IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37943-6.html
   My bibliography  Save this article

Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand

Author

Listed:
  • Shuo Wang

    (Nankai University)

  • Qian Zhao

    (Nankai University)

  • Abhijit Hazarika

    (CSIR-Indian Institute of Chemical Technology
    National Renewable Energy Laboratory)

  • Simiao Li

    (Nankai University)

  • Yue Wu

    (Nankai University)

  • Yaxin Zhai

    (National Renewable Energy Laboratory
    Hunan Normal University)

  • Xihan Chen

    (Southern University of Science and Technology)

  • Joseph M. Luther

    (National Renewable Energy Laboratory)

  • Guoran Li

    (Nankai University)

Abstract

A detailed picture of temperature dependent behavior of CsxFA1-xPbI3 perovskite quantum dots across the composition range is constructed by performing in situ optical spectroscopic and structural measurements, supported by theoretical calculations that focus on the relation between A-site chemical composition and surface ligand binding. The thermal degradation mechanism depends not only on the exact chemical composition, but also on the ligand binding energy. The thermal degradation of Cs-rich perovskite quantum dots is induced by a phase transition from black γ-phase to yellow δ-phase, while FA-rich perovskite quantum dots with higher ligand binding energy directly decompose into PbI2. Quantum dot growth to form large bulk size grain is observed for all CsxFA1-xPbI3 perovskite quantum dots at elevated temperatures. In addition, FA-rich quantum dots possess stronger electron−longitudinal optical phonon coupling, suggesting that photogenerated excitons in FA-rich quantum dots have higher probability to be dissociated by phonon scattering compared to Cs-rich quantum dots.

