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Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution

Author

Listed:
  • Yinghao Li

    (Nanyang Technological University)

  • Chun-Kuo Peng

    (National Yang Ming Chiao Tung University)

  • Huimin Hu

    (Soochow University)

  • San-Yuan Chen

    (National Yang Ming Chiao Tung University)

  • Jin-Ho Choi

    (Soochow University)

  • Yan-Gu Lin

    (National Synchrotron Radiation Research Center)

  • Jong-Min Lee

    (Nanyang Technological University)

Abstract

Developing high-performance electrocatalysts for hydrogen evolution reaction (HER) is crucial for sustainable hydrogen production, yet still challenging. Here, we report boron-modulated osmium (B-Os) aerogels with rich defects and ultra-fine diameter as a pH-universal HER electrocatalyst. The catalyst shows the small overpotentials of 12, 19, and 33 mV at a current density of 10 mA cm−2 in acidic, alkaline, and neutral electrolytes, respectively, as well as excellent stability, surpassing commercial Pt/C. Operando X-ray absorption spectroscopy shows that interventional interstitial B atoms can optimize the electron structure of B-Os aerogels and stabilize Os as active sites in an electron-deficient state under realistic working conditions, and simultaneously reveals the HER catalytic mechanisms of B-Os aerogels in pH-universal electrolytes. The density functional theory calculations also indicate introducing B atoms can tailor the electronic structure of Os, resulting in the reduced water dissociation energy and the improved adsorption/desorption behavior of hydrogen, which synergistically accelerate HER.

Suggested Citation

  • Yinghao Li & Chun-Kuo Peng & Huimin Hu & San-Yuan Chen & Jin-Ho Choi & Yan-Gu Lin & Jong-Min Lee, 2022. "Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28805-8
    DOI: 10.1038/s41467-022-28805-8
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