IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-39540-z.html
   My bibliography  Save this article

Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides

Author

Listed:
  • Le Zeng

    (Dalian University of Technology)

  • Tiexin Zhang

    (Dalian University of Technology)

  • Renhai Liu

    (Dalian University of Technology)

  • Wenming Tian

    (Chinese Academy of Sciences)

  • Kaifeng Wu

    (Chinese Academy of Sciences)

  • Jingyi Zhu

    (Chinese Academy of Sciences)

  • Zhonghe Wang

    (Dalian University of Technology)

  • Cheng He

    (Dalian University of Technology)

  • Jing Feng

    (Dalian University of Technology)

  • Xiangyang Guo

    (Chinese Academy of Sciences)

  • Abdoulkader Ibro Douka

    (Dalian University of Technology)

  • Chunying Duan

    (Dalian University of Technology)

Abstract

The ability to deliver electrons is vital for dye-based photocatalysts. Conventionally, the aromatic stacking-based charge-transfer complex increases photogenerated electron accessibility but decreases the energy of excited-state dyes. To circumvent this dilemma, here we show a strategy by tuning the stacking mode of dyes. By decorating naphthalene diimide with S-bearing branches, the S···S contact-linked naphthalene diimide string is created in coordination polymer, thereby enhancing electron mobility while simultaneously preserving competent excited-state reducing power. This benefit, along with in situ assembly between naphthalene diimide strings and exogenous reagent/reactant, improves the accessibility of short-lived excited states during consecutive photon excitation, resulting in greater efficiency in photoinduced electron-transfer activation of inert bonds in comparison to other coordination polymers with different dye-stacking modes. This heterogeneous approach is successfully applied in the photoreduction of inert aryl halides and the successive formation of CAr−C/S/P/B bonds with potential pharmaceutical applications.

