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Single-atomic platinum on fullerene C60 surfaces for accelerated alkaline hydrogen evolution

Author

Listed:
  • Ruiling Zhang

    (Huazhong University of Science and Technology)

  • Yaozhou Li

    (Huazhong University of Science and Technology)

  • Xuan Zhou

    (Chinese Academy of Sciences)

  • Ao Yu

    (Huazhong University of Science and Technology)

  • Qi Huang

    (Huazhong University of Science and Technology)

  • Tingting Xu

    (Huazhong University of Science and Technology)

  • Longtao Zhu

    (Huazhong University of Science and Technology)

  • Ping Peng

    (Huazhong University of Science and Technology)

  • Shuyan Song

    (Chinese Academy of Sciences)

  • Luis Echegoyen

    (University of Texas at El Paso)

  • Fang-Fang Li

    (Huazhong University of Science and Technology)

Abstract

The electrocatalytic hydrogen evolution reaction (HER) is one of the most studied and promising processes for hydrogen fuel generation. Single-atom catalysts have been shown to exhibit ultra-high HER catalytic activity, but the harsh preparation conditions and the low single-atom loading hinder their practical applications. Furthermore, promoting hydrogen evolution reaction kinetics, especially in alkaline electrolytes, remains as an important challenge. Herein, Pt/C60 catalysts with high-loading, high-dispersion single-atomic platinum anchored on C60 are achieved through a room-temperature synthetic strategy. Pt/C60-2 exhibits high HER catalytic performance with a low overpotential (η10) of 25 mV at 10 mA cm−2. Density functional theory calculations reveal that the Pt-C60 polymeric structures in Pt/C60-2 favors water adsorption, and the shell-like charge redistribution around the Pt-bonding region induced by the curved surfaces of two adjacent C60 facilitates the desorption of hydrogen, thus favoring fast reaction kinetics for hydrogen evolution.

Suggested Citation

  • Ruiling Zhang & Yaozhou Li & Xuan Zhou & Ao Yu & Qi Huang & Tingting Xu & Longtao Zhu & Ping Peng & Shuyan Song & Luis Echegoyen & Fang-Fang Li, 2023. "Single-atomic platinum on fullerene C60 surfaces for accelerated alkaline hydrogen evolution," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38126-z
    DOI: 10.1038/s41467-023-38126-z
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    References listed on IDEAS

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    2. Chenhui Zhou & Jia Shi & Zhaoqi Dong & Lingyou Zeng & Yan Chen & Ying Han & Lu Li & Wenyu Zhang & Qinghua Zhang & Lin Gu & Fan Lv & Mingchuan Luo & Shaojun Guo, 2024. "Oxophilic gallium single atoms bridged ruthenium clusters for practical anion-exchange membrane electrolyzer," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Jiachen Li & Yuqiang Ma & Cong Zhang & Chi Zhang & Huijun Ma & Zhaoqi Guo & Ning Liu & Ming Xu & Haixia Ma & Jieshan Qiu, 2023. "Green electrosynthesis of 3,3’-diamino-4,4’-azofurazan energetic materials coupled with energy-efficient hydrogen production over Pt-based catalysts," Nature Communications, Nature, vol. 14(1), pages 1-15, December.

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