IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v16y2025i1d10.1038_s41467-025-56605-3.html
   My bibliography  Save this article

Giant energy storage density with ultrahigh efficiency in multilayer ceramic capacitors via interlaminar strain engineering

Author

Listed:
  • Ying Yang

    (Huazhong University of Science and Technology)

  • Ke Xu

    (Beijing Institute of Technology)

  • Bin Yang

    (Hubei University)

  • Xu Hou

    (The Hong Kong Polytechnic University)

  • Zhanming Dou

    (Huazhong University of Science and Technology)

  • Yuhong Li

    (Huazhong University of Science and Technology)

  • Zihao Zheng

    (Hubei University)

  • Gengguang Luo

    (Huazhong University of Science and Technology
    Guangxi University)

  • Nengneng Luo

    (Guangxi University)

  • Guanglong Ge

    (Tongji University)

  • Jiwei Zhai

    (Tongji University)

  • Yuanyuan Fan

    (Beijing Institute of Technology)

  • Jing Wang

    (Beijing Institute of Technology)

  • Haoming Yang

    (Huazhong University of Science and Technology)

  • Yao Zhang

    (Huazhong University of Science and Technology)

  • Jing Wang

    (Hebei University)

  • Changyuan Wang

    (Huazhong University of Science and Technology)

  • Shenglin Jiang

    (Huazhong University of Science and Technology)

  • Kanghua Li

    (Huazhong University of Science and Technology)

  • Jinming Guo

    (Hubei University)

  • Houbing Huang

    (Beijing Institute of Technology)

  • Guangzu Zhang

    (Huazhong University of Science and Technology)

Abstract

Dielectric capacitors with high energy storage performance are highly desired for advanced power electronic devices and systems. Even though strenuous efforts have been dedicated to closing the gap of energy storage density between the dielectric capacitors and the electrochemical capacitors/batteries, a single-minded pursuit of high energy density without a near-zero energy loss for ultrahigh energy efficiency as the grantee is in vain. Herein, for the purpose of decoupling the inherent conflicts between high polarization and low electric hysteresis (loss), and achieving high energy storage density and efficiency simultaneously in multilayer ceramic capacitors (MLCCs), we propose an interlaminar strain engineering strategy to modulate the domain structure and manipulate the polarization behavior of the dielectric mediums. With a heterogeneous layered structure consisting of different antiferroelectric ceramics [(Pb0.9Ba0.04La0.04)(Zr0.65Sn0.3Ti0.05)O3/(Pb0.95Ba0.02La0.02)(Zr0.6Sn0.4)O3/(Pb0.92Ca0.06La0.02)(Zr0.6Sn0.4)0.995O3], our MLCC exhibits a giant recoverable energy density of 22.0 J cm−3 with an ultrahigh energy efficiency of 96.1%. Combined with the favorable temperature and frequency stabilities and the high antifatigue property, this work provides a strain engineering paradigm for designing MLCCs for high-power energy storage and conversion systems.

