IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v109y2013icp415-420.html
   My bibliography  Save this article

Intercomparative tests on phase change materials characterisation with differential scanning calorimeter

Author

Listed:
  • Lazaro, Ana
  • Peñalosa, Conchita
  • Solé, Aran
  • Diarce, Gonzalo
  • Haussmann, Thomas
  • Fois, Magali
  • Zalba, Belén
  • Gshwander, Stefan
  • Cabeza, Luisa F.

Abstract

For the correct design of thermal storage systems using phase change materials (PCMs) in any application, as well as for their simulation, it is essential to characterise the materials from thermophysical and rheological standpoints (phase change enthalpy, thermal conductivity in solid and liquid phases, viscosity and density in function of temperature). Taking advantage of the different research groups facilities available in two international networks: within the IEA (International Energy Agency), the ECES Implementing Agreement (Energy Conservation through Energy Storage IA) and SHC Programme (Solar Heating and Cooling) Task 42/Annex 24 “Compact Thermal Energy Storage – Material Development for System Integration”, and the COST Action TU0802 “Next generation cost effective phase change materials for increased energy efficiency in renewable energy systems in buildings (NeCoE-PCM)” a set of Round Robin Tests (RRTs) was proposed. The objective was to come to comparable results for PCMs using Differential Scanning Calorimetry (DSC) to determine their melting enthalpy as well as their melting and solidification behaviour. The first RRT was without defining the procedure, the second one with a predefined procedure for the measurements, but not for calibration and the third one with a predefined procedure for calibration, for the measurements and also for the data evaluation. This paper presents the conclusions after the three RRT. The main conclusion of the paper is that enthalpy in function of temperature determined using a dynamic method for DSC can be influenced by certain reasons and finally a methodology to avoid these influences have been proposed.

