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Interspecies exciton interactions lead to enhanced nonlinearity of dipolar excitons and polaritons in MoS2 homobilayers

Author

Listed:
  • Charalambos Louca

    (The University of Sheffield)

  • Armando Genco

    (Politecnico di Milano)

  • Salvatore Chiavazzo

    (University of Exeter)

  • Thomas P. Lyons

    (The University of Sheffield
    RIKEN Center for Emergent Matter Science)

  • Sam Randerson

    (The University of Sheffield)

  • Chiara Trovatello

    (Politecnico di Milano
    Columbia University)

  • Peter Claronino

    (The University of Sheffield
    University of Hull)

  • Rahul Jayaprakash

    (The University of Sheffield)

  • Xuerong Hu

    (The University of Sheffield)

  • James Howarth

    (University of Manchester
    University of Manchester)

  • Kenji Watanabe

    (National Institute for Materials Science)

  • Takashi Taniguchi

    (National Institute for Materials Science)

  • Stefano Dal Conte

    (Politecnico di Milano)

  • Roman Gorbachev

    (University of Manchester
    University of Manchester)

  • David G. Lidzey

    (The University of Sheffield)

  • Giulio Cerullo

    (Politecnico di Milano)

  • Oleksandr Kyriienko

    (University of Exeter)

  • Alexander I. Tartakovskii

    (The University of Sheffield)

Abstract

Nonlinear interactions between excitons strongly coupled to light are key for accessing quantum many-body phenomena in polariton systems. Atomically-thin two-dimensional semiconductors provide an attractive platform for strong light-matter coupling owing to many controllable excitonic degrees of freedom. Among these, the recently emerged exciton hybridization opens access to unexplored excitonic species, with a promise of enhanced interactions. Here, we employ hybridized interlayer excitons (hIX) in bilayer MoS2 to achieve highly nonlinear excitonic and polaritonic effects. Such interlayer excitons possess an out-of-plane electric dipole as well as an unusually large oscillator strength allowing observation of dipolar polaritons (dipolaritons) in bilayers in optical microcavities. Compared to excitons and polaritons in MoS2 monolayers, both hIX and dipolaritons exhibit ≈ 8 times higher nonlinearity, which is further strongly enhanced when hIX and intralayer excitons, sharing the same valence band, are excited simultaneously. This provides access to an unusual nonlinear regime which we describe theoretically as a mixed effect of Pauli exclusion and exciton-exciton interactions enabled through charge tunnelling. The presented insight into many-body interactions provides new tools for accessing few-polariton quantum correlations.

Suggested Citation

  • Charalambos Louca & Armando Genco & Salvatore Chiavazzo & Thomas P. Lyons & Sam Randerson & Chiara Trovatello & Peter Claronino & Rahul Jayaprakash & Xuerong Hu & James Howarth & Kenji Watanabe & Taka, 2023. "Interspecies exciton interactions lead to enhanced nonlinearity of dipolar excitons and polaritons in MoS2 homobilayers," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39358-9
    DOI: 10.1038/s41467-023-39358-9
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    References listed on IDEAS

    as
    1. Biswajit Datta & Mandeep Khatoniar & Prathmesh Deshmukh & Félix Thouin & Rezlind Bushati & Simone Liberato & Stephane Kena Cohen & Vinod M. Menon, 2022. "Highly nonlinear dipolar exciton-polaritons in bilayer MoS2," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    2. J. Kasprzak & M. Richard & S. Kundermann & A. Baas & P. Jeambrun & J. M. J. Keeling & F. M. Marchetti & M. H. Szymańska & R. André & J. L. Staehli & V. Savona & P. B. Littlewood & B. Deveaud & Le Si D, 2006. "Bose–Einstein condensation of exciton polaritons," Nature, Nature, vol. 443(7110), pages 409-414, September.
    3. Ioannis Paradisanos & Shivangi Shree & Antony George & Nadine Leisgang & Cedric Robert & Kenji Watanabe & Takashi Taniguchi & Richard J. Warburton & Andrey Turchanin & Xavier Marie & Iann C. Gerber & , 2020. "Controlling interlayer excitons in MoS2 layers grown by chemical vapor deposition," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
    4. Matthias Drüppel & Thorsten Deilmann & Peter Krüger & Michael Rohlfing, 2017. "Diversity of trion states and substrate effects in the optical properties of an MoS2 monolayer," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    5. Evgeny M. Alexeev & David A. Ruiz-Tijerina & Mark Danovich & Matthew J. Hamer & Daniel J. Terry & Pramoda K. Nayak & Seongjoon Ahn & Sangyeon Pak & Juwon Lee & Jung Inn Sohn & Maciej R. Molas & Maciej, 2019. "Resonantly hybridized excitons in moiré superlattices in van der Waals heterostructures," Nature, Nature, vol. 567(7746), pages 81-86, March.
    6. Long Zhang & Fengcheng Wu & Shaocong Hou & Zhe Zhang & Yu-Hsun Chou & Kenji Watanabe & Takashi Taniguchi & Stephen R. Forrest & Hui Deng, 2021. "Van der Waals heterostructure polaritons with moiré-induced nonlinearity," Nature, Nature, vol. 591(7848), pages 61-65, March.
    7. Jie Gu & Valentin Walther & Lutz Waldecker & Daniel Rhodes & Archana Raja & James C. Hone & Tony F. Heinz & Stéphane Kéna-Cohen & Thomas Pohl & Vinod M. Menon, 2021. "Enhanced nonlinear interaction of polaritons via excitonic Rydberg states in monolayer WSe2," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    8. A. Amo & D. Sanvitto & F. P. Laussy & D. Ballarini & E. del Valle & M. D. Martin & A. Lemaître & J. Bloch & D. N. Krizhanovskii & M. S. Skolnick & C. Tejedor & L. Viña, 2009. "Collective fluid dynamics of a polariton condensate in a semiconductor microcavity," Nature, Nature, vol. 457(7227), pages 291-295, January.
    9. L. V. Butov & A. C. Gossard & D. S. Chemla, 2002. "Macroscopically ordered state in an exciton system," Nature, Nature, vol. 418(6899), pages 751-754, August.
    10. S. Dufferwiel & S. Schwarz & F. Withers & A. A. P. Trichet & F. Li & M. Sich & O. Del Pozo-Zamudio & C. Clark & A. Nalitov & D. D. Solnyshkov & G. Malpuech & K. S. Novoselov & J. M. Smith & M. S. Skol, 2015. "Exciton–polaritons in van der Waals heterostructures embedded in tunable microcavities," Nature Communications, Nature, vol. 6(1), pages 1-7, December.
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    1. Ke Wei & Qirui Liu & Yuxiang Tang & Yingqian Ye & Zhongjie Xu & Tian Jiang, 2023. "Charged biexciton polaritons sustaining strong nonlinearity in 2D semiconductor-based nanocavities," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

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