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Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides

Author

Listed:
  • Wenhe Xie

    (Fudan University
    Chinese Academy of Sciences)

  • Yuan Ren

    (Fudan University)

  • Fengluan Jiang

    (Fudan University)

  • Xin-Yu Huang

    (Fudan University)

  • Bingjie Yu

    (Fudan University)

  • Jianhong Liu

    (Fudan University)

  • Jichun Li

    (Fudan University)

  • Keyu Chen

    (Fudan University)

  • Yidong Zou

    (Fudan University)

  • Bingwen Hu

    (East China Normal University)

  • Yonghui Deng

    (Fudan University
    Chinese Academy of Sciences)

Abstract

Organic-inorganic molecular assembly has led to numerous nano/mesostructured materials with fantastic properties, but it is dependent on and limited to the direct interaction between host organic structure-directing molecules and guest inorganic species. Here, we report a “solvent-pair surfactants” enabled assembly (SPEA) method to achieve a general synthesis of mesostructured materials requiring no direct host-guest interaction. Taking the synthesis of mesoporous metal oxides as an example, the dimethylformamide/water solvent pairs behave as surfactants and induce the formation of mesostructured polyoxometalates/copolymers nanocomposites, which can be converted into metal oxides. This SPEA method enables the synthesis of functional ordered mesoporous metal oxides with different pore sizes, structures, compositions and tailored pore-wall microenvironments that are difficult to access via conventional direct organic-inorganic assembly. Typically, nitrogen-doped mesoporous ε-WO3 with high specific surface area, uniform mesopores and stable framework is obtained and exhibits great application potentials such as gas sensing.

Suggested Citation

  • Wenhe Xie & Yuan Ren & Fengluan Jiang & Xin-Yu Huang & Bingjie Yu & Jianhong Liu & Jichun Li & Keyu Chen & Yidong Zou & Bingwen Hu & Yonghui Deng, 2023. "Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-44193-z
    DOI: 10.1038/s41467-023-44193-z
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