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Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes

Author

Listed:
  • Alok S. Tayi

    (Northwestern University)

  • Alexander K. Shveyd

    (Northwestern University)

  • Andrew C.-H. Sue

    (Northwestern University
    University of California, Los Angeles, Los Angeles, California 90095, USA)

  • Jodi M. Szarko

    (Northwestern University
    ANSER Center, Northwestern University
    Argonne National Laboratory)

  • Brian S. Rolczynski

    (Northwestern University
    ANSER Center, Northwestern University
    Argonne National Laboratory)

  • Dennis Cao

    (Northwestern University
    Graduate School of EEWS, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, South Korea)

  • T. Jackson Kennedy

    (Northwestern University)

  • Amy A. Sarjeant

    (Northwestern University)

  • Charlotte L. Stern

    (Northwestern University)

  • Walter F. Paxton

    (Northwestern University)

  • Wei Wu

    (Northwestern University)

  • Sanjeev K. Dey

    (Northwestern University)

  • Albert C. Fahrenbach

    (Northwestern University
    Graduate School of EEWS, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, South Korea)

  • Jeffrey R. Guest

    (Center for Nanoscale Materials, Argonne National Laboratory)

  • Hooman Mohseni

    (Northwestern University)

  • Lin X. Chen

    (Northwestern University
    ANSER Center, Northwestern University
    Argonne National Laboratory)

  • Kang L. Wang

    (University of California, Los Angeles, Los Angeles, California 90095, USA)

  • J. Fraser Stoddart

    (Northwestern University
    Graduate School of EEWS, Korea Advanced Institute of Science and Technology, Daejeon, 305-701, South Korea)

  • Samuel I. Stupp

    (Northwestern University
    Northwestern University
    Northwestern University
    Institute for BioNanotechnology in Medicine, Northwestern University)

Abstract

Organic ferroelectrics with switchable electrical polarization would be an attractive prospect for applications if their Curie temperature—below which these materials display ferroelectric behaviour—could be raised to room temperature or above; this goal has now been achieved with a family of organic materials characterized by a supramolecular structural motif.

Suggested Citation

  • Alok S. Tayi & Alexander K. Shveyd & Andrew C.-H. Sue & Jodi M. Szarko & Brian S. Rolczynski & Dennis Cao & T. Jackson Kennedy & Amy A. Sarjeant & Charlotte L. Stern & Walter F. Paxton & Wei Wu & Sanj, 2012. "Room-temperature ferroelectricity in supramolecular networks of charge-transfer complexes," Nature, Nature, vol. 488(7412), pages 485-489, August.
    • Handle: RePEc:nat:nature:v:488:y:2012:i:7412:d:10.1038_nature11395
    DOI: 10.1038/nature11395
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    Cited by:

    1. Bin Li & Lingling Liu & Yuan Wang & Kun Liu & Zhe Zheng & Shougang Sun & Yongxu Hu & Liqiang Li & Chunju Li, 2024. "Structurally diverse macrocycle co-crystals for solid-state luminescence modulation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    2. Jia-Rui Wu & Gengxin Wu & Dongxia Li & Meng-Hao Li & Yan Wang & Ying-Wei Yang, 2023. "Grinding-induced supramolecular charge-transfer assemblies with switchable vapochromism toward haloalkane isomers," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Le Zeng & Tiexin Zhang & Renhai Liu & Wenming Tian & Kaifeng Wu & Jingyi Zhu & Zhonghe Wang & Cheng He & Jing Feng & Xiangyang Guo & Abdoulkader Ibro Douka & Chunying Duan, 2023. "Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    4. Nan Zhang & Wencong Sun & Yao Zhang & Huan-Huan Jiang & Ren-Gen Xiong & Shuai Dong & Han-Yue Zhang, 2023. "Organic radical ferroelectric crystals with martensitic phase transition," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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