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Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals

Author

Listed:
  • E. Kirstein

    (Technische Universität Dortmund)

  • N. E. Kopteva

    (Technische Universität Dortmund)

  • D. R. Yakovlev

    (Technische Universität Dortmund
    Russian Academy of Sciences
    P. N. Lebedev Physical Institute of the Russian Academy of Sciences)

  • E. A. Zhukov

    (Technische Universität Dortmund
    Russian Academy of Sciences)

  • E. V. Kolobkova

    (ITMO University
    St. Petersburg State Institute of Technology)

  • M. S. Kuznetsova

    (St. Petersburg State University)

  • V. V. Belykh

    (P. N. Lebedev Physical Institute of the Russian Academy of Sciences)

  • I. A. Yugova

    (St. Petersburg State University)

  • M. M. Glazov

    (Russian Academy of Sciences)

  • M. Bayer

    (Technische Universität Dortmund)

  • A. Greilich

    (Technische Universität Dortmund)

Abstract

The spin physics of perovskite nanocrystals with confined electrons or holes is attracting increasing attention, both for fundamental studies and spintronic applications. Here, stable $${{{{{{{\rm{CsPb}}}}}}}}{({{{{{{{{\rm{Cl}}}}}}}}}_{0.56}{{{{{{{{\rm{Br}}}}}}}}}_{0.44})}_{3}$$ CsPb ( Cl 0.56 Br 0.44 ) 3 lead halide perovskite nanocrystals embedded in a fluorophosphate glass matrix are studied by time-resolved optical spectroscopy to unravel the coherent spin dynamics of holes and their interaction with nuclear spins of the 207Pb isotope. We demonstrate the spin mode locking effect provided by the synchronization of the Larmor precession of single hole spins in each nanocrystal in the ensemble that are excited periodically by a laser in an external magnetic field. The mode locking is enhanced by nuclei-induced frequency focusing. An ensemble spin dephasing time $${T}_{2}^{ * }$$ T 2 * of a nanosecond and a single hole spin coherence time of T2 = 13 ns are measured. The developed theoretical model accounting for the mode locking and nuclear focusing for randomly oriented nanocrystals with perovskite band structure describes the experimental data very well.

Suggested Citation

  • E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36165-0
    DOI: 10.1038/s41467-023-36165-0
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    as
    1. E. Kirstein & D. R. Yakovlev & M. M. Glazov & E. A. Zhukov & D. Kudlacik & I. V. Kalitukha & V. F. Sapega & G. S. Dimitriev & M. A. Semina & M. O. Nestoklon & E. L. Ivchenko & N. E. Kopteva & D. N. Di, 2022. "The Landé factors of electrons and holes in lead halide perovskites: universal dependence on the band gap," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Qiushui Chen & Jing Wu & Xiangyu Ou & Bolong Huang & Jawaher Almutlaq & Ayan A. Zhumekenov & Xinwei Guan & Sanyang Han & Liangliang Liang & Zhigao Yi & Juan Li & Xiaoji Xie & Yu Wang & Ying Li & Diany, 2018. "All-inorganic perovskite nanocrystal scintillators," Nature, Nature, vol. 561(7721), pages 88-93, September.
    3. Michael A. Becker & Roman Vaxenburg & Georgian Nedelcu & Peter C. Sercel & Andrew Shabaev & Michael J. Mehl & John G. Michopoulos & Samuel G. Lambrakos & Noam Bernstein & John L. Lyons & Thilo Stöferl, 2018. "Bright triplet excitons in caesium lead halide perovskites," Nature, Nature, vol. 553(7687), pages 189-193, January.
    4. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    5. Vasilii V. Belykh & Dmitri R. Yakovlev & Mikhail M. Glazov & Philipp S. Grigoryev & Mujtaba Hussain & Janina Rautert & Dmitry N. Dirin & Maksym V. Kovalenko & Manfred Bayer, 2019. "Author Correction: Coherent spin dynamics of electrons and holes in CsPbBr3 perovskite crystals," Nature Communications, Nature, vol. 10(1), pages 1-1, December.
    6. Jingying Wang & Chuang Zhang & Haoliang Liu & Ryan McLaughlin & Yaxin Zhai & Shai R. Vardeny & Xiaojie Liu & Stephen McGill & Dmitry Semenov & Hangwen Guo & Ryuichi Tsuchikawa & Vikram V. Deshpande & , 2019. "Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
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