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Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics

Author

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  • Huaxiang Fu

    (Carnegie Institution of Washington)

  • Ronald E. Cohen

    (Carnegie Institution of Washington)

Abstract

Piezoelectric materials, which convert mechanical to electrical energy (and vice versa), are crucial in medical imaging, telecommunication and ultrasonic devices1,2. A new generation of single-crystal materials3, such as Pb(Zn1/3Nb2/3)O3–PbTiO3 (PZN–PT) and Pb(Mg1/3Nb2/3)O3–PbTiO3 (PMN–PT), exhibit a piezoelectric effect that is ten times larger than conventional ceramics, and may revolutionize4 these applications. However, the mechanism underlying the ultrahigh performance of these new materials—and consequently the possibilities for further improvements—are not at present clear. Here we report a first-principles study of the ferroelectric perovskite, BaTiO3, which is similar5 to single-crystal PZN–PT but is a simpler system to analyse. We show that a large piezoelectric response can be driven by polarization rotation induced by an external electric field. Our computations suggest how to design materials with better performance, and may stimulate further interest in the fundamental theory of dielectric systems in finite electric fields.

Suggested Citation

  • Huaxiang Fu & Ronald E. Cohen, 2000. "Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics," Nature, Nature, vol. 403(6767), pages 281-283, January.
    • Handle: RePEc:nat:nature:v:403:y:2000:i:6767:d:10.1038_35002022
    DOI: 10.1038/35002022
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    Cited by:

    1. Jian Fu & Aiwen Xie & Ruzhong Zuo & Yiqian Liu & He Qi & Zongqian Wang & Quan Feng & Jinming Guo & Kun Zeng & Xuefeng Chen & Zhengqian Fu & Yifan Zhang & Xuewen Jiang & Tianyu Li & Shujun Zhang & Yuan, 2024. "A highly polarizable concentrated dipole glass for ultrahigh energy storage," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Fangping Zhuo & Xiandong Zhou & Shuang Gao & Marion Höfling & Felix Dietrich & Pedro B. Groszewicz & Lovro Fulanović & Patrick Breckner & Andreas Wohninsland & Bai-Xiang Xu & Hans-Joachim Kleebe & Xia, 2022. "Anisotropic dislocation-domain wall interactions in ferroelectrics," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Moaz Waqar & Haijun Wu & Khuong Phuong Ong & Huajun Liu & Changjian Li & Ping Yang & Wenjie Zang & Weng Heng Liew & Caozheng Diao & Shibo Xi & David J. Singh & Qian He & Kui Yao & Stephen J. Pennycook, 2022. "Origin of giant electric-field-induced strain in faulted alkali niobate films," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Mao-Hua Zhang & Chen Shen & Changhao Zhao & Mian Dai & Fang-Zhou Yao & Bo Wu & Jian Ma & Hu Nan & Dawei Wang & Qibin Yuan & Lucas Lemos Silva & Lovro Fulanović & Alexander Schökel & Peitao Liu & Hongb, 2022. "Deciphering the phase transition-induced ultrahigh piezoresponse in (K,Na)NbO3-based piezoceramics," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Ke Zhang & Pan Gao & Chang Liu & Xin Chen & Xinye Huang & Yongping Pu & Zenghui Liu, 2022. "Structural Evolution and Enhanced Piezoelectric Activity in Novel Lead-Free BaTiO 3 -Ca(Sn 1/2 Zr 1/2 )O 3 Solid Solutions," Energies, MDPI, vol. 15(20), pages 1-11, October.
    6. Liya Yang & Houbing Huang & Zengzhe Xi & Limei Zheng & Shiqi Xu & Gang Tian & Yuzhi Zhai & Feifei Guo & Lingping Kong & Yonggang Wang & Weiming Lü & Long Yuan & Minglei Zhao & Haiwu Zheng & Gang Liu, 2022. "Simultaneously achieving giant piezoelectricity and record coercive field enhancement in relaxor-based ferroelectric crystals," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    7. Hui Liu & Xiaoming Shi & Yonghao Yao & Huajie Luo & Qiang Li & Houbing Huang & He Qi & Yuanpeng Zhang & Yang Ren & Shelly D. Kelly & Krystian Roleder & Joerg C. Neuefeind & Long-Qing Chen & Xianran Xi, 2023. "Emergence of high piezoelectricity from competing local polar order-disorder in relaxor ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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