IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-39358-9.html
   My bibliography  Save this article

Interspecies exciton interactions lead to enhanced nonlinearity of dipolar excitons and polaritons in MoS2 homobilayers

Author

Listed:
  • Charalambos Louca

    (The University of Sheffield)

  • Armando Genco

    (Politecnico di Milano)

  • Salvatore Chiavazzo

    (University of Exeter)

  • Thomas P. Lyons

    (The University of Sheffield
    RIKEN Center for Emergent Matter Science)

  • Sam Randerson

    (The University of Sheffield)

  • Chiara Trovatello

    (Politecnico di Milano
    Columbia University)

  • Peter Claronino

    (The University of Sheffield
    University of Hull)

  • Rahul Jayaprakash

    (The University of Sheffield)

  • Xuerong Hu

    (The University of Sheffield)

  • James Howarth

    (University of Manchester
    University of Manchester)

  • Kenji Watanabe

    (National Institute for Materials Science)

  • Takashi Taniguchi

    (National Institute for Materials Science)

  • Stefano Dal Conte

    (Politecnico di Milano)

  • Roman Gorbachev

    (University of Manchester
    University of Manchester)

  • David G. Lidzey

    (The University of Sheffield)

  • Giulio Cerullo

    (Politecnico di Milano)

  • Oleksandr Kyriienko

    (University of Exeter)

  • Alexander I. Tartakovskii

    (The University of Sheffield)

Abstract

Nonlinear interactions between excitons strongly coupled to light are key for accessing quantum many-body phenomena in polariton systems. Atomically-thin two-dimensional semiconductors provide an attractive platform for strong light-matter coupling owing to many controllable excitonic degrees of freedom. Among these, the recently emerged exciton hybridization opens access to unexplored excitonic species, with a promise of enhanced interactions. Here, we employ hybridized interlayer excitons (hIX) in bilayer MoS2 to achieve highly nonlinear excitonic and polaritonic effects. Such interlayer excitons possess an out-of-plane electric dipole as well as an unusually large oscillator strength allowing observation of dipolar polaritons (dipolaritons) in bilayers in optical microcavities. Compared to excitons and polaritons in MoS2 monolayers, both hIX and dipolaritons exhibit ≈ 8 times higher nonlinearity, which is further strongly enhanced when hIX and intralayer excitons, sharing the same valence band, are excited simultaneously. This provides access to an unusual nonlinear regime which we describe theoretically as a mixed effect of Pauli exclusion and exciton-exciton interactions enabled through charge tunnelling. The presented insight into many-body interactions provides new tools for accessing few-polariton quantum correlations.

