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A promising perovskite primary explosive

Author

Listed:
  • Yongan Feng

    (North University of China)

  • Jichuan Zhang

    (University of Idaho)

  • Weiguo Cao

    (North University of China)

  • Jiaheng Zhang

    (Harbin Institute of Technology)

  • Jean’ne M. Shreeve

    (University of Idaho)

Abstract

A primary explosive is an ideal chemical substance for performing ignition in military and commercial applications. For over 150 years, nearly all of the developed primary explosives have suffered from various issues, such as troublesome syntheses, high toxicity, poor stability or/and weak ignition performance. Now we report an interesting example of a primary explosive with double perovskite framework, {(C6H14N2)2[Na(NH4)(IO4)6]}n (DPPE-1), which was synthesized using a simple green one-pot method in an aqueous solution at room temperature. DPPE-1 is free of heavy metals, toxic organic components, and doesn’t involve any explosive precursors. It exhibits good stability towards air, moisture, sunlight, and heat and has acceptable mechanical sensitivities. It affords ignition performance on par with the most powerful primary explosives reported to date. DPPE-1 promises to meet the challenges existing with current primary explosives, and this work could trigger more extensive applications of perovskite.

Suggested Citation

  • Yongan Feng & Jichuan Zhang & Weiguo Cao & Jiaheng Zhang & Jean’ne M. Shreeve, 2023. "A promising perovskite primary explosive," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43320-0
    DOI: 10.1038/s41467-023-43320-0
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    1. Qiushui Chen & Jing Wu & Xiangyu Ou & Bolong Huang & Jawaher Almutlaq & Ayan A. Zhumekenov & Xinwei Guan & Sanyang Han & Liangliang Liang & Zhigao Yi & Juan Li & Xiaoji Xie & Yu Wang & Ying Li & Diany, 2018. "All-inorganic perovskite nanocrystal scintillators," Nature, Nature, vol. 561(7721), pages 88-93, September.
    2. Mucong Deng & Yongan Feng & Wenquan Zhang & Xiujuan Qi & Qinghua Zhang, 2019. "A green metal-free fused-ring initiating substance," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    3. Hyun-Sung Yun & Hyoung Woo Kwon & Min Jae Paik & Sungtak Hong & Jaehui Kim & Eunseo Noh & Jaewang Park & Yonghui Lee & Sang Seok, 2022. "Ethanol-based green-solution processing of α-formamidinium lead triiodide perovskite layers," Nature Energy, Nature, vol. 7(9), pages 828-834, September.
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