Suggested Citation

  • Le Zeng & Tiexin Zhang & Renhai Liu & Wenming Tian & Kaifeng Wu & Jingyi Zhu & Zhonghe Wang & Cheng He & Jing Feng & Xiangyang Guo & Abdoulkader Ibro Douka & Chunying Duan, 2023. "Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39540-z
    DOI: 10.1038/s41467-023-39540-z
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-39540-z
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-39540-z?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Mattia Silvi & Paolo Melchiorre, 2018. "Enhancing the potential of enantioselective organocatalysis with light," Nature, Nature, vol. 554(7690), pages 41-49, February.
    2. Omar M. Yaghi & Michael O'Keeffe & Nathan W. Ockwig & Hee K. Chae & Mohamed Eddaoudi & Jaheon Kim, 2003. "Reticular synthesis and the design of new materials," Nature, Nature, vol. 423(6941), pages 705-714, June.
    3. Hee K. Chae & Diana Y. Siberio-Pérez & Jaheon Kim & YongBok Go & Mohamed Eddaoudi & Adam J. Matzger & Michael O'Keeffe & Omar M. Yaghi, 2004. "A route to high surface area, porosity and inclusion of large molecules in crystals," Nature, Nature, vol. 427(6974), pages 523-527, February.
    4. Alok S. Tayi & Alexander K. Shveyd & Andrew C.-H. Sue & Jodi M. Szarko & Brian S. Rolczynski & Dennis Cao & T. Jackson Kennedy & Amy A. Sarjeant & Charlotte L. Stern & Walter F. Paxton & Wei Wu & Sanj, 2012. "Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes," Nature, Nature, vol. 488(7412), pages 485-489, August.
    5. Shashikant Dighe & Fabio Juliá & Alberto Luridiana & James J. Douglas & Daniele Leonori, 2020. "A photochemical dehydrogenative strategy for aniline synthesis," Nature, Nature, vol. 584(7819), pages 75-81, August.
    6. Meng Gao & Cheng Lu & Hubert Jean-Ruel & Lai Chung Liu & Alexander Marx & Ken Onda & Shin-ya Koshihara & Yoshiaki Nakano & Xiangfeng Shao & Takaaki Hiramatsu & Gunzi Saito & Hideki Yamochi & Ryan R. C, 2013. "Mapping molecular motions leading to charge delocalization with ultrabright electrons," Nature, Nature, vol. 496(7445), pages 343-346, April.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Le Zeng & Ling Huang & Zhi Huang & Tomoyasu Mani & Kai Huang & Chunying Duan & Gang Han, 2024. "Long wavelength near-infrared and red light-driven consecutive photo-induced electron transfer for highly effective photoredox catalysis," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    2. Chong-Chen Wang & Yuh-Shan Ho, 2016. "Research trend of metal–organic frameworks: a bibliometric analysis," Scientometrics, Springer;Akadémiai Kiadó, vol. 109(1), pages 481-513, October.
    3. Onur Yildirim & Matteo Bonomo & Nadia Barbero & Cesare Atzori & Bartolomeo Civalleri & Francesca Bonino & Guido Viscardi & Claudia Barolo, 2020. "Application of Metal-Organic Frameworks and Covalent Organic Frameworks as (Photo)Active Material in Hybrid Photovoltaic Technologies," Energies, MDPI, vol. 13(21), pages 1-48, October.
    4. Zhi-Zhou Ma & Qiao-Hong Li & Zirui Wang & Zhi-Gang Gu & Jian Zhang, 2022. "Electrically regulating nonlinear optical limiting of metal-organic framework film," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Jie Liu & Yanjun Li & Zhichao Lou, 2022. "Recent Advancements in MOF/Biomass and Bio-MOF Multifunctional Materials: A Review," Sustainability, MDPI, vol. 14(10), pages 1-17, May.
    6. Mohammadreza Beydaghdari & Fahimeh Hooriabad Saboor & Aziz Babapoor & Vikram V. Karve & Mehrdad Asgari, 2022. "Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment," Energies, MDPI, vol. 15(6), pages 1-34, March.
    7. Kang Hun Kim & Moon Hyeon Kim, 2023. "Adsorption of CO 2 , CO, H 2 , and N 2 on Zeolites, Activated Carbons, and Metal-Organic Frameworks with Different Surface Nonuniformities," Sustainability, MDPI, vol. 15(15), pages 1-20, July.
    8. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    9. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    10. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    11. Chakrabortty, Sankha & Kumar, Ramesh & Nayak, Jayato & Jeon, Byong-Hun & Dargar, Shashi Kant & Tripathy, Suraj K. & Pal, Parimal & Ha, Geon-Soo & Kim, Kwang Ho & Jasiński, Michał, 2023. "Green synthesis of MeOH derivatives through in situ catalytic transformations of captured CO2 in a membrane integrated photo-microreactor system: A state-of-art review for carbon capture and utilizati," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    12. Long Huang & Tengfei Ji & Chen Zhu & Huifeng Yue & Nursaya Zhumabay & Magnus Rueping, 2022. "Bioinspired desaturation of alcohols enabled by photoredox proton-coupled electron transfer and cobalt dual catalysis," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Gordeeva, Larisa G. & Solovyeva, Marina V. & Sapienza, Alessio & Aristov, Yuri I., 2020. "Potable water extraction from the atmosphere: Potential of MOFs," Renewable Energy, Elsevier, vol. 148(C), pages 72-80.
    14. Pooja Sindhu & K. S. Ananthram & Anil Jain & Kartick Tarafder & Nirmalya Ballav, 2023. "Insulator-to-metal-like transition in thin films of a biological metal-organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    15. Hong-Jing Zhu & Duan-Hui Si & Hui Guo & Ziao Chen & Rong Cao & Yuan-Biao Huang, 2024. "Oxygen-tolerant CO2 electroreduction over covalent organic frameworks via photoswitching control oxygen passivation strategy," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    16. Louis Frentzel-Beyme & Pascal Kolodzeiski & Jan-Benedikt Weiß & Andreas Schneemann & Sebastian Henke, 2022. "Quantification of gas-accessible microporosity in metal-organic framework glasses," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    17. Shuaishuai Wang & Tingrui Li & Chengyihan Gu & Jie Han & Chuan-Gang Zhao & Chengjian Zhu & Hairen Tan & Jin Xie, 2022. "Decarboxylative tandem C-N coupling with nitroarenes via SH2 mechanism," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    18. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    19. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    20. Ryunosuke Hayashi & Shohei Tashiro & Masahiro Asakura & Shinya Mitsui & Mitsuhiko Shionoya, 2023. "Effector-dependent structural transformation of a crystalline framework with allosteric effects on molecular recognition ability," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39540-z. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.