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Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light

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  • Wang, Yunming
  • Tang, Bingtao
  • Zhang, Shufen

Abstract

Broadband visible sunlight usage and shape-stabilized effect were achieved using organic, cross-linking, and shape-stabilized phase-changed materials (OCSPCMs) with broadband visible light absorption, which were obtained by cross-linking reticulation and color matching (yellow, red, and blue) according to solar irradiation energy density. The obtained OCSPCMs exhibited excellent form-stable phase-change energy storage and broadband visible light-harvesting. Under broadband irradiation (from 400nm to 700nm), the light-to-heat conversion and the thermal energy storage efficiency (η>0.74) of the OCSPCMs were significantly improved upon solar irradiation by color matching compared with those of OCSPCMs with single-band selective absorption of visible light (yellow, red, or blue). Differential scanning calorimetric results indicated that the phase change temperatures and latent heats of OCSPCMs ranged from 32.6°C to 60.2°C and from 120.1J/g to 132.7J/g, respectively. The novel materials show a reversible (more than 200 cycles) phase transition via ON/OFF switching of visible light irradiation.

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  • Wang, Yunming & Tang, Bingtao & Zhang, Shufen, 2014. "Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light," Applied Energy, Elsevier, vol. 113(C), pages 59-66.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:59-66
    DOI: 10.1016/j.apenergy.2013.07.007
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