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Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides

Author

Listed:
  • Le Zeng

    (Dalian University of Technology)

  • Tiexin Zhang

    (Dalian University of Technology)

  • Renhai Liu

    (Dalian University of Technology)

  • Wenming Tian

    (Chinese Academy of Sciences)

  • Kaifeng Wu

    (Chinese Academy of Sciences)

  • Jingyi Zhu

    (Chinese Academy of Sciences)

  • Zhonghe Wang

    (Dalian University of Technology)

  • Cheng He

    (Dalian University of Technology)

  • Jing Feng

    (Dalian University of Technology)

  • Xiangyang Guo

    (Chinese Academy of Sciences)

  • Abdoulkader Ibro Douka

    (Dalian University of Technology)

  • Chunying Duan

    (Dalian University of Technology)

Abstract

The ability to deliver electrons is vital for dye-based photocatalysts. Conventionally, the aromatic stacking-based charge-transfer complex increases photogenerated electron accessibility but decreases the energy of excited-state dyes. To circumvent this dilemma, here we show a strategy by tuning the stacking mode of dyes. By decorating naphthalene diimide with S-bearing branches, the S···S contact-linked naphthalene diimide string is created in coordination polymer, thereby enhancing electron mobility while simultaneously preserving competent excited-state reducing power. This benefit, along with in situ assembly between naphthalene diimide strings and exogenous reagent/reactant, improves the accessibility of short-lived excited states during consecutive photon excitation, resulting in greater efficiency in photoinduced electron-transfer activation of inert bonds in comparison to other coordination polymers with different dye-stacking modes. This heterogeneous approach is successfully applied in the photoreduction of inert aryl halides and the successive formation of CAr−C/S/P/B bonds with potential pharmaceutical applications.

Suggested Citation

  • Le Zeng & Tiexin Zhang & Renhai Liu & Wenming Tian & Kaifeng Wu & Jingyi Zhu & Zhonghe Wang & Cheng He & Jing Feng & Xiangyang Guo & Abdoulkader Ibro Douka & Chunying Duan, 2023. "Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39540-z
    DOI: 10.1038/s41467-023-39540-z
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    References listed on IDEAS

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    Cited by:

    1. Le Zeng & Ling Huang & Zhi Huang & Tomoyasu Mani & Kai Huang & Chunying Duan & Gang Han, 2024. "Long wavelength near-infrared and red light-driven consecutive photo-induced electron transfer for highly effective photoredox catalysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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