Suggested Citation

  • Ying Yang & Ke Xu & Bin Yang & Xu Hou & Zhanming Dou & Yuhong Li & Zihao Zheng & Gengguang Luo & Nengneng Luo & Guanglong Ge & Jiwei Zhai & Yuanyuan Fan & Jing Wang & Haoming Yang & Yao Zhang & Jing W, 2025. "Giant energy storage density with ultrahigh efficiency in multilayer ceramic capacitors via interlaminar strain engineering," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-56605-3
    DOI: 10.1038/s41467-025-56605-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-025-56605-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-025-56605-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Qi Li & Lei Chen & Matthew R. Gadinski & Shihai Zhang & Guangzu Zhang & Haoyu U. Li & Elissei Iagodkine & Aman Haque & Long-Qing Chen & Thomas N. Jackson & Qing Wang, 2015. "Flexible high-temperature dielectric materials from polymer nanocomposites," Nature, Nature, vol. 523(7562), pages 576-579, July.
    2. Nengneng Luo & Kai Han & Matthew J. Cabral & Xiaozhou Liao & Shujun Zhang & Changzhong Liao & Guangzu Zhang & Xiyong Chen & Qin Feng & Jing-Feng Li & Yuezhou Wei, 2020. "Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    3. Liang Chen & Shiqing Deng & Hui Liu & Jie Wu & He Qi & Jun Chen, 2022. "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Weichen Zhao & Diming Xu & Da Li & Max Avdeev & Hongmei Jing & Mengkang Xu & Yan Guo & Dier Shi & Tao Zhou & Wenfeng Liu & Dong Wang & Di Zhou, 2023. "Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Jianhong Duan & Kun Wei & Qianbiao Du & Linzhao Ma & Huifen Yu & He Qi & Yangchun Tan & Gaokuo Zhong & Hao Li, 2024. "High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Yongxiao Zhou & Tianfu Zhang & Liang Chen & Huifen Yu & Ruiyu Wang & Hao Zhang & Jie Wu & Shiqing Deng & He Qi & Chang Zhou & Jun Chen, 2025. "Design of antiferroelectric polarization configuration for ultrahigh capacitive energy storage via increasing entropy," Nature Communications, Nature, vol. 16(1), pages 1-8, December.
    4. Rishi Gurnani & Stuti Shukla & Deepak Kamal & Chao Wu & Jing Hao & Christopher Kuenneth & Pritish Aklujkar & Ashish Khomane & Robert Daniels & Ajinkya A. Deshmukh & Yang Cao & Gregory Sotzing & Rampi , 2024. "AI-assisted discovery of high-temperature dielectrics for energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Xi Kong & Letao Yang & Fanqi Meng & Tao Zhang & Hejin Zhang & Yuan-Hua Lin & Houbing Huang & Shujun Zhang & Jinming Guo & Ce-Wen Nan, 2025. "High-entropy engineered BaTiO3-based ceramic capacitors with greatly enhanced high-temperature energy storage performance," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    6. Xinhui Li & Shan He & Yanda Jiang & Jian Wang & Yi Yu & Xiaofei Liu & Feng Zhu & Yimei Xie & Youyong Li & Cheng Ma & Zhonghui Shen & Baowen Li & Yang Shen & Xin Zhang & Shujun Zhang & Ce-Wen Nan, 2023. "Unraveling bilayer interfacial features and their effects in polar polymer nanocomposites," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Nengneng Luo & Li Ma & Gengguang Luo & Chao Xu & Lixiang Rao & Zhengu Chen & Zhenyong Cen & Qin Feng & Xiyong Chen & Fujita Toyohisa & Ye Zhu & Jiawang Hong & Jing-Feng Li & Shujun Zhang, 2023. "Well-defined double hysteresis loop in NaNbO3 antiferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Yi, Juan & Ye, Zhiwei & Zhang, Shixian & Song, Yiheng & Cao, Zhilong & Liu, Bin & Li, Chenjian & Liu, Shuang & Nie, Shuai & Xiong, Chuanxi, 2024. "Corona: An effective polarization strategy of polymer composites with high-k filler for piezoelectric nanogenerators," Applied Energy, Elsevier, vol. 353(PA).
    9. Jinfeng Lin & Jin Qian & Guanglong Ge & Yuxuan Yang & Jiangfan Li & Xiao Wu & Guohui Li & Simin Wang & Yingchun Liu & Jialiang Zhang & Jiwei Zhai & Xiaoming Shi & Haijun Wu, 2024. "Multiscale reconfiguration induced highly saturated poling in lead-free piezoceramics for giant energy conversion," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    10. Minzheng Yang & Weibin Ren & Zenghui Jin & Erxiang Xu & Yang Shen, 2024. "Enhanced high-temperature energy storage performances in polymer dielectrics by synergistically optimizing band-gap and polarization of dipolar glass," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    11. Zilong Xie & Jianan Zhu & Zhengli Dou & Yongzheng Zhang & Ke Wang & Kai Wu & Qiang Fu, 2024. "Liquid metal interface mechanochemistry disentangles energy density and biaxial stretchability tradeoff in composite capacitor film," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Rui Lu & Jian Wang & Tingzhi Duan & Tian-Yi Hu & Guangliang Hu & Yupeng Liu & Weijie Fu & Qiuyang Han & Yiqin Lu & Lu Lu & Shao-Dong Cheng & Yanzhu Dai & Dengwei Hu & Zhonghui Shen & Chun-Lin Jia & Ch, 2024. "Metadielectrics for high-temperature energy storage capacitors," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    13. Rui Wang & Yujie Zhu & Jing Fu & Mingcong Yang & Zhaoyu Ran & Junluo Li & Manxi Li & Jun Hu & Jinliang He & Qi Li, 2023. "Designing tailored combinations of structural units in polymer dielectrics for high-temperature capacitive energy storage," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    14. Liang Zhao & Lingyi Bi & Jiayue Hu & Guanhui Gao & Danzhen Zhang & Yun Li & Aidan Flynn & Teng Zhang & Ruocun Wang & Xuemei M. Cheng & Ling Liu & Yury Gogotsi & Bo Li, 2024. "Universal salt-assisted assembly of MXene from suspension on polymer substrates," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    15. Li-Feng Zhu & Shiqing Deng & Lei Zhao & Gen Li & Qi Wang & Linhai Li & Yongke Yan & He Qi & Bo-Ping Zhang & Jun Chen & Jing-Feng Li, 2023. "Heterovalent-doping-enabled atom-displacement fluctuation leads to ultrahigh energy-storage density in AgNbO3-based multilayer capacitors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    16. Mejia, Cristian & Kajikawa, Yuya, 2020. "Emerging topics in energy storage based on a large-scale analysis of academic articles and patents," Applied Energy, Elsevier, vol. 263(C).
    17. Huifen Yu & Tengfei Hu & Haoyu Wang & He Qi & Jie Wu & Ruonan Zhang & Weisan Fang & Xiaoming Shi & Zhengqian Fu & Liang Chen & Jun Chen, 2025. "Design of polymorphic heterogeneous shell in relaxor antiferroelectrics for ultrahigh capacitive energy storage," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    18. Jiaming Liu & Ying Jiang & Weichen Zhang & Xu Cheng & Peiyao Zhao & Yichao Zhen & Yanan Hao & Limin Guo & Ke Bi & Xiaohui Wang, 2024. "Ferroelectric tungsten bronze-based ceramics with high-energy storage performance via weakly coupled relaxor design and grain boundary optimization," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    19. Da Li & Zhaobo Liu & Weichen Zhao & Yan Guo & Zhentao Wang & Diming Xu & Houbing Huang & Li-Xia Pang & Tao Zhou & Wen-Feng Liu & Di Zhou, 2025. "Global-optimized energy storage performance in multilayer ferroelectric ceramic capacitors," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    20. Mao-Hua Zhang & Hui Ding & Sonja Egert & Changhao Zhao & Lorenzo Villa & Lovro Fulanović & Pedro B. Groszewicz & Gerd Buntkowsky & Hans-Joachim Kleebe & Karsten Albe & Andreas Klein & Jurij Koruza, 2023. "Tailoring high-energy storage NaNbO3-based materials from antiferroelectric to relaxor states," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-56605-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.