IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37641-3.html
   My bibliography  Save this article

Dopant triggered atomic configuration activates water splitting to hydrogen

Author

Listed:
  • Rui Wu

    (University of Science and Technology of China)

  • Jie Xu

    (Soochow University)

  • Chuan-Lin Zhao

    (University of Science and Technology of China)

  • Xiao-Zhi Su

    (Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, CAS)

  • Xiao-Long Zhang

    (University of Science and Technology of China)

  • Ya-Rong Zheng

    (University of Science and Technology of China)

  • Feng-Yi Yang

    (University of Science and Technology of China)

  • Xu-Sheng Zheng

    (University of Science and Technology of China)

  • Jun-Fa Zhu

    (University of Science and Technology of China)

  • Jun Luo

    (Tianjin University of Technology)

  • Wei-Xue Li

    (University of Science and Technology of China)

  • Min-Rui Gao

    (University of Science and Technology of China)

  • Shu-Hong Yu

    (University of Science and Technology of China)

Abstract

Finding highly efficient hydrogen evolution reaction (HER) catalysts is pertinent to the ultimate goal of transformation into a net-zero carbon emission society. The design principles for such HER catalysts lie in the well-known structure-property relationship, which guides the synthesis procedure that creates catalyst with target properties such as catalytic activity. Here we report a general strategy to synthesize 10 kinds of single-atom-doped CoSe2-DETA (DETA = diethylenetriamine) nanobelts. By systematically analyzing these products, we demonstrate a volcano-shape correlation between HER activity and Co atomic configuration (ratio of Co-N bonds to Co-Se bonds). Specifically, Pb-CoSe2-DETA catalyst reaches current density of 10 mA cm−2 at 74 mV in acidic electrolyte (0.5 M H2SO4, pH ~0.35). This striking catalytic performance can be attributed to its optimized Co atomic configuration induced by single-atom doping.

