IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-46712-y.html
   My bibliography  Save this article

Universal growth of perovskite thin monocrystals from high solute flux for sensitive self-driven X-ray detection

Author

Listed:
  • Da Liu

    (East China University of Science and Technology)

  • Yichu Zheng

    (Shanghai University)

  • Xin Yuan Sui

    (East China University of Science and Technology)

  • Xue Feng Wu

    (East China University of Science and Technology)

  • Can Zou

    (East China University of Science and Technology)

  • Yu Peng

    (East China University of Science and Technology)

  • Xinyi Liu

    (East China University of Science and Technology)

  • Miaoyu Lin

    (East China University of Science and Technology)

  • Zhanpeng Wei

    (East China University of Science and Technology)

  • Hang Zhou

    (East China Normal University)

  • Ye-Feng Yao

    (East China Normal University)

  • Sheng Dai

    (East China University of Science and Technology)

  • Haiyang Yuan

    (East China University of Science and Technology)

  • Hua Gui Yang

    (East China University of Science and Technology)

  • Shuang Yang

    (East China University of Science and Technology)

  • Yu Hou

    (East China University of Science and Technology)

Abstract

Metal-halide perovskite thin monocrystals featuring efficient carrier collection and transport capabilities are well suited for radiation detectors, yet their growth in a generic, well-controlled manner remains challenging. Here, we reveal that mass transfer is one major limiting factor during solution growth of perovskite thin monocrystals. A general approach is developed to overcome synthetic limitation by using a high solute flux system, in which mass diffusion coefficient is improved from 1.7×10–10 to 5.4×10–10 m2 s–1 by suppressing monomer aggregation. The generality of this approach is validated by the synthesis of 29 types of perovskite thin monocrystals at 40–90 °C with the growth velocity up to 27.2 μm min–1. The as-grown perovskite monocrystals deliver a high X-ray sensitivity of 1.74×105 µC Gy−1 cm−2 without applied bias. The findings regarding limited mass transfer and high-flux crystallization are crucial towards advancing the preparation and application of perovskite thin monocrystals.