Suggested Citation

  • Lazaro, Ana & Peñalosa, Conchita & Solé, Aran & Diarce, Gonzalo & Haussmann, Thomas & Fois, Magali & Zalba, Belén & Gshwander, Stefan & Cabeza, Luisa F., 2013. "Intercomparative tests on phase change materials characterisation with differential scanning calorimeter," Applied Energy, Elsevier, vol. 109(C), pages 415-420.
    • Handle: RePEc:eee:appene:v:109:y:2013:i:c:p:415-420
    DOI: 10.1016/j.apenergy.2012.11.045
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261912008483
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2012.11.045?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    2. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    3. Arce, Pablo & Medrano, Marc & Gil, Antoni & Oró, Eduard & Cabeza, Luisa F., 2011. "Overview of thermal energy storage (TES) potential energy savings and climate change mitigation in Spain and Europe," Applied Energy, Elsevier, vol. 88(8), pages 2764-2774, August.
    4. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    5. Zhang, Zhengguo & Zhang, Ni & Peng, Jing & Fang, Xiaoming & Gao, Xuenong & Fang, Yutang, 2012. "Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material," Applied Energy, Elsevier, vol. 91(1), pages 426-431.
    6. Medrano, Marc & Gil, Antoni & Martorell, Ingrid & Potau, Xavi & Cabeza, Luisa F., 2010. "State of the art on high-temperature thermal energy storage for power generation. Part 2--Case studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 56-72, January.
    7. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    8. He, Bo & Martin, Viktoria & Setterwall, Fredrik, 2004. "Phase transition temperature ranges and storage density of paraffin wax phase change materials," Energy, Elsevier, vol. 29(11), pages 1785-1804.
    9. Li, Min & Wu, Zhishen & Kao, Hongtao, 2011. "Study on preparation, structure and thermal energy storage property of capric–palmitic acid/attapulgite composite phase change materials," Applied Energy, Elsevier, vol. 88(9), pages 3125-3132.
    10. Li, Min & Wu, Zhishen & Tan, Jinmiao, 2012. "Properties of form-stable paraffin/silicon dioxide/expanded graphite phase change composites prepared by sol–gel method," Applied Energy, Elsevier, vol. 92(C), pages 456-461.
    11. Chen, Zhong-Hua & Yu, Fei & Zeng, Xing-Rong & Zhang, Zheng-Guo, 2012. "Preparation, characterization and thermal properties of nanocapsules containing phase change material n-dodecanol by miniemulsion polymerization with polymerizable emulsifier," Applied Energy, Elsevier, vol. 91(1), pages 7-12.
    12. Darkwa, J. & Su, O. & Zhou, T., 2012. "Development of non-deform micro-encapsulated phase change energy storage tablets," Applied Energy, Elsevier, vol. 98(C), pages 441-447.
    13. Cai, Yibing & Wei, Qufu & Huang, Fenglin & Gao, Weidong, 2008. "Preparation and properties studies of halogen-free flame retardant form-stable phase change materials based on paraffin/high density polyethylene composites," Applied Energy, Elsevier, vol. 85(8), pages 765-775, August.
    14. Gil, Antoni & Medrano, Marc & Martorell, Ingrid & Lázaro, Ana & Dolado, Pablo & Zalba, Belén & Cabeza, Luisa F., 2010. "State of the art on high temperature thermal energy storage for power generation. Part 1--Concepts, materials and modellization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 31-55, January.
    15. Diaconu, Bogdan M. & Varga, Szabolcs & Oliveira, Armando C., 2010. "Experimental assessment of heat storage properties and heat transfer characteristics of a phase change material slurry for air conditioning applications," Applied Energy, Elsevier, vol. 87(2), pages 620-628, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    2. Diarce, G. & Campos-Celador, Á. & Martin, K. & Urresti, A. & García-Romero, A. & Sala, J.M., 2014. "A comparative study of the CFD modeling of a ventilated active façade including phase change materials," Applied Energy, Elsevier, vol. 126(C), pages 307-317.
    3. Parameshwaran, R. & Kalaiselvam, S., 2013. "Energy efficient hybrid nanocomposite-based cool thermal storage air conditioning system for sustainable buildings," Energy, Elsevier, vol. 59(C), pages 194-214.
    4. Ling, Haoshu & Chen, Chao & Wei, Shen & Guan, Yong & Ma, Caiwen & Xie, Guangya & Li, Na & Chen, Ziguang, 2015. "Effect of phase change materials on indoor thermal environment under different weather conditions and over a long time," Applied Energy, Elsevier, vol. 140(C), pages 329-337.
