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Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand

Author

Listed:
  • Shuo Wang

    (Nankai University)

  • Qian Zhao

    (Nankai University)

  • Abhijit Hazarika

    (CSIR-Indian Institute of Chemical Technology
    National Renewable Energy Laboratory)

  • Simiao Li

    (Nankai University)

  • Yue Wu

    (Nankai University)

  • Yaxin Zhai

    (National Renewable Energy Laboratory
    Hunan Normal University)

  • Xihan Chen

    (Southern University of Science and Technology)

  • Joseph M. Luther

    (National Renewable Energy Laboratory)

  • Guoran Li

    (Nankai University)

Abstract

A detailed picture of temperature dependent behavior of CsxFA1-xPbI3 perovskite quantum dots across the composition range is constructed by performing in situ optical spectroscopic and structural measurements, supported by theoretical calculations that focus on the relation between A-site chemical composition and surface ligand binding. The thermal degradation mechanism depends not only on the exact chemical composition, but also on the ligand binding energy. The thermal degradation of Cs-rich perovskite quantum dots is induced by a phase transition from black γ-phase to yellow δ-phase, while FA-rich perovskite quantum dots with higher ligand binding energy directly decompose into PbI2. Quantum dot growth to form large bulk size grain is observed for all CsxFA1-xPbI3 perovskite quantum dots at elevated temperatures. In addition, FA-rich quantum dots possess stronger electron−longitudinal optical phonon coupling, suggesting that photogenerated excitons in FA-rich quantum dots have higher probability to be dissociated by phonon scattering compared to Cs-rich quantum dots.

Suggested Citation

  • Shuo Wang & Qian Zhao & Abhijit Hazarika & Simiao Li & Yue Wu & Yaxin Zhai & Xihan Chen & Joseph M. Luther & Guoran Li, 2023. "Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37943-6
    DOI: 10.1038/s41467-023-37943-6
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