IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v87y2010i5p1529-1534.html
   My bibliography  Save this article

Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage

Author

Listed:
  • SarI, Ahmet
  • Alkan, Cemil
  • Karaipekli, Ali

Abstract

This study is focused on the preparation, characterization and thermal properties of microencapsulated n-heptadecane with polymethylmethacrylate shell. The PMMA/heptadecane microcapsules were synthesized as novel solid-liquid microencapsulated phase change material (microPCMs) by emulsion polymerization method. The chemical and thermal characterization of the microPCMs were investigated using scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). The diameters of microPCMs were found in the narrow range (0.14-0.40Â [mu]m) under the stirring speed of 2000Â rpm. The spherical surfaces of microPCMs were smooth and compact. The DSC results show that microPCMs have good energy storage capacity. Thermal cycling test showed that the microPCMs have good thermal reliability with respect to the changes in their thermal properties after repeated 5000 thermal cycling. TGA analyses also indicated that the microPCMs degraded in three steps and have good thermal stability. Based on all results, it can be considered that the PMMA/heptadecane microcapsules as novel solid-liquid microPCMs have good energy storage potential.

Suggested Citation

  • SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
  • Handle: RePEc:eee:appene:v:87:y:2010:i:5:p:1529-1534
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306-2619(09)00439-5
    Download Restriction: Full text for ScienceDirect subscribers only
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rady, Mohamed, 2009. "Thermal performance of packed bed thermal energy storage units using multiple granular phase change composites," Applied Energy, Elsevier, vol. 86(12), pages 2704-2720, December.
    2. Medrano, M. & Yilmaz, M.O. & Nogués, M. & Martorell, I. & Roca, Joan & Cabeza, Luisa F., 2009. "Experimental evaluation of commercial heat exchangers for use as PCM thermal storage systems," Applied Energy, Elsevier, vol. 86(10), pages 2047-2055, October.
    3. Kuznik, Frédéric & Virgone, Joseph, 2009. "Experimental assessment of a phase change material for wall building use," Applied Energy, Elsevier, vol. 86(10), pages 2038-2046, October.
    4. Xiao, Wei & Wang, Xin & Zhang, Yinping, 2009. "Analytical optimization of interior PCM for energy storage in a lightweight passive solar room," Applied Energy, Elsevier, vol. 86(10), pages 2013-2018, October.
    5. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing, 2009. "Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid-liquid phase change materials," Applied Energy, Elsevier, vol. 86(2), pages 170-174, February.
    6. Mawire, A. & McPherson, M. & Heetkamp, R.R.J. van den & Mlatho, S.J.P., 2009. "Simulated performance of storage materials for pebble bed thermal energy storage (TES) systems," Applied Energy, Elsevier, vol. 86(7-8), pages 1246-1252, July.
    7. Hawlader, M. N. A. & Uddin, M. S. & Khin, Mya Mya, 2003. "Microencapsulated PCM thermal-energy storage system," Applied Energy, Elsevier, vol. 74(1-2), pages 195-202, January.
    8. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    9. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    10. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Enhanced thermal conductivity and thermal performance of form-stable composite phase change materials by using [beta]-Aluminum nitride," Applied Energy, Elsevier, vol. 86(7-8), pages 1196-1200, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Joulin, Annabelle & Younsi, Zohir & Zalewski, Laurent & Lassue, Stéphane & Rousse, Daniel R. & Cavrot, Jean-Paul, 2011. "Experimental and numerical investigation of a phase change material: Thermal-energy storage and release," Applied Energy, Elsevier, vol. 88(7), pages 2454-2462, July.
    2. Borreguero, Ana M. & Luz Sánchez, M. & Valverde, José Luis & Carmona, Manuel & Rodríguez, Juan F., 2011. "Thermal testing and numerical simulation of gypsum wallboards incorporated with different PCMs content," Applied Energy, Elsevier, vol. 88(3), pages 930-937, March.