    5. Tittelein, Pierre & Gibout, Stéphane & Franquet, Erwin & Johannes, Kevyn & Zalewski, Laurent & Kuznik, Frédéric & Dumas, Jean-Pierre & Lassue, Stéphane & Bédécarrats, Jean-Pierre & David, Damien, 2015. "Simulation of the thermal and energy behaviour of a composite material containing encapsulated-PCM: Influence of the thermodynamical modelling," Applied Energy, Elsevier, vol. 140(C), pages 269-274.
    6. López-Navarro, A. & Biosca-Taronger, J. & Corberán, J.M. & Peñalosa, C. & Lázaro, A. & Dolado, P. & Payá, J., 2014. "Performance characterization of a PCM storage tank," Applied Energy, Elsevier, vol. 119(C), pages 151-162.
    7. Saeed, Rami M. & Schlegel, J.P. & Sawafta, R., 2019. "Characterization of high-temperature PCMs for enhancing passive safety and heat removal capabilities in nuclear reactor systems," Energy, Elsevier, vol. 189(C).
    8. Kousksou, T. & Alaphilippe, M. & Jamil, A. & El Rhafiki, T. & Mouqalid, M. & Zeraouli, Y., 2014. "An implicit enthalpy formulation for macroscopic eutectic and progressive melting: DSC (Differential Scanning Calorimetry) applications," Energy, Elsevier, vol. 66(C), pages 919-926.
    9. Rodrigo Fuentes-Sepúlveda & Claudio García-Herrera & Diego A. Vasco & Carlos Salinas-Lira & Rubén A. Ananías, 2020. "Thermal Characterization of Pinus radiata Wood Vacuum-Impregnated with Octadecane," Energies, MDPI, vol. 13(4), pages 1-16, February.
    10. Pop, Octavian G. & Fechete Tutunaru, Lucian & Bode, Florin & Abrudan, Ancuţa C. & Balan, Mugur C., 2018. "Energy efficiency of PCM integrated in fresh air cooling systems in different climatic conditions," Applied Energy, Elsevier, vol. 212(C), pages 976-996.
    11. Castell, A. & Solé, C., 2015. "An overview on design methodologies for liquid–solid PCM storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 289-307.
    12. Gasia, Jaume & Miró, Laia & Cabeza, Luisa F., 2017. "Review on system and materials requirements for high temperature thermal energy storage. Part 1: General requirements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 1320-1338.
    13. Rathgeber, Christoph & Schmit, Henri & Hennemann, Peter & Hiebler, Stefan, 2014. "Investigation of pinacone hexahydrate as phase change material for thermal energy storage around 45°C," Applied Energy, Elsevier, vol. 136(C), pages 7-13.
    14. Mazzeo, Domenico & Oliveti, Giuseppe & de Gracia, Alvaro & Coma, Julià & Solé, Aran & Cabeza, Luisa F., 2017. "Experimental validation of the exact analytical solution to the steady periodic heat transfer problem in a PCM layer," Energy, Elsevier, vol. 140(P1), pages 1131-1147.
    15. Fang, Yutang & Liu, Xin & Liang, Xianghui & Liu, Hong & Gao, Xuenong & Zhang, Zhengguo, 2014. "Ultrasonic synthesis and characterization of polystyrene/n-dotriacontane composite nanoencapsulated phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 132(C), pages 551-556.
    16. Luca Brunelli & Emiliano Borri & Anna Laura Pisello & Andrea Nicolini & Carles Mateu & Luisa F. Cabeza, 2024. "Thermal Energy Storage in Energy Communities: A Perspective Overview through a Bibliometric Analysis," Sustainability, MDPI, vol. 16(14), pages 1-27, July.
    17. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2016. "Stable, low-cost phase change material for building applications: The eutectic mixture of decanoic acid and tetradecanoic acid," Applied Energy, Elsevier, vol. 168(C), pages 457-464.
    18. Cabeza, Luisa F. & Barreneche, Camila & Martorell, Ingrid & Miró, Laia & Sari-Bey, Sana & Fois, Magali & Paksoy, Halime O. & Sahan, Nurten & Weber, Robert & Constantinescu, Mariaella & Anghel, Elena M, 2015. "Unconventional experimental technologies available for phase change materials (PCM) characterization. Part 1. Thermophysical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1399-1414.
    19. Xu, Huaqian & Zuo, Hongyang & Zeng, Kuo & Lu, Yongwen & Chi, Bowen & Flamant, Gilles & Yang, Haiping & Chen, Hanping, 2024. "Investigation of the modified Gaussian-based non-phase field method for numerical simulation of latent heat storage," Energy, Elsevier, vol. 288(C).
    20. Mandilaras, I.D. & Kontogeorgos, D.A. & Founti, M.A., 2015. "A hybrid methodology for the determination of the effective heat capacity of PCM enhanced building components," Renewable Energy, Elsevier, vol. 76(C), pages 790-804.
