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An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries

Author

Listed:
  • Xiaowei Chi

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston
    Chinese Academy of Sciences)

  • Ye Zhang

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

  • Fang Hao

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

  • Steven Kmiec

    (Iowa State University)

  • Hui Dong

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

  • Rong Xu

    (Purdue University)

  • Kejie Zhao

    (Purdue University)

  • Qing Ai

    (Rice University)

  • Tanguy Terlier

    (Rice University)

  • Liang Wang

    (Northern Illinois University
    Beijing Institute of Technology)

  • Lihong Zhao

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

  • Liqun Guo

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

  • Jun Lou

    (Rice University)

  • Huolin L. Xin

    (University of California, Irvine)

  • Steve W. Martin

    (Iowa State University)

  • Yan Yao

    (Department of Electrical and Computer Engineering and Texas Center for Superconductivity at the University of Houston, University of Houston)

Abstract

All-solid-state sodium batteries (ASSSBs) are promising candidates for grid-scale energy storage. However, there are no commercialized ASSSBs yet, in part due to the lack of a low-cost, simple-to-fabricate solid electrolyte (SE) with electrochemical stability towards Na metal. In this work, we report a family of oxysulfide glass SEs (Na3PS4−xOx, where 0

Suggested Citation

  • Xiaowei Chi & Ye Zhang & Fang Hao & Steven Kmiec & Hui Dong & Rong Xu & Kejie Zhao & Qing Ai & Tanguy Terlier & Liang Wang & Lihong Zhao & Liqun Guo & Jun Lou & Huolin L. Xin & Steve W. Martin & Yan Y, 2022. "An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30517-y
    DOI: 10.1038/s41467-022-30517-y
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    References listed on IDEAS

    as
    1. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    2. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    3. Akitoshi Hayashi & Kousuke Noi & Atsushi Sakuda & Masahiro Tatsumisago, 2012. "Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries," Nature Communications, Nature, vol. 3(1), pages 1-5, January.
    4. Fudong Han & Andrew S. Westover & Jie Yue & Xiulin Fan & Fei Wang & Miaofang Chi & Donovan N. Leonard & Nancy J. Dudney & Howard Wang & Chunsheng Wang, 2019. "High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes," Nature Energy, Nature, vol. 4(3), pages 187-196, March.
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    Cited by:

    1. Ge Sun & Chenjie Lou & Boqian Yi & Wanqing Jia & Zhixuan Wei & Shiyu Yao & Ziheng Lu & Gang Chen & Zexiang Shen & Mingxue Tang & Fei Du, 2023. "Electrochemically induced crystalline-to-amorphization transformation in sodium samarium silicate solid electrolyte for long-lasting sodium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Chengyu Fu & Yifan Li & Wenjie Xu & Xuyong Feng & Weijian Gu & Jue Liu & Wenwen Deng & Wei Wang & A. M. Milinda Abeykoon & Laisuo Su & Lingyun Zhu & Xiaojun Wu & Hongfa Xiang, 2024. "LaCl3-based sodium halide solid electrolytes with high ionic conductivity for all-solid-state batteries," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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