Applied Energy, Elsevier, vol. 288(C).
    13. Zhang, Wan & Li, Yingjie & He, Zirui & Ma, Xiaotong & Song, Haiping, 2017. "CO2 capture by carbide slag calcined under high-concentration steam and energy requirement in calcium looping conditions," Applied Energy, Elsevier, vol. 206(C), pages 869-878.

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