    3. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    4. Wang, Weilong & Guo, Shaopeng & Li, Hailong & Yan, Jinyue & Zhao, Jun & Li, Xun & Ding, Jing, 2014. "Experimental study on the direct/indirect contact energy storage container in mobilized thermal energy system (M-TES)," Applied Energy, Elsevier, vol. 119(C), pages 181-189.
    5. Tao, Y.B. & He, Y.L., 2011. "Numerical study on thermal energy storage performance of phase change material under non-steady-state inlet boundary," Applied Energy, Elsevier, vol. 88(11), pages 4172-4179.
    6. Li, Min & Wu, Zhishen & Tan, Jinmiao, 2013. "Heat storage properties of the cement mortar incorporated with composite phase change material," Applied Energy, Elsevier, vol. 103(C), pages 393-399.
    7. Arce, Pablo & Medrano, Marc & Gil, Antoni & Oró, Eduard & Cabeza, Luisa F., 2011. "Overview of thermal energy storage (TES) potential energy savings and climate change mitigation in Spain and Europe," Applied Energy, Elsevier, vol. 88(8), pages 2764-2774, August.
    8. Cai, Yibing & Ke, Huizhen & Dong, Ju & Wei, Qufu & Lin, Jiulong & Zhao, Yong & Song, Lei & Hu, Yuan & Huang, Fenglin & Gao, Weidong & Fong, Hao, 2011. "Effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form-stable phase change materials," Applied Energy, Elsevier, vol. 88(6), pages 2106-2112, June.
    9. Wang, Weilong & Li, Hailong & Guo, Shaopeng & He, Shiquan & Ding, Jing & Yan, Jinyue & Yang, Jianping, 2015. "Numerical simulation study on discharging process of the direct-contact phase change energy storage system," Applied Energy, Elsevier, vol. 150(C), pages 61-68.
    10. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    11. Wang, Lijiu & Meng, Duo, 2010. "Fatty acid eutectic/polymethyl methacrylate composite as form-stable phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 87(8), pages 2660-2665, August.
    12. Chen, Changzhong & Wang, Linge & Huang, Yong, 2011. "Electrospun phase change fibers based on polyethylene glycol/cellulose acetate blends," Applied Energy, Elsevier, vol. 88(9), pages 3133-3139.
    13. Wang, Chih Lin & Yeh, Kuan Lin & Chen, Chih Wei & Lee, Yun & Lee, Hung Lin & Lee, Tu, 2017. "A quick-fix design of phase change material by particle blending and spherical agglomeration," Applied Energy, Elsevier, vol. 191(C), pages 239-250.
    14. Chiu, Justin N.W. & Martin, Viktoria, 2012. "Submerged finned heat exchanger latent heat storage design and its experimental verification," Applied Energy, Elsevier, vol. 93(C), pages 507-516.
    15. Pielichowska, Kinga & Nowak, Michał & Szatkowski, Piotr & Macherzyńska, Beata, 2016. "The influence of chain extender on properties of polyurethane-based phase change materials modified with graphene," Applied Energy, Elsevier, vol. 162(C), pages 1024-1033.
    16. Qian, Yong & Wei, Ping & Jiang, Pingkai & Li, Zhi & Yan, Yonggang & Liu, Jiping, 2013. "Preparation of a novel PEG composite with halogen-free flame retardant supporting matrix for thermal energy storage application," Applied Energy, Elsevier, vol. 106(C), pages 321-327.
    17. Zhou, Guobing & Yang, Yongping & Wang, Xin & Cheng, Jinming, 2010. "Thermal characteristics of shape-stabilized phase change material wallboard with periodical outside temperature waves," Applied Energy, Elsevier, vol. 87(8), pages 2666-2672, August.
    18. Kenisarin, Murat M. & Kenisarina, Kamola M., 2012. "Form-stable phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1999-2040.
    19. Lu, W. & Tassou, S.A., 2013. "Characterization and experimental investigation of phase change materials for chilled food refrigerated cabinet applications," Applied Energy, Elsevier, vol. 112(C), pages 1376-1382.
    20. Li, Hailong & Wang, Weilong & Yan, Jinyue & Dahlquist, Erik, 2013. "Economic assessment of the mobilized thermal energy storage (M-TES) system for distributed heat supply," Applied Energy, Elsevier, vol. 104(C), pages 178-186.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:87:y:2010:i:5:p:1529-1534. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.