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Universal growth of perovskite thin monocrystals from high solute flux for sensitive self-driven X-ray detection

Author

Listed:
  • Da Liu

    (East China University of Science and Technology)

  • Yichu Zheng

    (Shanghai University)

  • Xin Yuan Sui

    (East China University of Science and Technology)

  • Xue Feng Wu

    (East China University of Science and Technology)

  • Can Zou

    (East China University of Science and Technology)

  • Yu Peng

    (East China University of Science and Technology)

  • Xinyi Liu

    (East China University of Science and Technology)

  • Miaoyu Lin

    (East China University of Science and Technology)

  • Zhanpeng Wei

    (East China University of Science and Technology)

  • Hang Zhou

    (East China Normal University)

  • Ye-Feng Yao

    (East China Normal University)

  • Sheng Dai

    (East China University of Science and Technology)

  • Haiyang Yuan

    (East China University of Science and Technology)

  • Hua Gui Yang

    (East China University of Science and Technology)

  • Shuang Yang

    (East China University of Science and Technology)

  • Yu Hou

    (East China University of Science and Technology)

Abstract

Metal-halide perovskite thin monocrystals featuring efficient carrier collection and transport capabilities are well suited for radiation detectors, yet their growth in a generic, well-controlled manner remains challenging. Here, we reveal that mass transfer is one major limiting factor during solution growth of perovskite thin monocrystals. A general approach is developed to overcome synthetic limitation by using a high solute flux system, in which mass diffusion coefficient is improved from 1.7×10–10 to 5.4×10–10 m2 s–1 by suppressing monomer aggregation. The generality of this approach is validated by the synthesis of 29 types of perovskite thin monocrystals at 40–90 °C with the growth velocity up to 27.2 μm min–1. The as-grown perovskite monocrystals deliver a high X-ray sensitivity of 1.74×105 µC Gy−1 cm−2 without applied bias. The findings regarding limited mass transfer and high-flux crystallization are crucial towards advancing the preparation and application of perovskite thin monocrystals.

Suggested Citation

  • Da Liu & Yichu Zheng & Xin Yuan Sui & Xue Feng Wu & Can Zou & Yu Peng & Xinyi Liu & Miaoyu Lin & Zhanpeng Wei & Hang Zhou & Ye-Feng Yao & Sheng Dai & Haiyang Yuan & Hua Gui Yang & Shuang Yang & Yu Hou, 2024. "Universal growth of perovskite thin monocrystals from high solute flux for sensitive self-driven X-ray detection," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46712-y
    DOI: 10.1038/s41467-024-46712-y
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