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Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping

Author

Listed:
  • Yiming Zhu

    (Tongji University)

  • Malte Klingenhof

    (Technische Universität Berlin, Department of Chemistry)

  • Chenlong Gao

    (Tongji University)

  • Toshinari Koketsu

    (Technische Universität Berlin, Department of Chemistry)

  • Gregor Weiser

    (Technische Universität Berlin, Department of Chemistry)

  • Yecan Pi

    (Yangzhou University)

  • Shangheng Liu

    (Xiamen University)

  • Lijun Sui

    (Tongji University)

  • Jingrong Hou

    (Tongji University)

  • Jiayi Li

    (Tongji University)

  • Haomin Jiang

    (Baoshan Iron & Steel Co., Ltd.
    State Key Laboratory of Development and Application Technology of Automotive Steels, Baosteel)

  • Limin Xu

    (Baoshan Iron & Steel Co., Ltd.
    Shanghai Engineering Research Center of Metals for Lightweight Transportation)

  • Wei-Hsiang Huang

    (National Synchrotron Radiation Research Center)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Menghao Yang

    (Tongji University)

  • Zhiwei Hu

    (Max Planck Institute for Chemical Physics of Solids)

  • Peter Strasser

    (Technische Universität Berlin, Department of Chemistry)

  • Jiwei Ma

    (Tongji University)

Abstract

Exploring an active and cost-effective electrocatalyst alternative to carbon-supported platinum nanoparticles for alkaline hydrogen evolution reaction (HER) have remained elusive to date. Here, we report a catalyst based on platinum single atoms (SAs) doped into the hetero-interfaced Ru/RuO2 support (referred to as Pt-Ru/RuO2), which features a low HER overpotential, an excellent stability and a distinctly enhanced cost-based activity compared to commercial Pt/C and Ru/C in 1 M KOH. Advanced physico-chemical characterizations disclose that the sluggish water dissociation is accelerated by RuO2 while Pt SAs and the metallic Ru facilitate the subsequent H* combination. Theoretical calculations correlate with the experimental findings. Furthermore, Pt-Ru/RuO2 only requires 1.90 V to reach 1 A cm−2 and delivers a high price activity in the anion exchange membrane water electrolyzer, outperforming the benchmark Pt/C. This research offers a feasible guidance for developing the noble metal-based catalysts with high performance and low cost toward practical H2 production.

Suggested Citation

  • Yiming Zhu & Malte Klingenhof & Chenlong Gao & Toshinari Koketsu & Gregor Weiser & Yecan Pi & Shangheng Liu & Lijun Sui & Jingrong Hou & Jiayi Li & Haomin Jiang & Limin Xu & Wei-Hsiang Huang & Chih-We, 2024. "Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45654-9
    DOI: 10.1038/s41467-024-45654-9
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