    21. Rebeca Salgado-Pizarro & Jose Antonio Padilla & Elena Xuriguera & Camila Barreneche & Ana Inés Fernández, 2021. "Novel Shape-Stabilized Phase Change Material with Cascade Character: Synthesis, Performance and Shaping Evaluation," Energies, MDPI, vol. 14(9), pages 1-13, May.
    22. Feng, Guohui & Huang, Kailiang & Xie, Hailun & Li, Huixing & Liu, Xin & Liu, Shibo & Cao, Chihong, 2016. "DSC test error of phase change material (PCM) and its influence on the simulation of the PCM floor," Renewable Energy, Elsevier, vol. 87(P3), pages 1148-1153.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    2. Giro-Paloma, Jessica & Oncins, Gerard & Barreneche, Camila & Martínez, Mònica & Fernández, A. Inés & Cabeza, Luisa F., 2013. "Physico-chemical and mechanical properties of microencapsulated phase change material," Applied Energy, Elsevier, vol. 109(C), pages 441-448.
    3. Su, Weiguang & Darkwa, Jo & Kokogiannakis, Georgios, 2015. "Review of solid–liquid phase change materials and their encapsulation technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 373-391.
    4. Cao, Lei & Su, Di & Tang, Yaojie & Fang, Guiyin & Tang, Fang, 2015. "Properties evaluation and applications of thermal energystorage materials in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 500-522.
    5. Ge, Haoshan & Li, Haiyan & Mei, Shengfu & Liu, Jing, 2013. "Low melting point liquid metal as a new class of phase change material: An emerging frontier in energy area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 331-346.
    6. Kenisarin, Murat M. & Kenisarina, Kamola M., 2012. "Form-stable phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1999-2040.
    7. Arteconi, A. & Hewitt, N.J. & Polonara, F., 2012. "State of the art of thermal storage for demand-side management," Applied Energy, Elsevier, vol. 93(C), pages 371-389.
    8. Qiu, Xiaolin & Li, Wei & Song, Guolin & Chu, Xiaodong & Tang, Guoyi, 2012. "Microencapsulated n-octadecane with different methylmethacrylate-based copolymer shells as phase change materials for thermal energy storage," Energy, Elsevier, vol. 46(1), pages 188-199.
    9. Rao, Zhonghao & Wang, Shuangfeng & Peng, Feifei, 2012. "Self diffusion of the nano-encapsulated phase change materials: A molecular dynamics study," Applied Energy, Elsevier, vol. 100(C), pages 303-308.
    10. Parameshwaran, R. & Deepak, K. & Saravanan, R. & Kalaiselvam, S., 2014. "Preparation, thermal and rheological properties of hybrid nanocomposite phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 115(C), pages 320-330.
    11. Nomura, Takahiro & Tabuchi, Kazuki & Zhu, Chunyu & Sheng, Nan & Wang, Shuangfeng & Akiyama, Tomohiro, 2015. "High thermal conductivity phase change composite with percolating carbon fiber network," Applied Energy, Elsevier, vol. 154(C), pages 678-685.
    12. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    13. Wang, Zhangyuan & Qiu, Feng & Yang, Wansheng & Zhao, Xudong, 2015. "Applications of solar water heating system with phase change material," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 645-652.
    14. Oró, E. & de Gracia, A. & Castell, A. & Farid, M.M. & Cabeza, L.F., 2012. "Review on phase change materials (PCMs) for cold thermal energy storage applications," Applied Energy, Elsevier, vol. 99(C), pages 513-533.
    15. Chinnasamy, Veerakumar & Heo, Jaehyeok & Jung, Sungyong & Lee, Hoseong & Cho, Honghyun, 2023. "Shape stabilized phase change materials based on different support structures for thermal energy storage applications–A review," Energy, Elsevier, vol. 262(PB).
    16. Kenisarin, Murat & Mahkamov, Khamid, 2016. "Passive thermal control in residential buildings using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 371-398.
    17. Fang, Guiyin & Tang, Fang & Cao, Lei, 2014. "Preparation, thermal properties and applications of shape-stabilized thermal energy storage materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 237-259.
    18. Gil, Antoni & Barreneche, Camila & Moreno, Pere & Solé, Cristian & Inés Fernández, A. & Cabeza, Luisa F., 2013. "Thermal behaviour of d-mannitol when used as PCM: Comparison of results obtained by DSC and in a thermal energy storage unit at pilot plant scale," Applied Energy, Elsevier, vol. 111(C), pages 1107-1113.
    19. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    20. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:109:y:2013:i:c:p:415-420. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.