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Polymorphic relaxor phase and defect dipole polarization co-reinforced capacitor energy storage in temperature-monitorable high-entropy ferroelectrics

Author

Listed:
  • Xiangfu Zeng

    (Fuzhou University)

  • Jinfeng Lin

    (Fujian Normal University and Strait Laboratory of Flexible Electronics (SLoFE)
    Tongji University)

  • Gaolei Dong

    (Fuzhou University)

  • Jie Shen

    (Fuzhou University)

  • Luomeng Tang

    (Tongji University)

  • Qifa Lin

    (Fuzhou University)

  • Simin Wang

    (Tongji University)

  • Min Gao

    (Fuzhou University)

  • Chunlin Zhao

    (Fuzhou University)

  • Tengfei Lin

    (Fuzhou University)

  • Laihui Luo

    (Ningbo University)

  • Chao Chen

    (Jingdezhen Ceramic University)

  • Baisheng Sa

    (Fuzhou University)

  • Cong Lin

    (Fuzhou University)

  • Xiao Wu

    (Fuzhou University)

  • Jiwei Zhai

    (Tongji University)

Abstract

Energy storage high-entropy ceramics are famous for their ultrahigh power density and ultrafast discharge rate. However, achieving a synchronous combination of high energy density and efficiency along with intelligent temperature-monitorable function remains a significant challenge. Here, based on high-entropy strategy and phase field simulation, the polarization response of domains in Bi0.5Na0.5TiO3-based ceramics is optimized by constructing a concomitant nanostructure of defect dipole polarization and a polymorphic relaxor phase. The optimal ceramic possesses a high recyclable energy storage density (11.23 J cm−3) and a high energy storage efficiency (90.87%) at 670 kV cm−1. Furthermore, real-time temperature sensing is explored based on abnormal fluorescent negative thermal expansion, highlighting the application of intelligent cardiac defibrillation pulse capacitors. This study develops an effective strategy for enhancing the overall energy storage performance of ferroelectric ceramics to overcome the problems of insufficient energy supply and thermal runaway in traditional counterparts.

Suggested Citation

  • Xiangfu Zeng & Jinfeng Lin & Gaolei Dong & Jie Shen & Luomeng Tang & Qifa Lin & Simin Wang & Min Gao & Chunlin Zhao & Tengfei Lin & Laihui Luo & Chao Chen & Baisheng Sa & Cong Lin & Xiao Wu & Jiwei Zh, 2025. "Polymorphic relaxor phase and defect dipole polarization co-reinforced capacitor energy storage in temperature-monitorable high-entropy ferroelectrics," Nature Communications, Nature, vol. 16(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-57139-4
    DOI: 10.1038/s41467-025-57139-4
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    References listed on IDEAS

    as
    1. Xuefan Zhou & Jun Zhang & Hang Luo & Yan Zhang & Shiyu Tang & Houbing Huang & Xi Yuan & Miao Song & He Qi & Dou Zhang, 2024. "Lead-free ferroelectrics with giant unipolar strain for high-precision actuators," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Bingbing Yang & Qinghua Zhang & Houbing Huang & Hao Pan & Wenxuan Zhu & Fanqi Meng & Shun Lan & Yiqian Liu & Bin Wei & Yiqun Liu & Letao Yang & Lin Gu & Long-Qing Chen & Ce-Wen Nan & Yuan-Hua Lin, 2023. "Engineering relaxors by entropy for high energy storage performance," Nature Energy, Nature, vol. 8(9), pages 956-964, September.
    3. Liang Chen & Shiqing Deng & Hui Liu & Jie Wu & He Qi & Jun Chen, 2022. "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Jianhong Duan & Kun Wei & Qianbiao Du & Linzhao Ma & Huifen Yu & He Qi & Yangchun Tan & Gaokuo Zhong & Hao Li, 2024. "High-entropy superparaelectrics with locally diverse ferroic distortion for high-capacitive energy storage," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    5. Weichen Zhao & Diming Xu & Da Li & Max Avdeev & Hongmei Jing & Mengkang Xu & Yan Guo & Dier Shi & Tao Zhou & Wenfeng Liu & Dong Wang & Di Zhou, 2023. "Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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