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A highly polarizable concentrated dipole glass for ultrahigh energy storage

Author

Listed:
  • Jian Fu

    (Hefei University of Technology)

  • Aiwen Xie

    (Anhui Polytechnic University)

  • Ruzhong Zuo

    (Hefei University of Technology
    Anhui Polytechnic University)

  • Yiqian Liu

    (Tsinghua University)

  • He Qi

    (University of Science and Technology Beijing)

  • Zongqian Wang

    (Anhui Polytechnic University)

  • Quan Feng

    (Anhui Polytechnic University)

  • Jinming Guo

    (School of Materials Science and Engineering, Hubei University)

  • Kun Zeng

    (Chinese Academy of Sciences)

  • Xuefeng Chen

    (Chinese Academy of Sciences)

  • Zhengqian Fu

    (Chinese Academy of Sciences)

  • Yifan Zhang

    (Hefei University of Technology)

  • Xuewen Jiang

    (Anhui Polytechnic University)

  • Tianyu Li

    (Anhui Polytechnic University)

  • Shujun Zhang

    (University of Wollongong)

  • Yuan-Hua Lin

    (Tsinghua University)

  • Ce-Wen Nan

    (Tsinghua University)

Abstract

Relaxor ferroelectrics are highly desired for pulse-power dielectric capacitors, however it has become a bottleneck that substantial enhancements of energy density generally sacrifice energy efficiency under superhigh fields. Here, we demonstrate a novel concept of highly polarizable concentrated dipole glass in delicately-designed high-entropy (Bi1/3Ba1/3Na1/3)(Fe2/9Ti5/9Nb2/9)O3 ceramic achieved via substitution of multiple heterovalent ferroelectric-active principal cation species on equivalent lattice sites. The atomic-scaled polar heterogeneity of dipoles with different polar vectors between adjacent unit cells enables diffuse reorientation process but disables appreciable growth with electric fields. These unique features cause superior recoverable energy density of ~15.9 J cm−3 and efficiency of ~93.3% in bulk ceramics. We also extend the highly polarizable concentrated dipole glass to the prototype multilayer ceramic capacitor, which exhibits record-breaking recoverable energy density of ~26.3 J cm−3 and efficiency of ~92.4% with excellent temperature and cycle stability. This research presents a distinctive approach for designing high-performance energy-storage dielectric capacitors.

Suggested Citation

  • Jian Fu & Aiwen Xie & Ruzhong Zuo & Yiqian Liu & He Qi & Zongqian Wang & Quan Feng & Jinming Guo & Kun Zeng & Xuefeng Chen & Zhengqian Fu & Yifan Zhang & Xuewen Jiang & Tianyu Li & Shujun Zhang & Yuan, 2024. "A highly polarizable concentrated dipole glass for ultrahigh energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51766-z
    DOI: 10.1038/s41467-024-51766-z
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    References listed on IDEAS

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    1. Bingbing Yang & Qinghua Zhang & Houbing Huang & Hao Pan & Wenxuan Zhu & Fanqi Meng & Shun Lan & Yiqian Liu & Bin Wei & Yiqun Liu & Letao Yang & Lin Gu & Long-Qing Chen & Ce-Wen Nan & Yuan-Hua Lin, 2023. "Engineering relaxors by entropy for high energy storage performance," Nature Energy, Nature, vol. 8(9), pages 956-964, September.
    2. Liang Chen & Shiqing Deng & Hui Liu & Jie Wu & He Qi & Jun Chen, 2022. "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Mao-Hua Zhang & Hui Ding & Sonja Egert & Changhao Zhao & Lorenzo Villa & Lovro Fulanović & Pedro B. Groszewicz & Gerd Buntkowsky & Hans-Joachim Kleebe & Karsten Albe & Andreas Klein & Jurij Koruza, 2023. "Tailoring high-energy storage NaNbO3-based materials from antiferroelectric to relaxor states," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Christina M. Rost & Edward Sachet & Trent Borman & Ali Moballegh & Elizabeth C. Dickey & Dong Hou & Jacob L. Jones & Stefano Curtarolo & Jon-Paul Maria, 2015. "Entropy-stabilized oxides," Nature Communications, Nature, vol. 6(1), pages 1-8, December.
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    Cited by:

    1. Tongxin Wei & Jinzhu Zou & Xuefan Zhou & Miao Song & Yan Zhang & Cewen Nan & Yuanhua Lin & Dou Zhang, 2025. "High-entropy assisted capacitive energy storage in relaxor ferroelectrics by chemical short-range order," Nature Communications, Nature, vol. 16(1), pages 1-11, December.

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