Suggested Citation

  • Shuo Wang & Qian Zhao & Abhijit Hazarika & Simiao Li & Yue Wu & Yaxin Zhai & Xihan Chen & Joseph M. Luther & Guoran Li, 2023. "Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37943-6
    DOI: 10.1038/s41467-023-37943-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37943-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37943-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Qiushui Chen & Jing Wu & Xiangyu Ou & Bolong Huang & Jawaher Almutlaq & Ayan A. Zhumekenov & Xinwei Guan & Sanyang Han & Liangliang Liang & Zhigao Yi & Juan Li & Xiaoji Xie & Yu Wang & Ying Li & Diany, 2018. "All-inorganic perovskite nanocrystal scintillators," Nature, Nature, vol. 561(7721), pages 88-93, September.
    2. Meng-Cheng Yen & Chia-Jung Lee & Kang-Hsiang Liu & Yi Peng & Junfu Leng & Tzu-Hsuan Chang & Chun-Chieh Chang & Kaoru Tamada & Ya-Ju Lee, 2021. "All-inorganic perovskite quantum dot light-emitting memories," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    3. Qian Zhao & Abhijit Hazarika & Xihan Chen & Steve P. Harvey & Bryon W. Larson & Glenn R. Teeter & Jun Liu & Tao Song & Chuanxiao Xiao & Liam Shaw & Minghui Zhang & Guoran Li & Matthew C. Beard & Josep, 2019. "High efficiency perovskite quantum dot solar cells with charge separating heterostructure," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    4. Marina R. Filip & Giles E. Eperon & Henry J. Snaith & Feliciano Giustino, 2014. "Steric engineering of metal-halide perovskites with tunable optical band gaps," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    5. Adam D. Wright & Carla Verdi & Rebecca L. Milot & Giles E. Eperon & Miguel A. Pérez-Osorio & Henry J. Snaith & Feliciano Giustino & Michael B. Johnston & Laura M. Herz, 2016. "Electron–phonon coupling in hybrid lead halide perovskites," Nature Communications, Nature, vol. 7(1), pages 1-9, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Feng Ke & Jiejuan Yan & Shanyuan Niu & Jiajia Wen & Ketao Yin & Hong Yang & Nathan R. Wolf & Yan-Kai Tzeng & Hemamala I. Karunadasa & Young S. Lee & Wendy L. Mao & Yu Lin, 2022. "Cesium-mediated electron redistribution and electron-electron interaction in high-pressure metallic CsPbI3," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Weilun Li & Mengmeng Hao & Ardeshir Baktash & Lianzhou Wang & Joanne Etheridge, 2023. "The role of ion migration, octahedral tilt, and the A-site cation on the instability of Cs1-xFAxPbI3," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Hailei Zhang & Bo Zhang & Chongyang Cai & Kaiming Zhang & Yu Wang & Yuan Wang & Yanmin Yang & Yonggang Wu & Xinwu Ba & Richard Hoogenboom, 2024. "Water-dispersible X-ray scintillators enabling coating and blending with polymer materials for multiple applications," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. Huihui Zhu & Ao Liu & Kyu In Shim & Haksoon Jung & Taoyu Zou & Youjin Reo & Hyunjun Kim & Jeong Woo Han & Yimu Chen & Hye Yong Chu & Jun Hyung Lim & Hyung-Jun Kim & Sai Bai & Yong-Young Noh, 2022. "High-performance hysteresis-free perovskite transistors through anion engineering," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    5. Xuan Trung Nguyen & Katrin Winte & Daniel Timmer & Yevgeny Rakita & Davide Raffaele Ceratti & Sigalit Aharon & Muhammad Sufyan Ramzan & Caterina Cocchi & Michael Lorke & Frank Jahnke & David Cahen & C, 2023. "Phonon-driven intra-exciton Rabi oscillations in CsPbBr3 halide perovskites," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Ahmad R. Kirmani & Todd A. Byers & Zhenyi Ni & Kaitlyn VanSant & Darshpreet K. Saini & Rebecca Scheidt & Xiaopeng Zheng & Tatchen Buh Kum & Ian R. Sellers & Lyndsey McMillon-Brown & Jinsong Huang & Bi, 2024. "Unraveling radiation damage and healing mechanisms in halide perovskites using energy-tuned dual irradiation dosing," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    7. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    8. Tong Jin & Zheng Liu & Jiajun Luo & Jun-Hui Yuan & Hanqi Wang & Zuoxiang Xie & Weicheng Pan & Haodi Wu & Kan-Hao Xue & Linyue Liu & Zhanli Hu & Zhiping Zheng & Jiang Tang & Guangda Niu, 2023. "Self-wavelength shifting in two-dimensional perovskite for sensitive and fast gamma-ray detection," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    9. Yongan Feng & Jichuan Zhang & Weiguo Cao & Jiaheng Zhang & Jean’ne M. Shreeve, 2023. "A promising perovskite primary explosive," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    10. Xinchen Dai & Pramod Koshy & Charles Christopher Sorrell & Jongchul Lim & Jae Sung Yun, 2020. "Focussed Review of Utilization of Graphene-Based Materials in Electron Transport Layer in Halide Perovskite Solar Cells: Materials-Based Issues," Energies, MDPI, vol. 13(23), pages 1-24, December.
    11. Claudiu M. Iaru & Annalisa Brodu & Niels J. J. Hoof & Stan E. T. Huurne & Jonathan Buhot & Federico Montanarella & Sophia Buhbut & Peter C. M. Christianen & Daniël Vanmaekelbergh & Celso Mello Donega , 2021. "Fröhlich interaction dominated by a single phonon mode in CsPbBr3," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    12. Da Liu & Yichu Zheng & Xin Yuan Sui & Xue Feng Wu & Can Zou & Yu Peng & Xinyi Liu & Miaoyu Lin & Zhanpeng Wei & Hang Zhou & Ye-Feng Yao & Sheng Dai & Haiyang Yuan & Hua Gui Yang & Shuang Yang & Yu Hou, 2024. "Universal growth of perovskite thin monocrystals from high solute flux for sensitive self-driven X-ray detection," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    13. Paribesh Acharyya & Tanmoy Ghosh & Koushik Pal & Kewal Singh Rana & Moinak Dutta & Diptikanta Swain & Martin Etter & Ajay Soni & Umesh V. Waghmare & Kanishka Biswas, 2022. "Glassy thermal conductivity in Cs3Bi2I6Cl3 single crystal," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    14. Amanda A. Volk & Robert W. Epps & Daniel T. Yonemoto & Benjamin S. Masters & Felix N. Castellano & Kristofer G. Reyes & Milad Abolhasani, 2023. "AlphaFlow: autonomous discovery and optimization of multi-step chemistry using a self-driven fluidic lab guided by reinforcement learning," Nature Communications, Nature, vol. 14(1), pages 1-16, December.
    15. Peisheng Cao & Haoyue Zheng & Peng Wu, 2022. "Multicolor ultralong phosphorescence from perovskite-like octahedral α-AlF3," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    16. Artem Musiienko & Fengjiu Yang & Thomas William Gries & Chiara Frasca & Dennis Friedrich & Amran Al-Ashouri & Elifnaz Sağlamkaya & Felix Lang & Danny Kojda & Yi-Teng Huang & Valerio Stacchini & Robert, 2024. "Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    17. Nan Zhang & Lei Qu & Shuheng Dai & Guohua Xie & Chunmiao Han & Jing Zhang & Ran Huo & Huan Hu & Qiushui Chen & Wei Huang & Hui Xu, 2023. "Intramolecular charge transfer enables highly-efficient X-ray luminescence in cluster scintillators," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    18. Sean A. Bourelle & Franco V. A. Camargo & Soumen Ghosh & Timo Neumann & Tim W. J. Goor & Ravichandran Shivanna & Thomas Winkler & Giulio Cerullo & Felix Deschler, 2022. "Optical control of exciton spin dynamics in layered metal halide perovskites via polaronic state formation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    19. Naveen Kumar Elumalai & Md Arafat Mahmud & Dian Wang & Ashraf Uddin, 2016. "Perovskite Solar Cells: Progress and Advancements," Energies, MDPI, vol. 9(11), pages 1-20, October.
    20. Sujung Min & Hara Kang & Bumkyung Seo & JaeHak Cheong & Changhyun Roh & Sangbum Hong, 2021. "A Review of Nanomaterial Based Scintillators," Energies, MDPI, vol. 14(22), pages 1-43, November.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37943-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.