IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-51370-1.html
   My bibliography  Save this article

Bimetallic nanoalloys planted on super-hydrophilic carbon nanocages featuring tip-intensified hydrogen evolution electrocatalysis

Author

Listed:
  • Linjie Zhang

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Haihui Hu

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Chen Sun

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Dongdong Xiao

    (Institute of Physics, Chinese Academy of Sciences)

  • Hsiao-Tsu Wang

    (Tamkang University)

  • Yi Xiao

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Shuwen Zhao

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Kuan Hung Chen

    (Tamkang University)

  • Wei-Xuan Lin

    (Tamkang University)

  • Yu-Cheng Shao

    (National Synchrotron Radiation Research Center)

  • Xiuyun Wang

    (Fuzhou University)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Lili Han

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

Abstract

The insufficient availability and activity of interfacial water remain a major challenge for alkaline hydrogen evolution reaction (HER). Here, we propose an “on-site disruption and near-site compensation” strategy to reform the interfacial water hydrogen bonding network via deliberate cation penetration and catalyst support engineering. This concept is validated using tip-like bimetallic RuNi nanoalloys planted on super-hydrophilic and high-curvature carbon nanocages (RuNi/NC). Theoretical simulations suggest that tip-induced localized concentration of hydrated K+ facilitates optimization of interfacial water dynamics and intermediate adsorption. In situ synchrotron X-ray spectroscopy endorses an H* spillover-bridged Volmer‒Tafel mechanism synergistically relayed between Ru and Ni. Consequently, RuNi/NC exhibits low overpotential of 12 mV and high durability of 1600 h at 10 mA cm‒2 for alkaline HER, and demonstrates high performance in both water electrolysis and chlor-alkali electrolysis. This strategy offers a microscopic perspective on catalyst design for manipulation of the local interfacial water structure toward enhanced HER kinetics.

