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Observation of a robust and active catalyst for hydrogen evolution under high current densities

Author

Listed:
  • Yudi Zhang

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Kathryn E. Arpino

    (Max Planck Institute for Chemical Physics of Solids)

  • Qun Yang

    (Max Planck Institute for Chemical Physics of Solids)

  • Naoki Kikugawa

    (National Institute for Materials Science (NIMS))

  • Dmitry A. Sokolov

    (Max Planck Institute for Chemical Physics of Solids)

  • Clifford W. Hicks

    (Max Planck Institute for Chemical Physics of Solids)

  • Jian Liu

    (University of Chinese Academy of Sciences
    Shanghai University)

  • Claudia Felser

    (Max Planck Institute for Chemical Physics of Solids)

  • Guowei Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

Despite the fruitful achievements in the development of hydrogen production catalysts with record-breaking performances, there is still a lack of durable catalysts that could work under large current densities (>1000 mA cm−2). Here, we investigated the catalytic behaviors of Sr2RuO4 bulk single crystals. This crystal has demonstrated remarkable activities under the current density of 1000 mA cm−2, which require overpotentials of 182 and 278 mV in 0.5 M H2SO4 and 1 M KOH electrolytes, respectively. These materials are stable for 56 days of continuous testing at a high current density of above 1000 mA cm−2 and then under operating temperatures of 70 °C. The in-situ formation of ferromagnetic Ru clusters at the crystal surface is observed, endowing the single-crystal catalyst with low charge transfer resistance and high wettability for rapid gas bubble removal. These experiments exemplify the potential of designing HER catalysts that work under industrial-scale current density.

Suggested Citation

  • Yudi Zhang & Kathryn E. Arpino & Qun Yang & Naoki Kikugawa & Dmitry A. Sokolov & Clifford W. Hicks & Jian Liu & Claudia Felser & Guowei Li, 2022. "Observation of a robust and active catalyst for hydrogen evolution under high current densities," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35464-2
    DOI: 10.1038/s41467-022-35464-2
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    2. Gaoxin Lin & Zhuang Zhang & Qiangjian Ju & Tong Wu & Carlo U. Segre & Wei Chen & Hongru Peng & Hui Zhang & Qiunan Liu & Zhi Liu & Yifan Zhang & Shuyi Kong & Yuanlv Mao & Wei Zhao & Kazu Suenaga & Fuqi, 2023. "Bottom-up evolution of perovskite clusters into high-activity rhodium nanoparticles toward alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Rui Yao & Kaian Sun & Kaiyang Zhang & Yun Wu & Yujie Du & Qiang Zhao & Guang Liu & Chen Chen & Yuhan Sun & Jinping Li, 2024. "Stable hydrogen evolution reaction at high current densities via designing the Ni single atoms and Ru nanoparticles linked by carbon bridges," Nature Communications, Nature, vol. 15(1), pages 1-12, December.

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