Suggested Citation

  • Rui Wu & Jie Xu & Chuan-Lin Zhao & Xiao-Zhi Su & Xiao-Long Zhang & Ya-Rong Zheng & Feng-Yi Yang & Xu-Sheng Zheng & Jun-Fa Zhu & Jun Luo & Wei-Xue Li & Min-Rui Gao & Shu-Hong Yu, 2023. "Dopant triggered atomic configuration activates water splitting to hydrogen," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37641-3
    DOI: 10.1038/s41467-023-37641-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37641-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37641-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jiadong Zhou & Junhao Lin & Xiangwei Huang & Yao Zhou & Yu Chen & Juan Xia & Hong Wang & Yu Xie & Huimei Yu & Jincheng Lei & Di Wu & Fucai Liu & Qundong Fu & Qingsheng Zeng & Chuang-Han Hsu & Changli , 2018. "A library of atomically thin metal chalcogenides," Nature, Nature, vol. 556(7701), pages 355-359, April.
    2. Kang Jiang & Boyang Liu & Min Luo & Shoucong Ning & Ming Peng & Yang Zhao & Ying-Rui Lu & Ting-Shan Chan & Frank M. F. Groot & Yongwen Tan, 2019. "Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    3. Wen Liu & Enyuan Hu & Hong Jiang & Yingjie Xiang & Zhe Weng & Min Li & Qi Fan & Xiqian Yu & Eric I. Altman & Hailiang Wang, 2016. "A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
    4. Kun Qi & Xiaoqiang Cui & Lin Gu & Shansheng Yu & Xiaofeng Fan & Mingchuan Luo & Shan Xu & Ningbo Li & Lirong Zheng & Qinghua Zhang & Jingyuan Ma & Yue Gong & Fan Lv & Kai Wang & Haihua Huang & Wei Zha, 2019. "Single-atom cobalt array bound to distorted 1T MoS2 with ensemble effect for hydrogen evolution catalysis," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    5. Yangyang Xu & Veerabhadran Ramanathan & David G. Victor, 2018. "Global warming will happen faster than we think," Nature, Nature, vol. 564(7734), pages 30-32, December.
    6. Yi Shi & Zhi-Rui Ma & Yi-Ying Xiao & Yun-Chao Yin & Wen-Mao Huang & Zhi-Chao Huang & Yun-Zhe Zheng & Fang-Ya Mu & Rong Huang & Guo-Yue Shi & Yi-Yang Sun & Xing-Hua Xia & Wei Chen, 2021. "Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    7. Jiao Deng & Haobo Li & Suheng Wang & Ding Ding & Mingshu Chen & Chuan Liu & Zhongqun Tian & K. S. Novoselov & Chao Ma & Dehui Deng & Xinhe Bao, 2017. "Multiscale structural and electronic control of molybdenum disulfide foam for highly efficient hydrogen production," Nature Communications, Nature, vol. 8(1), pages 1-8, April.
    8. Huang Zhou & Yafei Zhao & Jie Xu & Haoran Sun & Zhijun Li & Wei Liu & Tongwei Yuan & Wei Liu & Xiaoqian Wang & Weng-Chon Cheong & Zhiyuan Wang & Xin Wang & Chao Zhao & Yancai Yao & Wenyu Wang & Fangya, 2020. "Recover the activity of sintered supported catalysts by nitrogen-doped carbon atomization," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    9. Ya-Rong Zheng & Ping Wu & Min-Rui Gao & Xiao-Long Zhang & Fei-Yue Gao & Huan-Xin Ju & Rui Wu & Qiang Gao & Rui You & Wei-Xin Huang & Shou-Jie Liu & Shan-Wei Hu & Junfa Zhu & Zhenyu Li & Shu-Hong Yu, 2018. "Doping-induced structural phase transition in cobalt diselenide enables enhanced hydrogen evolution catalysis," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    10. Zhaoyan Luo & Yixin Ouyang & Hao Zhang & Meiling Xiao & Junjie Ge & Zheng Jiang & Jinlan Wang & Daiming Tang & Xinzhong Cao & Changpeng Liu & Wei Xing, 2018. "Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ruiling Zhang & Yaozhou Li & Xuan Zhou & Ao Yu & Qi Huang & Tingting Xu & Longtao Zhu & Ping Peng & Shuyan Song & Luis Echegoyen & Fang-Fang Li, 2023. "Single-atomic platinum on fullerene C60 surfaces for accelerated alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Xiaowei Shi & Chao Dai & Xin Wang & Jiayue Hu & Junying Zhang & Lingxia Zheng & Liang Mao & Huajun Zheng & Mingshan Zhu, 2022. "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Kenichi Endo & Masaki Saruyama & Toshiharu Teranishi, 2023. "Location-selective immobilisation of single-atom catalysts on the surface or within the interior of ionic nanocrystals using coordination chemistry," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    4. Yiming Zhu & Malte Klingenhof & Chenlong Gao & Toshinari Koketsu & Gregor Weiser & Yecan Pi & Shangheng Liu & Lijun Sui & Jingrong Hou & Jiayi Li & Haomin Jiang & Limin Xu & Wei-Hsiang Huang & Chih-We, 2024. "Facilitating alkaline hydrogen evolution reaction on the hetero-interfaced Ru/RuO2 through Pt single atoms doping," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    5. Huaning Jiang & Weiwei Yang & Mingquan Xu & Erqing Wang & Yi Wei & Wei Liu & Xiaokang Gu & Lixuan Liu & Qian Chen & Pengbo Zhai & Xiaolong Zou & Pulickel M. Ajayan & Wu Zhou & Yongji Gong, 2022. "Single atom catalysts in Van der Waals gaps," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    6. Tianyu Zhang & Jing Jin & Junmei Chen & Yingyan Fang & Xu Han & Jiayi Chen & Yaping Li & Yu Wang & Junfeng Liu & Lei Wang, 2022. "Pinpointing the axial ligand effect on platinum single-atom-catalyst towards efficient alkaline hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-14, December.