Suggested Citation

  • Charalambos Louca & Armando Genco & Salvatore Chiavazzo & Thomas P. Lyons & Sam Randerson & Chiara Trovatello & Peter Claronino & Rahul Jayaprakash & Xuerong Hu & James Howarth & Kenji Watanabe & Taka, 2023. "Interspecies exciton interactions lead to enhanced nonlinearity of dipolar excitons and polaritons in MoS2 homobilayers," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39358-9
    DOI: 10.1038/s41467-023-39358-9
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-39358-9
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-023-39358-9?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Biswajit Datta & Mandeep Khatoniar & Prathmesh Deshmukh & Félix Thouin & Rezlind Bushati & Simone Liberato & Stephane Kena Cohen & Vinod M. Menon, 2022. "Highly nonlinear dipolar exciton-polaritons in bilayer MoS2," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    2. J. Kasprzak & M. Richard & S. Kundermann & A. Baas & P. Jeambrun & J. M. J. Keeling & F. M. Marchetti & M. H. Szymańska & R. André & J. L. Staehli & V. Savona & P. B. Littlewood & B. Deveaud & Le Si D, 2006. "Bose–Einstein condensation of exciton polaritons," Nature, Nature, vol. 443(7110), pages 409-414, September.
    3. Evgeny M. Alexeev & David A. Ruiz-Tijerina & Mark Danovich & Matthew J. Hamer & Daniel J. Terry & Pramoda K. Nayak & Seongjoon Ahn & Sangyeon Pak & Juwon Lee & Jung Inn Sohn & Maciej R. Molas & Maciej, 2019. "Resonantly hybridized excitons in moiré superlattices in van der Waals heterostructures," Nature, Nature, vol. 567(7746), pages 81-86, March.
    4. Long Zhang & Fengcheng Wu & Shaocong Hou & Zhe Zhang & Yu-Hsun Chou & Kenji Watanabe & Takashi Taniguchi & Stephen R. Forrest & Hui Deng, 2021. "Van der Waals heterostructure polaritons with moiré-induced nonlinearity," Nature, Nature, vol. 591(7848), pages 61-65, March.
    5. Jie Gu & Valentin Walther & Lutz Waldecker & Daniel Rhodes & Archana Raja & James C. Hone & Tony F. Heinz & Stéphane Kéna-Cohen & Thomas Pohl & Vinod M. Menon, 2021. "Enhanced nonlinear interaction of polaritons via excitonic Rydberg states in monolayer WSe2," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    6. L. V. Butov & A. C. Gossard & D. S. Chemla, 2002. "Macroscopically ordered state in an exciton system," Nature, Nature, vol. 418(6899), pages 751-754, August.
    7. S. Dufferwiel & S. Schwarz & F. Withers & A. A. P. Trichet & F. Li & M. Sich & O. Del Pozo-Zamudio & C. Clark & A. Nalitov & D. D. Solnyshkov & G. Malpuech & K. S. Novoselov & J. M. Smith & M. S. Skol, 2015. "Exciton–polaritons in van der Waals heterostructures embedded in tunable microcavities," Nature Communications, Nature, vol. 6(1), pages 1-7, December.
    8. Ioannis Paradisanos & Shivangi Shree & Antony George & Nadine Leisgang & Cedric Robert & Kenji Watanabe & Takashi Taniguchi & Richard J. Warburton & Andrey Turchanin & Xavier Marie & Iann C. Gerber & , 2020. "Controlling interlayer excitons in MoS2 layers grown by chemical vapor deposition," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
    9. Matthias Drüppel & Thorsten Deilmann & Peter Krüger & Michael Rohlfing, 2017. "Diversity of trion states and substrate effects in the optical properties of an MoS2 monolayer," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    10. A. Amo & D. Sanvitto & F. P. Laussy & D. Ballarini & E. del Valle & M. D. Martin & A. Lemaître & J. Bloch & D. N. Krizhanovskii & M. S. Skolnick & C. Tejedor & L. Viña, 2009. "Collective fluid dynamics of a polariton condensate in a semiconductor microcavity," Nature, Nature, vol. 457(7227), pages 291-295, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ke Wei & Qirui Liu & Yuxiang Tang & Yingqian Ye & Zhongjie Xu & Tian Jiang, 2023. "Charged biexciton polaritons sustaining strong nonlinearity in 2D semiconductor-based nanocavities," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jiaxin Zhao & Antonio Fieramosca & Kevin Dini & Ruiqi Bao & Wei Du & Rui Su & Yuan Luo & Weijie Zhao & Daniele Sanvitto & Timothy C. H. Liew & Qihua Xiong, 2023. "Exciton polariton interactions in Van der Waals superlattices at room temperature," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    2. Zhiheng Huang & Yunfei Bai & Yanchong Zhao & Le Liu & Xuan Zhao & Jiangbin Wu & Kenji Watanabe & Takashi Taniguchi & Wei Yang & Dongxia Shi & Yang Xu & Tiantian Zhang & Qingming Zhang & Ping-Heng Tan , 2024. "Observation of phonon Stark effect," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    3. Shun Feng & Aidan J. Campbell & Mauro Brotons-Gisbert & Daniel Andres-Penares & Hyeonjun Baek & Takashi Taniguchi & Kenji Watanabe & Bernhard Urbaszek & Iann C. Gerber & Brian D. Gerardot, 2024. "Highly tunable ground and excited state excitonic dipoles in multilayer 2H-MoSe2," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Biswajit Datta & Mandeep Khatoniar & Prathmesh Deshmukh & Félix Thouin & Rezlind Bushati & Simone Liberato & Stephane Kena Cohen & Vinod M. Menon, 2022. "Highly nonlinear dipolar exciton-polaritons in bilayer