IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37060-4.html
   My bibliography  Save this article

Tailoring high-energy storage NaNbO3-based materials from antiferroelectric to relaxor states

Author

Listed:
  • Mao-Hua Zhang

    (Technical University of Darmstadt
    The Pennsylvania State University)

  • Hui Ding

    (Technical University of Darmstadt)

  • Sonja Egert

    (Technical University of Darmstadt)

  • Changhao Zhao

    (Technical University of Darmstadt)

  • Lorenzo Villa

    (Technical University of Darmstadt)

  • Lovro Fulanović

    (Technical University of Darmstadt)

  • Pedro B. Groszewicz

    (Delft University of Technology)

  • Gerd Buntkowsky

    (Technical University of Darmstadt)

  • Hans-Joachim Kleebe

    (Technical University of Darmstadt)

  • Karsten Albe

    (Technical University of Darmstadt)

  • Andreas Klein

    (Technical University of Darmstadt)

  • Jurij Koruza

    (Technical University of Darmstadt
    Graz University of Technology)

Abstract

Reversible field-induced phase transitions define antiferroelectric perovskite oxides and lay the foundation for high-energy storage density materials, required for future green technologies. However, promising new antiferroelectrics are hampered by transition´s irreversibility and low electrical resistivity. Here, we demonstrate an approach to overcome these problems by adjusting the local structure and defect chemistry, delivering NaNbO3-based antiferroelectrics with well-defined double polarization loops. The attending reversible phase transition and structural changes at different length scales are probed by in situ high-energy X-ray diffraction, total scattering, transmission electron microcopy, and nuclear magnetic resonance spectroscopy. We show that the energy-storage density of the antiferroelectric compositions can be increased by an order of magnitude, while increasing the chemical disorder transforms the material to a relaxor state with a high energy efficiency of 90%. The results provide guidelines for efficient design of (anti-)ferroelectrics and open the way for the development of new material systems for a sustainable future.

Suggested Citation

  • Mao-Hua Zhang & Hui Ding & Sonja Egert & Changhao Zhao & Lorenzo Villa & Lovro Fulanović & Pedro B. Groszewicz & Gerd Buntkowsky & Hans-Joachim Kleebe & Karsten Albe & Andreas Klein & Jurij Koruza, 2023. "Tailoring high-energy storage NaNbO3-based materials from antiferroelectric to relaxor states," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37060-4
    DOI: 10.1038/s41467-023-37060-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37060-4
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-37060-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Hao Pan & Jing Ma & Ji Ma & Qinghua Zhang & Xiaozhi Liu & Bo Guan & Lin Gu & Xin Zhang & Yu-Jun Zhang & Liangliang Li & Yang Shen & Yuan-Hua Lin & Ce-Wen Nan, 2018. "Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Zhengqian Fu & Xuefeng Chen & Zhenqin Li & Tengfei Hu & Linlin Zhang & Ping Lu & Shujun Zhang & Genshui Wang & Xianlin Dong & Fangfang Xu, 2020. "Unveiling the ferrielectric nature of PbZrO3-based antiferroelectric materials," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    3. Nengneng Luo & Kai Han & Matthew J. Cabral & Xiaozhou Liao & Shujun Zhang & Changzhong Liao & Guangzu Zhang & Xiyong Chen & Qin Feng & Jing-Feng Li & Yuezhou Wei, 2020. "Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    4. Bin Xu & Jorge Íñiguez & L. Bellaiche, 2017. "Designing lead-free antiferroelectrics for energy storage," Nature Communications, Nature, vol. 8(1), pages 1-8, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jian Fu & Aiwen Xie & Ruzhong Zuo & Yiqian Liu & He Qi & Zongqian Wang & Quan Feng & Jinming Guo & Kun Zeng & Xuefeng Chen & Zhengqian Fu & Yifan Zhang & Xuewen Jiang & Tianyu Li & Shujun Zhang & Yuan, 2024. "A highly polarizable concentrated dipole glass for ultrahigh energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nengneng Luo & Li Ma & Gengguang Luo & Chao Xu & Lixiang Rao & Zhengu Chen & Zhenyong Cen & Qin Feng & Xiyong Chen & Fujita Toyohisa & Ye Zhu & Jiawang Hong & Jing-Feng Li & Shujun Zhang, 2023. "Well-defined double hysteresis loop in NaNbO3 antiferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Weichen Zhao & Diming Xu & Da Li & Max Avdeev & Hongmei Jing & Mengkang Xu & Yan Guo & Dier Shi & Tao Zhou & Wenfeng Liu & Dong Wang & Di Zhou, 2023. "Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Peng Chen & Charles Paillard & Hong Jian Zhao & Jorge Íñiguez & Laurent Bellaiche, 2022. "Deterministic control of ferroelectric polarization by ultrafast laser pulses," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Li-Feng Zhu & Shiqing Deng & Lei Zhao & Gen Li & Qi Wang & Linhai Li & Yongke Yan & He Qi & Bo-Ping Zhang & Jun Chen & Jing-Feng Li, 2023. "Heterovalent-doping-enabled atom-displacement fluctuation leads to ultrahigh energy-storage density in AgNbO3-based multilayer capacitors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Jianhong Duan & Kun Wei & Qianbiao Du & Linzhao Ma & Huifen Yu & He Qi & Yangchun Tan & Gaokuo Zhong & Hao Li, 2024. "High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    6. Wei Li & Zhong-Hui Shen & Run-Lin Liu & Xiao-Xiao Chen & Meng-Fan Guo & Jin-Ming Guo & Hua Hao & Yang Shen & Han-Xing Liu & Long-Qing Chen & Ce-Wen Nan, 2024. "Generative learning facilitated discovery of high-entropy ceramic dielectrics for capacitive energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. Liang Chen & Shiqing Deng & Hui Liu & Jie Wu & He Qi & Jun Chen, 2022. "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Michael Hoffmann & Zheng Wang & Nujhat Tasneem & Ahmad Zubair & Prasanna Venkatesan Ravindran & Mengkun Tian & Anthony Arthur Gaskell & Dina Triyoso & Steven Consiglio & Kandabara Tapily & Robert Clar, 2022. "Antiferroelectric negative capacitance from a structural phase transition in zirconia," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Wei Luo & Alireza Akbarzadeh & Yousra Nahas & Sergei Prokhorenko & Laurent Bellaiche, 2023. "Quantum criticality at cryogenic melting of polar bubble lattices," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    10. Yunting Guo & Bin Peng & Guangming Lu & Guohua Dong & Guannan Yang & Bohan Chen & Ruibin Qiu & Haixia Liu & Butong Zhang & Yufei Yao & Yanan Zhao & Suzhi Li & Xiangdong Ding & Jun Sun & Ming Liu, 2024. "Remarkable flexibility in freestanding single-crystalline antiferroelectric PbZrO3 membranes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Mengjiao Han & Cong Wang & Kangdi Niu & Qishuo Yang & Chuanshou Wang & Xi Zhang & Junfeng Dai & Yujia Wang & Xiuliang Ma & Junling Wang & Lixing Kang & Wei Ji & Junhao Lin, 2022. "Continuously tunable ferroelectric domain width down to the single-atomic limit in bismuth tellurite," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    12. Kiumars Aryana & John A. Tomko & Ran Gao & Eric R. Hoglund & Takanori Mimura & Sara Makarem & Alejandro Salanova & Md Shafkat Bin Hoque & Thomas W. Pfeifer & David H. Olson & Jeffrey L. Braun & Joyeet, 2022. "Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37060-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.