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Electrically regulating nonlinear optical limiting of metal-organic framework film

Author

Listed:
  • Zhi-Zhou Ma

    (Chinese Academy of Sciences)

  • Qiao-Hong Li

    (Chinese Academy of Sciences)

  • Zirui Wang

    (Chinese Academy of Sciences
    ShanghaiTech University)

  • Zhi-Gang Gu

    (Chinese Academy of Sciences
    Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China)

  • Jian Zhang

    (Chinese Academy of Sciences
    Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China)

Abstract

Regulating nonlinear optical (NLO) property of metal−organic frameworks (MOFs) is of pronounced significance for their scientific research and practical application, but the regulation through external stimuli is still a challenging task. Here we prepare and electrically control the nonlinear optical regulation of conductive MOFs Cu-HHTP films with [001]- (Cu-HHTP[001]) and [100]-orientations (Cu-HHTP[100]). Z-scan results show that the nonlinear absorption coefficient (β) of Cu-HHTP[001] film (7.60 × 10−6 m/W) is much higher than that of Cu-HHTP[100] film (0.84 × 10−6 m/W) at 0 V and the β of Cu-HHTP[001] and Cu-HHTP[100] films gradually increase to 3.84 × 10−5 and 1.71 × 10−6 m/W at 10 V by increasing the applied voltage, respectively. Due to 2D Cu-HHTP having anisotropy of charge transfer in different orientations, the NLO of MOFs film can be dependent on their growth orientations and improved by tuning the electrical field. This study provides more avenues for the regulation and NLO applications of MOFs.

Suggested Citation

  • Zhi-Zhou Ma & Qiao-Hong Li & Zirui Wang & Zhi-Gang Gu & Jian Zhang, 2022. "Electrically regulating nonlinear optical limiting of metal-organic framework film," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34139-2
    DOI: 10.1038/s41467-022-34139-2
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    References listed on IDEAS

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    1. Omar M. Yaghi & Michael O'Keeffe & Nathan W. Ockwig & Hee K. Chae & Mohamed Eddaoudi & Jaheon Kim, 2003. "Reticular synthesis and the design of new materials," Nature, Nature, vol. 423(6941), pages 705-714, June.
    2. Hee K. Chae & Diana Y. Siberio-Pérez & Jaheon Kim & YongBok Go & Mohamed Eddaoudi & Adam J. Matzger & Michael O'Keeffe & Omar M. Yaghi, 2004. "A route to high surface area, porosity and inclusion of large molecules in crystals," Nature, Nature, vol. 427(6974), pages 523-527, February.
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