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Light-induced Kondo-like exciton-spin interaction in neodymium(II) doped hybrid perovskite

Author

Listed:
  • Xudong Xiao

    (Northern Illinois University)

  • Kyaw Zin Latt

    (Argonne National Laboratory)

  • Jue Gong

    (Northern Illinois University)

  • Taewoo Kim

    (Argonne National Laboratory)

  • Justin G. Connell

    (Argonne National Laboratory)

  • Yuzi Liu

    (Argonne National Laboratory)

  • H. Christopher Fry

    (Argonne National Laboratory)

  • John E. Pearson

    (Argonne National Laboratory)

  • Owen S. Wostoupal

    (Northern Illinois University)

  • Mengyuan Li

    (Northern Illinois University)

  • Calvin Soldan

    (Northern Illinois University)

  • Zhenzhen Yang

    (Argonne National Laboratory)

  • Richard D. Schaller

    (Argonne National Laboratory)

  • Benjamin T. Diroll

    (Argonne National Laboratory)

  • Saw Wai Hla

    (Argonne National Laboratory)

  • Tao Xu

    (Northern Illinois University)

Abstract

Tuning the properties of a pair of entangled electron and hole in a light-induced exciton is a fundamentally intriguing inquiry for quantum science. Here, using semiconducting hybrid perovskite as an exploratory platform, we discover that Nd2+-doped CH3NH3PbI3 (MAPbI3) perovskite exhibits a Kondo-like exciton-spin interaction under cryogenic and photoexcitation conditions. The feedback to such interaction between excitons in perovskite and the localized spins in Nd2+ is observed as notably prolonged carrier lifetimes measured by time-resolved photoluminescence, ~10 times to that of pristine MAPbI3 without Nd2+ dopant. From a mechanistic standpoint, such extended charge separation states are the consequence of the trap state enabled by the antiferromagnetic exchange interaction between the light-induced exciton and the localized 4 f spins of the Nd2+ in the proximity. Importantly, this Kondo-like exciton-spin interaction can be modulated by either increasing Nd2+ doping concentration that enhances the coupling between the exciton and Nd2+ 4 f spins as evidenced by elongated carrier lifetime, or by using an external magnetic field that can nullify the spin-dependent exchange interaction therein due to the unified orientations of Nd2+ spin angular momentum, thereby leading to exciton recombination at the dynamics comparable to pristine MAPbI3.

Suggested Citation

  • Xudong Xiao & Kyaw Zin Latt & Jue Gong & Taewoo Kim & Justin G. Connell & Yuzi Liu & H. Christopher Fry & John E. Pearson & Owen S. Wostoupal & Mengyuan Li & Calvin Soldan & Zhenzhen Yang & Richard D., 2024. "Light-induced Kondo-like exciton-spin interaction in neodymium(II) doped hybrid perovskite," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50196-1
    DOI: 10.1038/s41467-024-50196-1
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    References listed on IDEAS

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    2. D. Goldhaber-Gordon & Hadas Shtrikman & D. Mahalu & David Abusch-Magder & U. Meirav & M. A. Kastner, 1998. "Kondo effect in a single-electron transistor," Nature, Nature, vol. 391(6663), pages 156-159, January.
    3. Adam D. Wright & Carla Verdi & Rebecca L. Milot & Giles E. Eperon & Miguel A. Pérez-Osorio & Henry J. Snaith & Feliciano Giustino & Michael B. Johnston & Laura M. Herz, 2016. "Electron–phonon coupling in hybrid lead halide perovskites," Nature Communications, Nature, vol. 7(1), pages 1-9, September.
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