Suggested Citation

  • Da Liu & Yichu Zheng & Xin Yuan Sui & Xue Feng Wu & Can Zou & Yu Peng & Xinyi Liu & Miaoyu Lin & Zhanpeng Wei & Hang Zhou & Ye-Feng Yao & Sheng Dai & Haiyang Yuan & Hua Gui Yang & Shuang Yang & Yu Hou, 2024. "Universal growth of perovskite thin monocrystals from high solute flux for sensitive self-driven X-ray detection," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46712-y
    DOI: 10.1038/s41467-024-46712-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-46712-y
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-46712-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ye Liu & Xiaopeng Zheng & Yanjun Fang & Ying Zhou & Zhenyi Ni & Xun Xiao & Shangshang Chen & Jinsong Huang, 2021. "Ligand assisted growth of perovskite single crystals with low defect density," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    2. Zhaolai Chen & Qingfeng Dong & Ye Liu & Chunxiong Bao & Yanjun Fang & Yun Lin & Shi Tang & Qi Wang & Xun Xiao & Yang Bai & Yehao Deng & Jinsong Huang, 2017. "Thin single crystal perovskite solar cells to harvest below-bandgap light absorption," Nature Communications, Nature, vol. 8(1), pages 1-7, December.
    3. Qiushui Chen & Jing Wu & Xiangyu Ou & Bolong Huang & Jawaher Almutlaq & Ayan A. Zhumekenov & Xinwei Guan & Sanyang Han & Liangliang Liang & Zhigao Yi & Juan Li & Xiaoji Xie & Yu Wang & Ying Li & Diany, 2018. "All-inorganic perovskite nanocrystal scintillators," Nature, Nature, vol. 561(7721), pages 88-93, September.
    4. Fang Yao & Jiali Peng & Ruiming Li & Wenjing Li & Pengbin Gui & Borui Li & Chang Liu & Chen Tao & Qianqian Lin & Guojia Fang, 2020. "Room-temperature liquid diffused separation induced crystallization for high-quality perovskite single crystals," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Henry N. Chapman & Petra Fromme & Anton Barty & Thomas A. White & Richard A. Kirian & Andrew Aquila & Mark S. Hunter & Joachim Schulz & Daniel P. DePonte & Uwe Weierstall & R. Bruce Doak & Filipe R. N, 2011. "Femtosecond X-ray protein nanocrystallography," Nature, Nature, vol. 470(7332), pages 73-77, February.
    6. Hyun-Sung Yun & Hyoung Woo Kwon & Min Jae Paik & Sungtak Hong & Jaehui Kim & Eunseo Noh & Jaewang Park & Yonghui Lee & Sang Seok, 2022. "Ethanol-based green-solution processing of α-formamidinium lead triiodide perovskite layers," Nature Energy, Nature, vol. 7(9), pages 828-834, September.
    7. Xiangyu Ou & Xian Qin & Bolong Huang & Jie Zan & Qinxia Wu & Zhongzhu Hong & Lili Xie & Hongyu Bian & Zhigao Yi & Xiaofeng Chen & Yiming Wu & Xiaorong Song & Juan Li & Qiushui Chen & Huanghao Yang & X, 2021. "High-resolution X-ray luminescence extension imaging," Nature, Nature, vol. 590(7846), pages 410-415, February.
    8. Hong Zhang & Kasra Darabi & Narges Yaghoobi Nia & Anurag Krishna & Paramvir Ahlawat & Boyu Guo & Masaud Hassan S. Almalki & Tzu-Sen Su & Dan Ren & Viacheslav Bolnykh & Luigi Angelo Castriotta & Mahmou, 2022. "A universal co-solvent dilution strategy enables facile and cost-effective fabrication of perovskite photovoltaics," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    9. Yimu Chen & Yusheng Lei & Yuheng Li & Yugang Yu & Jinze Cai & Ming-Hui Chiu & Rahul Rao & Yue Gu & Chunfeng Wang & Woojin Choi & Hongjie Hu & Chonghe Wang & Yang Li & Jiawei Song & Jingxin Zhang & Bai, 2020. "Strain engineering and epitaxial stabilization of halide perovskites," Nature, Nature, vol. 577(7789), pages 209-215, January.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hailei Zhang & Bo Zhang & Chongyang Cai & Kaiming Zhang & Yu Wang & Yuan Wang & Yanmin Yang & Yonggang Wu & Xinwu Ba & Richard Hoogenboom, 2024. "Water-dispersible X-ray scintillators enabling coating and blending with polymer materials for multiple applications," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Yurou Zhang & Miaoqiang Lyu & Tengfei Qiu & Ekyu Han & Il Ku Kim & Min-Cherl Jung & Yun Hau Ng & Jung-Ho Yun & Lianzhou Wang, 2020. "Halide Perovskite Single Crystals: Optoelectronic Applications and Strategical Approaches," Energies, MDPI, vol. 13(16), pages 1-27, August.
    3. Yongan Feng & Jichuan Zhang & Weiguo Cao & Jiaheng Zhang & Jean’ne M. Shreeve, 2023. "A promising perovskite primary explosive," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    4. Ouedraogo, Nabonswende Aida Nadege & Odunmbaku, George Omololu & Ouyang, Yunfei & Xiong, Xiqiu & Guo, Bing & Chen, Shanshan & Lu, Shirong & Sun, Kuan, 2024. "Eco-friendly processing of perovskite solar cells in ambient air," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    5. Nan Zhang & Lei Qu & Shuheng Dai & Guohua Xie & Chunmiao Han & Jing Zhang & Ran Huo & Huan Hu & Qiushui Chen & Wei Huang & Hui Xu, 2023. "Intramolecular charge transfer enables highly-efficient X-ray luminescence in cluster scintillators," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Yun-Lan Li & Hai-Ling Wang & Zhong-Hong Zhu & Yu-Feng