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Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction

Author

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  • Kai Ling Zhou

    (Beijing University of Technology)

  • Zelin Wang

    (Beijing University of Technology)

  • Chang Bao Han

    (Beijing University of Technology)

  • Xiaoxing Ke

    (Beijing University of Technology)

  • Changhao Wang

    (Beijing University of Technology)

  • Yuhong Jin

    (Beijing University of Technology)

  • Qianqian Zhang

    (Beijing University of Technology)

  • Jingbing Liu

    (Beijing University of Technology)

  • Hao Wang

    (Beijing University of Technology)

  • Hui Yan

    (Beijing University of Technology)

Abstract

Single-atom catalysts provide an effective approach to reduce the amount of precious metals meanwhile maintain their catalytic activity. However, the sluggish activity of the catalysts for alkaline water dissociation has hampered advances in highly efficient hydrogen production. Herein, we develop a single-atom platinum immobilized NiO/Ni heterostructure (PtSA-NiO/Ni) as an alkaline hydrogen evolution catalyst. It is found that Pt single atom coupled with NiO/Ni heterostructure enables the tunable binding abilities of hydroxyl ions (OH*) and hydrogen (H*), which efficiently tailors the water dissociation energy and promotes the H* conversion for accelerating alkaline hydrogen evolution reaction. A further enhancement is achieved by constructing PtSA-NiO/Ni nanosheets on Ag nanowires to form a hierarchical three-dimensional morphology. Consequently, the fabricated PtSA-NiO/Ni catalyst displays high alkaline hydrogen evolution performances with a quite high mass activity of 20.6 A mg−1 for Pt at the overpotential of 100 mV, significantly outperforming the reported catalysts.

Suggested Citation

  • Kai Ling Zhou & Zelin Wang & Chang Bao Han & Xiaoxing Ke & Changhao Wang & Yuhong Jin & Qianqian Zhang & Jingbing Liu & Hao Wang & Hui Yan, 2021. "Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-24079-8
    DOI: 10.1038/s41467-021-24079-8
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    2. Fucong Lyu & Shanshan Zeng & Zhe Jia & Fei-Xiang Ma & Ligang Sun & Lizi Cheng & Jie Pan & Yan Bao & Zhengyi Mao & Yu Bu & Yang Yang Li & Jian Lu, 2022. "Two-dimensional mineral hydrogel-derived single atoms-anchored heterostructures for ultrastable hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Yinghao Li & Chun-Kuo Peng & Huimin Hu & San-Yuan Chen & Jin-Ho Choi & Yan-Gu Lin & Jong-Min Lee, 2022. "Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    4. Ziqi Zhang & Zhe Zhang & Cailing Chen & Rui Wang & Minggang Xie & Sheng Wan & Ruige Zhang & Linchuan Cong & Haiyan Lu & Yu Han & Wei Xing & Zhan Shi & Shouhua Feng, 2024. "Single-atom platinum with asymmetric coordination environment on fully conjugated covalent organic framework for efficient electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Fengyi Shen & Zhihao Zhang & Zhe Wang & Hao Ren & Xinhu Liang & Zengjian Cai & Shitu Yang & Guodong Sun & Yanan Cao & Xiaoxin Yang & Mingzhen Hu & Zhengping Hao & Kebin Zhou, 2024. "Oxophilic Ce single atoms-triggered active sites reverse for superior alkaline hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Jiaxin Li & Kai Li & Zhao Li & Chunxue Wang & Yifei Liang & Yatong Pang & Jinzhu Ma & Fei Wang & Ping Ning & Hong He, 2024. "Capture of single Ag atoms through high-temperature-induced crystal plane reconstruction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Yudi Zhang & Kathryn E. Arpino & Qun Yang & Naoki Kikugawa & Dmitry A. Sokolov & Clifford W. Hicks & Jian Liu & Claudia Felser & Guowei Li, 2022. "Observation of a robust and active catalyst for hydrogen evolution under high current densities," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Sheng Qian & Feng Xu & Yu Fan & Ningyan Cheng & Huaiguo Xue & Ye Yuan & Romain Gautier & Tengfei Jiang & Jingqi Tian, 2024. "Tailoring coordination environments of single-atom electrocatalysts for hydrogen evolution by topological heteroatom transfer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Tianyu Zhang & Jing Jin & Junmei Chen & Yingyan Fang & Xu Han & Jiayi Chen & Yaping Li & Yu Wang & Junfeng Liu & Lei Wang, 2022. "Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    10. Yang Gao & Yurui Xue & Lu Qi & Chengyu Xing & Xuchen Zheng & Feng He & Yuliang Li, 2022. "Rhodium nanocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    11. Luqi Wang & Yixin Hao & Liming Deng & Feng Hu & Sheng Zhao & Linlin Li & Shengjie Peng, 2022. "Rapid complete reconfiguration induced actual active species for industrial hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Li, Dandan & Ding, Lei & Zhao, Qiang & Yang, Feng & Zhang, Sihang, 2024. "Controllable construction of bifunctional sites on Ir@Ni/NiO core/shell porous nanorod arrays for efficient water splitting," Applied Energy, Elsevier, vol. 356(C).
    13. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. Sang Eon Jun & Youn-Hye Kim & Jaehyun Kim & Woo Seok Cheon & Sungkyun Choi & Jinwook Yang & Hoonkee Park & Hyungsoo Lee & Sun Hwa Park & Ki Chang Kwon & Jooho Moon & Soo-Hyun Kim & Ho Won Jang, 2023. "Atomically dispersed iridium catalysts on silicon photoanode for efficient photoelectrochemical water splitting," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    15. Yiming Zhu & Malte Klingenhof & Chenlong Gao & Toshinari Koketsu & Gregor Weiser & Yecan Pi & Shangheng Liu & Lijun Sui & Jingrong Hou & Jiayi Li & Haomin Jiang & Limin Xu & Wei-Hsiang Huang & Chih-We, 2024. "Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    16. Kamran Dastafkan & Xiangjian Shen & Rosalie K. Hocking & Quentin Meyer & Chuan Zhao, 2023. "Monometallic interphasic synergy via nano-hetero-interfacing for hydrogen evolution in alkaline electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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