MoS2," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    5. Ke Wei & Qirui Liu & Yuxiang Tang & Yingqian Ye & Zhongjie Xu & Tian Jiang, 2023. "Charged biexciton polaritons sustaining strong nonlinearity in 2D semiconductor-based nanocavities," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Madeleine Laitz & Alexander E. K. Kaplan & Jude Deschamps & Ulugbek Barotov & Andrew H. Proppe & Inés García-Benito & Anna Osherov & Giulia Grancini & Dane W. deQuilettes & Keith A. Nelson & Moungi G., 2023. "Uncovering temperature-dependent exciton-polariton relaxation mechanisms in hybrid organic-inorganic perovskites," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Shivangi Shree & Delphine Lagarde & Laurent Lombez & Cedric Robert & Andrea Balocchi & Kenji Watanabe & Takashi Taniguchi & Xavier Marie & Iann C. Gerber & Mikhail M. Glazov & Leonid E. Golub & Bernha, 2021. "Interlayer exciton mediated second harmonic generation in bilayer MoS2," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    8. Yesenia A. García Jomaso & Brenda Vargas & David Ley Domínguez & Román J. Armenta-Rico & Huziel E. Sauceda & César L. Ordoñez-Romero & Hugo A. Lara-García & Arturo Camacho-Guardian & Giuseppe Pirrucci, 2024. "Intercavity polariton slows down dynamics in strongly coupled cavities," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    9. Francesco L. Ruta & Shuai Zhang & Yinming Shao & Samuel L. Moore & Swagata Acharya & Zhiyuan Sun & Siyuan Qiu & Johannes Geurs & Brian S. Y. Kim & Matthew Fu & Daniel G. Chica & Dimitar Pashov & Xiaod, 2023. "Hyperbolic exciton polaritons in a van der Waals magnet," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    10. Zehua Hu & Tanjung Krisnanda & Antonio Fieramosca & Jiaxin Zhao & Qianlu Sun & Yuzhong Chen & Haiyun Liu & Yuan Luo & Rui Su & Junyong Wang & Kenji Watanabe & Takashi Taniguchi & Goki Eda & Xiao Rensh, 2024. "Energy transfer driven brightening of MoS2 by ultrafast polariton relaxation in microcavity MoS2/hBN/WS2 heterostructures," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    11. Hangyong Shan & Lukas Lackner & Bo Han & Evgeny Sedov & Christoph Rupprecht & Heiko Knopf & Falk Eilenberger & Johannes Beierlein & Nils Kunte & Martin Esmann & Kentaro Yumigeta & Kenji Watanabe & Tak, 2021. "Spatial coherence of room-temperature monolayer WSe2 exciton-polaritons in a trap," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    12. Benjamin Carey & Nils Kolja Wessling & Paul Steeger & Robert Schmidt & Steffen Michaelis de Vasconcellos & Rudolf Bratschitsch & Ashish Arora, 2024. "Giant Faraday rotation in atomically thin semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    13. Xuecou Tu & Yichen Zhang & Shuyu Zhou & Wenjing Tang & Xu Yan & Yunjie Rui & Wohu Wang & Bingnan Yan & Chen Zhang & Ziyao Ye & Hongkai Shi & Runfeng Su & Chao Wan & Daxing Dong & Ruiying Xu & Qing-Yua, 2024. "Tamm-cavity terahertz detector," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    14. Suman Chatterjee & Medha Dandu & Pushkar Dasika & Rabindra Biswas & Sarthak Das & Kenji Watanabe & Takashi Taniguchi & Varun Raghunathan & Kausik Majumdar, 2023. "Harmonic to anharmonic tuning of moiré potential leading to unconventional Stark effect and giant dipolar repulsion in WS2/WSe2 heterobilayer," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    15. Ruoming Peng & Adina Ripin & Yusen Ye & Jiayi Zhu & Changming Wu & Seokhyeong Lee & Huan Li & Takashi Taniguchi & Kenji Watanabe & Ting Cao & Xiaodong Xu & Mo Li, 2022. "Long-range transport of 2D excitons with acoustic waves," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    16. Seong Won Lee & Jong Seok Lee & Woo Hun Choi & Daegwang Choi & Su-Hyun Gong, 2024. "Ultra-compact exciton polariton modulator based on van der Waals semiconductors," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    17. Mengjie Wei & Wouter Verstraelen & Konstantinos Orfanakis & Arvydas Ruseckas & Timothy C. H. Liew & Ifor D. W. Samuel & Graham A. Turnbull & Hamid Ohadi, 2022. "Optically trapped room temperature polariton condensate in an organic semiconductor," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    18. Yusuke Morita & Kosuke Yoshioka & Makoto Kuwata-Gonokami, 2022. "Observation of Bose-Einstein condensates of excitons in a bulk semiconductor," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    19. María Barra-Burillo & Unai Muniain & Sara Catalano & Marta Autore & Fèlix Casanova & Luis E. Hueso & Javier Aizpurua & Ruben Esteban & Rainer Hillenbrand, 2021. "Microcavity phonon polaritons from the weak to the ultrastrong phonon–photon coupling regime," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    20. Qiuyang Li & Adam Alfrey & Jiaqi Hu & Nathanial Lydick & Eunice Paik & Bin Liu & Haiping Sun & Yang Lu & Ruoyu Wang & Stephen Forrest & Hui Deng, 2023. "Macroscopic transition metal dichalcogenides monolayers with uniformly high optical quality," Nature Communications, Nature, vol. 14(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39358-9. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.