Wang & Fu-Pei Liang & Hua-Hong Zou, 2024. "Aggregation induced emission dynamic chiral europium(III) complexes with excellent circularly polarized luminescence and smart sensors," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    7. Chao Ge & Yachao Li & Haiying Song & Qiyuan Xie & Leilei Zhang & Xiaoran Ma & Junfeng Liu & Xiangjing Guo & Yinzhou Yan & Danmin Liu & Wenkai Zhang & Shibing Liu & Yang Liu, 2024. "Anisotropic carrier dynamics and laser-fabricated luminescent patterns on oriented single-crystal perovskite wafers," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Huihui Zhu & Ao Liu & Kyu In Shim & Haksoon Jung & Taoyu Zou & Youjin Reo & Hyunjun Kim & Jeong Woo Han & Yimu Chen & Hye Yong Chu & Jun Hyung Lim & Hyung-Jun Kim & Sai Bai & Yong-Young Noh, 2022. "High-performance hysteresis-free perovskite transistors through anion engineering," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    9. Shuo Wang & Qian Zhao & Abhijit Hazarika & Simiao Li & Yue Wu & Yaxin Zhai & Xihan Chen & Joseph M. Luther & Guoran Li, 2023. "Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    10. Yangshuang Bian & Mingliang Zhu & Chengyu Wang & Kai Liu & Wenkang Shi & Zhiheng Zhu & Mingcong Qin & Fan Zhang & Zhiyuan Zhao & Hanlin Wang & Yunqi Liu & Yunlong Guo, 2024. "A detachable interface for stable low-voltage stretchable transistor arrays and high-resolution X-ray imaging," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    11. Basudev Maity & Mitsuo Shoji & Fangjia Luo & Takanori Nakane & Satoshi Abe & Shigeki Owada & Jungmin Kang & Kensuke Tono & Rie Tanaka & Thuc Toan Pham & Mariko Kojima & Yuki Hishikawa & Junko Tanaka &, 2024. "Real-time observation of a metal complex-driven reaction intermediate using a porous protein crystal and serial femtosecond crystallography," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    12. Ilya Svetlizky & Seongsoo Kim & David A. Weitz & Frans Spaepen, 2023. "Dislocation interactions during plastic relaxation of epitaxial colloidal crystals," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    13. Gábor Bortel & Miklós Tegze & Marcin Sikorski & Richard Bean & Johan Bielecki & Chan Kim & Jayanath C. P. Koliyadu & Faisal H. M. Koua & Marco Ramilli & Adam Round & Tokushi Sato & Dmitrii Zabelskii &, 2024. "3D atomic structure from a single X-ray free electron laser pulse," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    14. E. Kirstein & N. E. Kopteva & D. R. Yakovlev & E. A. Zhukov & E. V. Kolobkova & M. S. Kuznetsova & V. V. Belykh & I. A. Yugova & M. M. Glazov & M. Bayer & A. Greilich, 2023. "Mode locking of hole spin coherences in CsPb(Cl, Br)3 perovskite nanocrystals," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    15. Jiajia Suo & Bowen Yang & Edoardo Mosconi & Dmitry Bogachuk & Tiarnan A. S. Doherty & Kyle Frohna & Dominik J. Kubicki & Fan Fu & YeonJu Kim & Oussama Er-Raji & Tiankai Zhang & Lorenzo Baldinelli & Lu, 2024. "Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests," Nature Energy, Nature, vol. 9(2), pages 172-183, February.
    16. Tong Jin & Zheng Liu & Jiajun Luo & Jun-Hui Yuan & Hanqi Wang & Zuoxiang Xie & Weicheng Pan & Haodi Wu & Kan-Hao Xue & Linyue Liu & Zhanli Hu & Zhiping Zheng & Jiang Tang & Guangda Niu, 2023. "Self-wavelength shifting in two-dimensional perovskite for sensitive and fast gamma-ray detection," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    17. Susannah Holmes & Henry J. Kirkwood & Richard Bean & Klaus Giewekemeyer & Andrew V. Martin & Marjan Hadian-Jazi & Max O. Wiedorn & Dominik Oberthür & Hugh Marman & Luigi Adriano & Nasser Al-Qudami & S, 2022. "Megahertz pulse trains enable multi-hit serial femtosecond crystallography experiments at X-ray free electron lasers," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    18. Xiao Wang & Wenjing Sun & Huifang Shi & Huili Ma & Guowei Niu & Yuxin Li & Jiahuan Zhi & Xiaokang Yao & Zhicheng Song & Lei Chen & Shi Li & Guohui Yang & Zixing Zhou & Yixiao He & Shuli Qu & Min Wu & , 2022. "Organic phosphorescent nanoscintillator for low-dose X-ray-induced photodynamic therapy," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    19. Guillaume Tetreau & Michael R. Sawaya & Elke Zitter & Elena A. Andreeva & Anne-Sophie Banneville & Natalie A. Schibrowsky & Nicolas Coquelle & Aaron S. Brewster & Marie Luise Grünbein & Gabriela Nass , 2022. "De novo determination of mosquitocidal Cry11Aa and Cry11Ba structures from naturally-occurring nanocrystals," Nature Communications, Nature, vol. 13(1), pages 1-18, December.
    20. Hailei Zhang & Boyan Tang & Bo Zhang & Kai Huang & Shanshan Li & Yuangong Zhang & Haisong Zhang & Libin Bai & Yonggang Wu & Yongqiang Cheng & Yanmin Yang & Gang Han, 2024. "X-ray-activated polymerization expanding the frontiers of deep-tissue hydrogel formation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46712-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.