Suggested Citation

  • Linjie Zhang & Haihui Hu & Chen Sun & Dongdong Xiao & Hsiao-Tsu Wang & Yi Xiao & Shuwen Zhao & Kuan Hung Chen & Wei-Xuan Lin & Yu-Cheng Shao & Xiuyun Wang & Chih-Wen Pao & Lili Han, 2024. "Bimetallic nanoalloys planted on super-hydrophilic carbon nanocages featuring tip-intensified hydrogen evolution electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51370-1
    DOI: 10.1038/s41467-024-51370-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-51370-1
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-51370-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jiaxi Zhang & Longhai Zhang & Jiamin Liu & Chengzhi Zhong & Yuanhua Tu & Peng Li & Li Du & Shengli Chen & Zhiming Cui, 2022. "OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Ian T. McCrum & Marc T. M. Koper, 2020. "The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum," Nature Energy, Nature, vol. 5(11), pages 891-899, November.
    3. Wei Liu & Haisong Feng & Yusen Yang & Yiming Niu & Lei Wang & Pan Yin & Song Hong & Bingsen Zhang & Xin Zhang & Min Wei, 2022. "Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Yong Zuo & Sebastiano Bellani & Michele Ferri & Gabriele Saleh & Dipak V. Shinde & Marilena Isabella Zappia & Rosaria Brescia & Mirko Prato & Luca Trizio & Ivan Infante & Francesco Bonaccorso & Libera, 2023. "High-performance alkaline water electrolyzers based on Ru-perturbed Cu nanoplatelets cathode," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    5. Yunqing Kang & Ovidiu Cretu & Jun Kikkawa & Koji Kimoto & Hiroki Nara & Asep Sugih Nugraha & Hiroki Kawamoto & Miharu Eguchi & Ting Liao & Ziqi Sun & Toru Asahi & Yusuke Yamauchi, 2023. "Publisher Correction: Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites," Nature Communications, Nature, vol. 14(1), pages 1-1, December.
    6. Xu Zhang & Hui Su & Peixin Cui & Yongyong Cao & Zhenyuan Teng & Qitao Zhang & Yang Wang & Yibo Feng & Ran Feng & Jixiang Hou & Xiyuan Zhou & Peijie Ma & Hanwen Hu & Kaiwen Wang & Cong Wang & Liyong Ga, 2023. "Developing Ni single-atom sites in carbon nitride for efficient photocatalytic H2O2 production," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    7. Min Liu & Yuanjie Pang & Bo Zhang & Phil De Luna & Oleksandr Voznyy & Jixian Xu & Xueli Zheng & Cao Thang Dinh & Fengjia Fan & Changhong Cao & F. Pelayo García de Arquer & Tina Saberi Safaei & Adam Me, 2016. "Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration," Nature, Nature, vol. 537(7620), pages 382-386, September.
    8. Kaian Sun & Xueyan Wu & Zewen Zhuang & Leyu Liu & Jinjie Fang & Lingyou Zeng & Junguo Ma & Shoujie Liu & Jiazhan Li & Ruoyun Dai & Xin Tan & Ke Yu & Di Liu & Weng-Chon Cheong & Aijian Huang & Yunqi Li, 2022. "Interfacial water engineering boosts neutral water reduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    9. Yunqing Kang & Ovidiu Cretu & Jun Kikkawa & Koji Kimoto & Hiroki Nara & Asep Sugih Nugraha & Hiroki Kawamoto & Miharu Eguchi & Ting Liao & Ziqi Sun & Toru Asahi & Yusuke Yamauchi, 2023. "Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Qilun Wang & Cong-Qiao Xu & Wei Liu & Sung-Fu Hung & Hong Yang & Jiajian Gao & Weizheng Cai & Hao Ming Chen & Jun Li & Bin Liu, 2020. "Coordination engineering of iridium nanocluster bifunctional electrocatalyst for highly efficient and pH-universal overall water splitting," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    11. Xing Chen & Xiao-Ting Wang & Jia-Bo Le & Shu-Min Li & Xue Wang & Yu-Jin Zhang & Petar Radjenovic & Yu Zhao & Yao-Hui Wang & Xiu-Mei Lin & Jin-Chao Dong & Jian-Feng Li, 2023. "Revealing the role of interfacial water and key intermediates at ruthenium surfaces in the alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    12. Zhi Wen Chen & Jian Li & Pengfei Ou & Jianan Erick Huang & Zi Wen & LiXin Chen & Xue Yao & GuangMing Cai & Chun Cheng Yang & Chandra Veer Singh & Qing Jiang, 2024. "Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    13. Qiang Sun & Nicholas J. Oliveira & Soonho Kwon & Sergiy Tyukhtenko & Jason J. Guo & Nathalie Myrthil & Steven A. Lopez & Ian Kendrick & Sanjeev Mukerjee & Lu Ma & Steven N. Ehrlich & Jingkun Li & Will, 2023. "Understanding hydrogen electrocatalysis by probing the hydrogen-bond network of water at the electrified Pt–solution interface," Nature Energy, Nature, vol. 8(8), pages 859-869, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tao Zhang & Qitong Ye & Zengyu Han & Qingyi Liu & Yipu Liu & Dongshuang Wu & Hong Jin Fan, 2024. "Biaxial strain induced OH engineer for accelerating alkaline hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Rui Yao & Kaian Sun & Kaiyang Zhang & Yun Wu & Yujie Du & Qiang Zhao & Guang Liu & Chen Chen & Yuhan Sun & Jinping Li, 2024. "Stable hydrogen evolution reaction at high current densities via