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System analysis of dry black liquor gasification based synthetic gas production comparing oxygen and air blown gasification systems

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  • Naqvi, Muhammad
  • Yan, Jinyue
  • Dahlquist, Erik

Abstract

The black liquor gasification based bio-fuel production at chemical pulp mill is an attractive option to replace conventional recovery boilers increasing system energy efficiency. The present paper studies circulating fluidized bed system with direct causticization using TiO2 for the gasification of the black liquor to the synthesis gas. The advantage of using direct causticization is the elimination of energy-intensive lime kiln which is an integral part of the conventional black liquor recovery system. The study evaluates the effects of gasifying medium i.e. oxygen or air, on the fluidized bed gasification system, the synthesis gas composition, and the downstream processes for the synthesis gas conversion to the synthetic natural gas (SNG). The results showed higher synthetic natural gas production potential with about 10% higher energy efficiency using oxygen blown gasification system than the air blown system. From the pulp mill integration perspective, the material and energy balance results in better integration of air blown system than the oxygen blown system, e.g. less steam required to be generated in the power boiler, less electricity import, and less additional biomass requirement. However, the air blown system still requires a significant amount of energy in terms of the synthesis gas handling and gas upgrading using the nitrogen rejection system.

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  • Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2013. "System analysis of dry black liquor gasification based synthetic gas production comparing oxygen and air blown gasification systems," Applied Energy, Elsevier, vol. 112(C), pages 1275-1282.
  • Handle: RePEc:eee:appene:v:112:y:2013:i:c:p:1275-1282
    DOI: 10.1016/j.apenergy.2012.11.065
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    References listed on IDEAS

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    1. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Bio-refinery system in a pulp mill for methanol production with comparison of pressurized black liquor gasification and dry gasification using direct causticization," Applied Energy, Elsevier, vol. 90(1), pages 24-31.
    2. Möllersten, Kenneth & Gao, Lin & Yan, Jinyue & Obersteiner, Michael, 2004. "Efficient energy systems with CO2 capture and storage from renewable biomass in pulp and paper mills," Renewable Energy, Elsevier, vol. 29(9), pages 1583-1598.
    3. Andersson, E. & Harvey, S., 2006. "System analysis of hydrogen production from gasified black liquor," Energy, Elsevier, vol. 31(15), pages 3426-3434.
    4. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Synthetic gas production from dry black liquor gasification process using direct causticization with CO2 capture," Applied Energy, Elsevier, vol. 97(C), pages 49-55.
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    Cited by:

    1. Carvalho, Lara & Lundgren, Joakim & Wetterlund, Elisabeth & Wolf, Jens & Furusjö, Erik, 2018. "Methanol production via black liquor co-gasification with expanded raw material base – Techno-economic assessment," Applied Energy, Elsevier, vol. 225(C), pages 570-584.
    2. Darmawan, Arif & Ajiwibowo, Muhammad W. & Yoshikawa, Kunio & Aziz, Muhammad & Tokimatsu, Koji, 2018. "Energy-efficient recovery of black liquor through gasification and syngas chemical looping," Applied Energy, Elsevier, vol. 219(C), pages 290-298.
    3. Zimmer, Tobias & Rudi, Andreas & Müller, Ann-Kathrin & Fröhling, Magnus & Schultmann, Frank, 2017. "Modeling the impact of competing utilization paths on biomass-to-liquid (BtL) supply chains," Applied Energy, Elsevier, vol. 208(C), pages 954-971.
    4. Akbari, Maryam & Oyedun, Adetoyese Olajire & Kumar, Amit, 2018. "Ammonia production from black liquor gasification and co-gasification with pulp and waste sludges: A techno-economic assessment," Energy, Elsevier, vol. 151(C), pages 133-143.
    5. Naqvi, M. & Dahlquist, E. & Yan, J. & Naqvi, S.R. & Nizami, A.S. & Salman, C.A. & Danish, M. & Farooq, U. & Rehan, M. & Khan, Z. & Qureshi, A.S., 2018. "Polygeneration system integrated with small non-wood pulp mills for substitute natural gas production," Applied Energy, Elsevier, vol. 224(C), pages 636-646.
    6. Imai, Akihisa & Hardi, Flabianus & Lundqvist, Petter & Furusjö, Erik & Kirtania, Kawnish & Karagöz, Selhan & Tekin, Kubilay & Yoshikawa, Kunio, 2018. "Alkali-catalyzed hydrothermal treatment of sawdust for production of a potential feedstock for catalytic gasification," Applied Energy, Elsevier, vol. 231(C), pages 594-599.
    7. Dahlquist, Erik & Naqvi, Muhammad & Thorin, Eva & Yan, Jinyue & Kyprianidis, Konstantinos & Hartwell, Philip, 2017. "Experimental and numerical investigation of pellet and black liquor gasification for polygeneration plant," Applied Energy, Elsevier, vol. 204(C), pages 1055-1064.
    8. Darmawan, Arif & Hardi, Flabianus & Yoshikawa, Kunio & Aziz, Muhammad & Tokimatsu, Koji, 2017. "Enhanced process integration of black liquor evaporation, gasification, and combined cycle," Applied Energy, Elsevier, vol. 204(C), pages 1035-1042.
    9. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik & Naqvi, Salman Raza, 2017. "Off-grid electricity generation using mixed biomass compost: A scenario-based study with sensitivity analysis," Applied Energy, Elsevier, vol. 201(C), pages 363-370.

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