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Intervalence plasmons in boron-doped diamond

Author

Listed:
  • Souvik Bhattacharya

    (University of Illinois Urbana-Champaign)

  • Jonathan Boyd

    (Case Western Reserve University)

  • Sven Reichardt

    (University of Luxembourg)

  • Valentin Allard

    (Institut Fresnel)

  • Amir Hossein Talebi

    (University of Luxembourg)

  • Nicolò Maccaferri

    (Umeå University)

  • Olga Shenderova

    (Adamas Nanotechnologies)

  • Aude L. Lereu

    (Institut Fresnel)

  • Ludger Wirtz

    (University of Luxembourg)

  • Giuseppe Strangi

    (Case Western Reserve University
    University of Calabria)

  • R. Mohan Sankaran

    (University of Illinois Urbana-Champaign)

Abstract

Doped semiconductors can exhibit metallic-like properties ranging from superconductivity to tunable localized surface plasmon resonances. Diamond is a wide-bandgap semiconductor that is rendered electronically active by incorporating a hole dopant, boron. While the effects of boron doping on the electronic band structure of diamond are well-studied, any link between charge carriers and plasmons has never been shown. Here, we report intervalence plasmons in boron-doped diamond, defined as collective electronic excitations between the valence subbands, opened up by the presence of holes. Evidence for these low-energy excitations is provided by valence electron energy loss spectroscopy and near-field infrared spectroscopy. The measured spectra are subsequently reproduced by first-principles calculations based on the contribution of intervalence band transitions to the dielectric function. Our calculations also reveal that the real part of the dielectric function exhibits a crossover characteristic of metallicity. These results suggest a new mechanism for inducing plasmon-like behavior in doped semiconductors, and the possibility of attaining such properties in diamond, a key emerging material for quantum information technologies.

Suggested Citation

  • Souvik Bhattacharya & Jonathan Boyd & Sven Reichardt & Valentin Allard & Amir Hossein Talebi & Nicolò Maccaferri & Olga Shenderova & Aude L. Lereu & Ludger Wirtz & Giuseppe Strangi & R. Mohan Sankaran, 2025. "Intervalence plasmons in boron-doped diamond," Nature Communications, Nature, vol. 16(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-024-55353-0
    DOI: 10.1038/s41467-024-55353-0
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    1. Ondrej L. Krivanek & Tracy C. Lovejoy & Niklas Dellby & Toshihiro Aoki & R. W. Carpenter & Peter Rez & Emmanuel Soignard & Jiangtao Zhu & Philip E. Batson & Maureen J. Lagos & Ray F. Egerton & Peter A, 2014. "Vibrational spectroscopy in the electron microscope," Nature, Nature, vol. 514(7521), pages 209-212, October.
    2. T. Yokoya & T. Nakamura & T. Matsushita & T. Muro & Y. Takano & M. Nagao & T. Takenouchi & H. Kawarada & T. Oguchi, 2005. "Origin of the metallic properties of heavily boron-doped superconducting diamond," Nature, Nature, vol. 438(7068), pages 647-650, December.
    3. Ryosuke Senga & Kazu Suenaga & Paolo Barone & Shigeyuki Morishita & Francesco Mauri & Thomas Pichler, 2019. "Position and momentum mapping of vibrations in graphene nanostructures," Nature, Nature, vol. 573(7773), pages 247-250, September.
    4. Jiawei Zhou & Hangtian Zhu & Qichen Song & Zhiwei Ding & Jun Mao & Zhifeng Ren & Gang Chen, 2022. "Mobility enhancement in heavily doped semiconductors via electron cloaking," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Steven C. Erwin & Lijun Zu & Michael I. Haftel & Alexander L. Efros & Thomas A. Kennedy & David J. Norris, 2005. "Doping semiconductor nanocrystals," Nature, Nature, vol. 436(7047), pages 91-94, July.
    6. E. A. Ekimov & V. A. Sidorov & E. D. Bauer & N. N. Mel'nik & N. J. Curro & J. D. Thompson & S. M. Stishov, 2004. "Superconductivity in diamond," Nature, Nature, vol. 428(6982), pages 542-545, April.
    7. Carlo Bradac & Weibo Gao & Jacopo Forneris & Matthew E. Trusheim & Igor Aharonovich, 2019. "Quantum nanophotonics with group IV defects in diamond," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    8. Takahiro Shinada & Shintaro Okamoto & Takahiro Kobayashi & Iwao Ohdomari, 2005. "Enhancing semiconductor device performance using ordered dopant arrays," Nature, Nature, vol. 437(7062), pages 1128-1131, October.
    9. B. E. Kane, 1998. "A silicon-based nuclear spin quantum computer," Nature, Nature, vol. 393(6681), pages 133-137, May.
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