designing the Ni single atoms and Ru nanoparticles linked by carbon bridges," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    3. Yiming Zhu & Malte Klingenhof & Chenlong Gao & Toshinari Koketsu & Gregor Weiser & Yecan Pi & Shangheng Liu & Lijun Sui & Jingrong Hou & Jiayi Li & Haomin Jiang & Limin Xu & Wei-Hsiang Huang & Chih-We, 2024. "Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    4. Jinjie Fang & Haiyong Wang & Qian Dang & Hao Wang & Xingdong Wang & Jiajing Pei & Zhiyuan Xu & Chengjin Chen & Wei Zhu & Hui Li & Yushan Yan & Zhongbin Zhuang, 2024. "Atomically dispersed Iridium on Mo2C as an efficient and stable alkaline hydrogen oxidation reaction catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Hao Shi & Tanyuan Wang & Jianyun Liu & Weiwei Chen & Shenzhou Li & Jiashun Liang & Shuxia Liu & Xuan Liu & Zhao Cai & Chao Wang & Dong Su & Yunhui Huang & Lior Elbaz & Qing Li, 2023. "A sodium-ion-conducted asymmetric electrolyzer to lower the operation voltage for direct seawater electrolysis," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Yong-Qing Yan & Ya Chen & Zhao Wang & Li-Hua Chen & Hao-Lin Tang & Bao-Lian Su, 2023. "Electrochemistry-assisted selective butadiene hydrogenation with water," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    7. Ruixin Yang & Yanming Cai & Yongbing Qi & Zhuodong Tang & Jun-Jie Zhu & Jinxiang Li & Wenlei Zhu & Zixuan Chen, 2024. "How local electric field regulates C–C coupling at a single nanocavity in electrocatalytic CO2 reduction," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Yicui Kang & Simão M. João & Rui Lin & Kang Liu & Li Zhu & Junwei Fu & Weng-Chon (Max) Cheong & Seunghoon Lee & Kilian Frank & Bert Nickel & Min Liu & Johannes Lischner & Emiliano Cortés, 2024. "Effect of crystal facets in plasmonic catalysis," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    9. Yunqing Kang & Ovidiu Cretu & Jun Kikkawa & Koji Kimoto & Hiroki Nara & Asep Sugih Nugraha & Hiroki Kawamoto & Miharu Eguchi & Ting Liao & Ziqi Sun & Toru Asahi & Yusuke Yamauchi, 2023. "Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Jiaxi Zhang & Longhai Zhang & Jiamin Liu & Chengzhi Zhong & Yuanhua Tu & Peng Li & Li Du & Shengli Chen & Zhiming Cui, 2022. "OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    11. Jia Zhao & Ricardo Urrego-Ortiz & Nan Liao & Federico Calle-Vallejo & Jingshan Luo, 2024. "Rationally designed Ru catalysts supported on TiN for highly efficient and stable hydrogen evolution in alkaline conditions," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    12. Xiaowei Shi & Chao Dai & Xin Wang & Jiayue Hu & Junying Zhang & Lingxia Zheng & Liang Mao & Huajun Zheng & Mingshan Zhu, 2022. "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Jie Xu & Xiong-Xiong Xue & Gonglei Shao & Changfei Jing & Sheng Dai & Kun He & Peipei Jia & Shun Wang & Yifei Yuan & Jun Luo & Jun Lu, 2023. "Atomic-level polarization in electric fields of defects for electrocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    14. Qiqi Mao & Xu Mu & Wenxin Wang & Kai Deng & Hongjie Yu & Ziqiang Wang & You Xu & Liang Wang & Hongjing Wang, 2023. "Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    15. Qi Huang & Baokai Xia & Ming Li & Hongxin Guan & Markus Antonietti & Sheng Chen, 2024. "Single-zinc vacancy unlocks high-rate H2O2 electrosynthesis from mixed dioxygen beyond Le Chatelier principle," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    16. Ye Tian & Botao Huang & Yizhi Song & Yirui Zhang & Dong Guan & Jiani Hong & Duanyun Cao & Enge Wang & Limei Xu & Yang Shao-Horn & Ying Jiang, 2024. "Effect of ion-specific water structures at metal surfaces on hydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    17. Qiyou Wang & Kang Liu & Kangman Hu & Chao Cai & Huangjingwei Li & Hongmei Li & Matias Herran & Ying-Rui Lu & Ting-Shan Chan & Chao Ma & Junwei Fu & Shiguo Zhang & Ying Liang & Emiliano Cortés & Min Li, 2022. "Attenuating metal-substrate conjugation in atomically dispersed nickel catalysts for electroreduction of CO2 to CO," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    18. Chenhui Zhou & Jia Shi & Zhaoqi Dong & Lingyou Zeng & Yan Chen & Ying Han & Lu Li & Wenyu Zhang & Qinghua Zhang & Lin Gu & Fan Lv & Mingchuan Luo & Shaojun Guo, 2024. "Oxophilic gallium single atoms bridged ruthenium clusters for practical anion-exchange membrane electrolyzer," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    19. Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    20. Meng He & Rui Li & Chuanqi Cheng & Cuibo Liu & Bin Zhang, 2024. "Microenvironment regulation breaks the Faradaic efficiency-current density trade-off for electrocatalytic deuteration using D2O," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51370-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.