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Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction

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  • Tianyu Zhang

    (Beijing University of Chemical Technology
    National University of Singapore)

  • Jing Jin

    (Beijing University of Chemical Technology
    Chinese Academy of Sciences Institution)

  • Junmei Chen

    (National University of Singapore)

  • Yingyan Fang

    (Beijing University of Chemical Technology)

  • Xu Han

    (Beijing University of Chemical Technology)

  • Jiayi Chen

    (National University of Singapore)

  • Yaping Li

    (Beijing University of Chemical Technology)

  • Yu Wang

    (Chinese Academy of Sciences)

  • Junfeng Liu

    (Beijing University of Chemical Technology)

  • Lei Wang

    (National University of Singapore)

Abstract

Developing active single-atom-catalyst (SAC) for alkaline hydrogen evolution reaction (HER) is a promising solution to lower the green hydrogen cost. However, the correlations are not clear between the chemical environments around the active-sites and their desired catalytic activity. Here we study a group of SACs prepared by anchoring platinum atoms on NiFe-layered-double-hydroxide. While maintaining the homogeneity of the Pt-SACs, various axial ligands (−F, −Cl, −Br, −I, −OH) are employed via a facile irradiation-impregnation procedure, enabling us to discover definite chemical-environments/performance correlations. Owing to its high first-electron-affinity, chloride chelated Pt-SAC exhibits optimized bindings with hydrogen and hydroxide, which favor the sluggish water dissociation and further promote the alkaline HER. Specifically, it shows high mass-activity of 30.6 A mgPt−1 and turnover frequency of 30.3 H2 s−1 at 100 mV overpotential, which are significantly higher than those of the state-of-the-art Pt-SACs and commercial Pt/C catalyst. Moreover, high energy efficiency of 80% is obtained for the alkaline water electrolyser assembled using the above catalyst under practical-relevant conditions.

Suggested Citation

  • Tianyu Zhang & Jing Jin & Junmei Chen & Yingyan Fang & Xu Han & Jiayi Chen & Yaping Li & Yu Wang & Junfeng Liu & Lei Wang, 2022. "Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34619-5
    DOI: 10.1038/s41467-022-34619-5
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