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Biaxial strain induced OH engineer for accelerating alkaline hydrogen evolution

Author

Listed:
  • Tao Zhang

    (Nanyang Technological University)

  • Qitong Ye

    (Hainan University)

  • Zengyu Han

    (Nanyang Technological University)

  • Qingyi Liu

    (Nanyang Technological University)

  • Yipu Liu

    (Hainan University)

  • Dongshuang Wu

    (Nanyang Technological University)

  • Hong Jin Fan

    (Nanyang Technological University)

Abstract

The sluggish kinetics of Volmer step in the alkaline hydrogen evolution results in large energy consumption. The challenge that has yet well resolved is to control the water adsorption and dissociation. Here, we develop biaxially strained MoSe2 three dimensional nanoshells that exhibit enhanced catalytic performance with a low overpotential of 58.2 mV at 10 mA cm−2 in base, and long-term stable activity in membrane-electrode-assembly based electrolyser at 1 A cm−2. Compared to the flat and uniaxial-strained MoSe2, we establish that the stably adsorbed OH engineer on biaxially strained MoSe2 changes the water adsorption configuration from O-down on Mo to O-horizontal on OH* via stronger hydrogen bonds. The favorable water dissociation on 3-coordinated Mo sites and hydrogen adsorption on 4-coordinated Mo sites constitute a tandem electrolysis, resulting in thermodynamically favorable hydrogen evolution. This work deepens our understanding to the impact of strain dimensions on water dissociation and inspires the design of nanostructured catalysts for accelerating the rate-determining step in multi-electron reactions.

Suggested Citation

  • Tao Zhang & Qitong Ye & Zengyu Han & Qingyi Liu & Yipu Liu & Dongshuang Wu & Hong Jin Fan, 2024. "Biaxial strain induced OH engineer for accelerating alkaline hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50942-5
    DOI: 10.1038/s41467-024-50942-5
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    References listed on IDEAS

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    1. Jiaxi Zhang & Longhai Zhang & Jiamin Liu & Chengzhi Zhong & Yuanhua Tu & Peng Li & Li Du & Shengli Chen & Zhiming Cui, 2022. "OH spectator at IrMo intermetallic narrowing activity gap between alkaline and acidic hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Gunther Glenk & Stefan Reichelstein, 2019. "Economics of converting renewable power to hydrogen," Nature Energy, Nature, vol. 4(3), pages 216-222, March.
    3. Kang Jiang & Min Luo & Zhixiao Liu & Ming Peng & Dechao Chen & Ying-Rui Lu & Ting-Shan Chan & Frank M. F. Groot & Yongwen Tan, 2021. "Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Yao-Hui Wang & Shisheng Zheng & Wei-Min Yang & Ru-Yu Zhou & Quan-Feng He & Petar Radjenovic & Jin-Chao Dong & Shunning Li & Jiaxin Zheng & Zhi-Lin Yang & Gary Attard & Feng Pan & Zhong-Qun Tian & Jian, 2021. "In situ Raman spectroscopy reveals the structure and dissociation of interfacial water," Nature, Nature, vol. 600(7887), pages 81-85, December.
    5. Gunther Glenk & Stefan Reichelstein, 2019. "Publisher Correction: Economics of converting renewable power to hydrogen," Nature Energy, Nature, vol. 4(4), pages 347-347, April.
    6. Ian T. McCrum & Marc T. M. Koper, 2020. "The role of adsorbed hydroxide in hydrogen evolution reaction kinetics on modified platinum," Nature Energy, Nature, vol. 5(11), pages 891-899, November.
    7. Jiayi Chen & Mohammed Aliasgar & Fernando Buendia Zamudio & Tianyu Zhang & Yilin Zhao & Xu Lian & Lan Wen & Haozhou Yang & Wenping Sun & Sergey M. Kozlov & Wei Chen & Lei Wang, 2023. "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Tianou He & Weicong Wang & Fenglei Shi & Xiaolong Yang & Xiang Li & Jianbo Wu & Yadong Yin & Mingshang Jin, 2021. "Mastering the surface strain of platinum catalysts for efficient electrocatalysis," Nature, Nature, vol. 598(7879), pages 76-81, October.
    9. Xing Chen & Xiao-Ting Wang & Jia-Bo Le & Shu-Min Li & Xue Wang & Yu-Jin Zhang & Petar Radjenovic & Yu Zhao & Yao-Hui Wang & Xiu-Mei Lin & Jin-Chao Dong & Jian-Feng Li, 2023. "Revealing the role of interfacial water and key intermediates at ruthenium surfaces in the alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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