    7. Jiachen Li & Yuqiang Ma & Cong Zhang & Chi Zhang & Huijun Ma & Zhaoqi Guo & Ning Liu & Ming Xu & Haixia Ma & Jieshan Qiu, 2023. "Green electrosynthesis of 3,3’-diamino-4,4’-azofurazan energetic materials coupled with energy-efficient hydrogen production over Pt-based catalysts," Nature Communications, Nature, vol. 14(1), pages 1-15, December.
    8. Yiming Zhu & Jiaao Wang & Toshinari Koketsu & Matthias Kroschel & Jin-Ming Chen & Su-Yang Hsu & Graeme Henkelman & Zhiwei Hu & Peter Strasser & Jiwei Ma, 2022. "Iridium single atoms incorporated in Co3O4 efficiently catalyze the oxygen evolution in acidic conditions," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Kamran Dastafkan & Xiangjian Shen & Rosalie K. Hocking & Quentin Meyer & Chuan Zhao, 2023. "Monometallic interphasic synergy via nano-hetero-interfacing for hydrogen evolution in alkaline electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Hao Shi & Tanyuan Wang & Jianyun Liu & Weiwei Chen & Shenzhou Li & Jiashun Liang & Shuxia Liu & Xuan Liu & Zhao Cai & Chao Wang & Dong Su & Yunhui Huang & Lior Elbaz & Qing Li, 2023. "A sodium-ion-conducted asymmetric electrolyzer to lower the operation voltage for direct seawater electrolysis," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    11. Lutao Li & Junjie Yao & Juntong Zhu & Yuan Chen & Chen Wang & Zhicheng Zhou & Guoxiang Zhao & Sihan Zhang & Ruonan Wang & Jiating Li & Xiangyi Wang & Zheng Lu & Lingbo Xiao & Qiang Zhang & Guifu Zou, 2023. "Colloid driven low supersaturation crystallization for atomically thin Bismuth halide perovskite," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    12. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    13. Yuannan Wang & Mingcheng Zhang & Zhenye Kang & Lei Shi & Yucheng Shen & Boyuan Tian & Yongcun Zou & Hui Chen & Xiaoxin Zou, 2023. "Nano-metal diborides-supported anode catalyst with strongly coupled TaOx/IrO2 catalytic layer for low-iridium-loading proton exchange membrane electrolyzer," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    14. John Byrne & Peter Lund & Job Taminiau, 2022. "Rapid climate transformation requires transformative policy and science thinking—An editorial essay," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(1), January.
    15. Alexander Foster & Jennifer Cole & Andrew Farlow & Ivica Petrikova, 2019. "Planetary Health Ethics: Beyond First Principles," Challenges, MDPI, vol. 10(1), pages 1-8, February.
    16. Zhongqiang Chen & Hongsong Qiu & Xinjuan Cheng & Jizhe Cui & Zuanming Jin & Da Tian & Xu Zhang & Kankan Xu & Ruxin Liu & Wei Niu & Liqi Zhou & Tianyu Qiu & Yequan Chen & Caihong Zhang & Xiaoxiang Xi &, 2024. "Defect-induced helicity dependent terahertz emission in Dirac semimetal PtTe2 thin films," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    17. Wei Wang & Qun Song & Qiang Luo & Linqian Li & Xiaobing Huo & Shipeng Chen & Jinyang Li & Yunhong Li & Se Shi & Yihui Yuan & Xiwen Du & Kai Zhang & Ning Wang, 2023. "Photothermal-enabled single-atom catalysts for high-efficiency hydrogen peroxide photosynthesis from natural seawater," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    18. Siyuan Xie & He Si & Hongxia Sun & Qian Zhao & Xiaodong Li & Shiqiang Wang & Junfeng Niu & Zhezhi Wang, 2023. "Predicting the Potential Distribution of the Endangered Plant Eucommia ulmoides in China under the Background of Climate Change," Sustainability, MDPI, vol. 15(6), pages 1-23, March.
    19. Mahalik, Mantu Kumar & Mallick, Hrushikesh & Padhan, Hemachandra, 2021. "Do educational levels influence the environmental quality? The role of renewable and non-renewable energy demand in selected BRICS countries with a new policy perspective," Renewable Energy, Elsevier, vol. 164(C), pages 419-432.
    20. Mingru Bai & Ting Wang & Zhenyu Xing & Haoju Huang & Xizheng Wu & Mohsen Adeli & Mao Wang & Xianglong Han & Ling Ye & Chong Cheng, 2024. "Electron-donable heterojunctions with synergetic Ru-Cu pair sites for biocatalytic microenvironment modulations in inflammatory mandible defects," Nature Communications, Nature, vol. 15(1), pages 1-22, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37641-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.