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Bimetallic nanoalloys planted on super-hydrophilic carbon nanocages featuring tip-intensified hydrogen evolution electrocatalysis

Author

Listed:
  • Linjie Zhang

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Haihui Hu

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Chen Sun

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Dongdong Xiao

    (Institute of Physics, Chinese Academy of Sciences)

  • Hsiao-Tsu Wang

    (Tamkang University)

  • Yi Xiao

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Shuwen Zhao

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Kuan Hung Chen

    (Tamkang University)

  • Wei-Xuan Lin

    (Tamkang University)

  • Yu-Cheng Shao

    (National Synchrotron Radiation Research Center)

  • Xiuyun Wang

    (Fuzhou University)

  • Chih-Wen Pao

    (National Synchrotron Radiation Research Center)

  • Lili Han

    (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

Abstract

The insufficient availability and activity of interfacial water remain a major challenge for alkaline hydrogen evolution reaction (HER). Here, we propose an “on-site disruption and near-site compensation” strategy to reform the interfacial water hydrogen bonding network via deliberate cation penetration and catalyst support engineering. This concept is validated using tip-like bimetallic RuNi nanoalloys planted on super-hydrophilic and high-curvature carbon nanocages (RuNi/NC). Theoretical simulations suggest that tip-induced localized concentration of hydrated K+ facilitates optimization of interfacial water dynamics and intermediate adsorption. In situ synchrotron X-ray spectroscopy endorses an H* spillover-bridged Volmer‒Tafel mechanism synergistically relayed between Ru and Ni. Consequently, RuNi/NC exhibits low overpotential of 12 mV and high durability of 1600 h at 10 mA cm‒2 for alkaline HER, and demonstrates high performance in both water electrolysis and chlor-alkali electrolysis. This strategy offers a microscopic perspective on catalyst design for manipulation of the local interfacial water structure toward enhanced HER kinetics.

Suggested Citation

  • Linjie Zhang & Haihui Hu & Chen Sun & Dongdong Xiao & Hsiao-Tsu Wang & Yi Xiao & Shuwen Zhao & Kuan Hung Chen & Wei-Xuan Lin & Yu-Cheng Shao & Xiuyun Wang & Chih-Wen Pao & Lili Han, 2024. "Bimetallic nanoalloys planted on super-hydrophilic carbon nanocages featuring tip-intensified hydrogen evolution electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51370-1
    DOI: 10.1038/s41467-024-51370-1
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