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Two-dimensional single-crystalline mesoporous high-entropy oxide nanoplates for efficient electrochemical biomass upgrading

Author

Listed:
  • Yanzhi Wang

    (Sichuan University)

  • Hangjuan He

    (Sichuan University)

  • Hao Lv

    (Sichuan University
    Shanghai Jiao Tong University)

  • Fengrui Jia

    (Sichuan University)

  • Ben Liu

    (Sichuan University)

Abstract

Mesoporous single crystals have received more attention than ever in catalysis-related applications due to their unique structural functions. Despite great efforts, their progress in engineering crystallinity and composition has been remarkably slower than expected. In this manuscript, a template-free strategy is developed to prepare two-dimensional high-entropy oxide (HEO) nanoplates with single-crystallinity and penetrated mesoporosity, which further ensures precise control over high-entropy compositions and crystalline phases. Single-crystalline mesoporous HEOs (SC-MHEOs) disclose high electrocatalytic performance in 5-hydroxymethylfurfural oxidation reaction (HMFOR) for efficient biomass upgrading, with remarkable HMF conversion of 99.3% and superior 2,5-furandicarboxylic acid (FDCA) selectivity of 97.7%. Moreover, with nitrate reduction as coupling cathode reaction, SC-MHEO realizes concurrent electrosynthesis of value-added FDCA and ammonia in the two-electrode cell. Our study provides a powerful paradigm for producing a library of novel mesoporous single crystals for important catalysis-related applications, especially in the two-electrode cell.

Suggested Citation

  • Yanzhi Wang & Hangjuan He & Hao Lv & Fengrui Jia & Ben Liu, 2024. "Two-dimensional single-crystalline mesoporous high-entropy oxide nanoplates for efficient electrochemical biomass upgrading," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50721-2
    DOI: 10.1038/s41467-024-50721-2
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    References listed on IDEAS

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