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Evolving contact mechanics and microstructure formation dynamics of the lithium metal-Li7La3Zr2O12 interface

Author

Listed:
  • Wesley Chang

    (Princeton University
    Princeton University
    Columbia University
    Columbia University)

  • Richard May

    (Columbia University
    Columbia University)

  • Michael Wang

    (University of Michigan)

  • Gunnar Thorsteinsson

    (Columbia University)

  • Jeff Sakamoto

    (University of Michigan
    University of Michigan)

  • Lauren Marbella

    (Columbia University
    Columbia University)

  • Daniel Steingart

    (Columbia University
    Columbia University
    Columbia University)

Abstract

The dynamic behavior of the interface between the lithium metal electrode and a solid-state electrolyte plays a critical role in all-solid-state battery performance. The evolution of this interface throughout cycling involves multiscale mechanical and chemical heterogeneity at the micro- and nano-scale. These features are dependent on operating conditions such as current density and stack pressure. Here we report the coupling of operando acoustic transmission measurements with nuclear magnetic resonance spectroscopy and magnetic resonance imaging to correlate changes in interfacial mechanics (such as contact loss and crack formation) with the growth of lithium microstructures during cell cycling. Together, the techniques reveal the chemo-mechanical behavior that governs lithium metal and Li7La3Zr2O12 interfacial dynamics at various stack pressure regimes and with voltage polarization.

Suggested Citation

  • Wesley Chang & Richard May & Michael Wang & Gunnar Thorsteinsson & Jeff Sakamoto & Lauren Marbella & Daniel Steingart, 2021. "Evolving contact mechanics and microstructure formation dynamics of the lithium metal-Li7La3Zr2O12 interface," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-26632-x
    DOI: 10.1038/s41467-021-26632-x
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    References listed on IDEAS

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    4. Shasha Lv & Tomas Verhallen & Alexandros Vasileiadis & Frans Ooms & Yaolin Xu & Zhaolong Li & Zhengcao Li & Marnix Wagemaker, 2018. "Operando monitoring the lithium spatial distribution of lithium metal anodes," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    5. Michael J. Wang & Eric Carmona & Arushi Gupta & Paul Albertus & Jeff Sakamoto, 2020. "Enabling “lithium-free” manufacturing of pure lithium metal solid-state batteries through in situ plating," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
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    Cited by:

    1. Chao Zhu & Till Fuchs & Stefan A. L. Weber & Felix. H. Richter & Gunnar Glasser & Franjo Weber & Hans-Jürgen Butt & Jürgen Janek & Rüdiger Berger, 2023. "Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    2. V. Reisecker & F. Flatscher & L. Porz & C. Fincher & J. Todt & I. Hanghofer & V. Hennige & M. Linares-Moreau & P. Falcaro & S. Ganschow & S. Wenner & Y.-M. Chiang & J. Keckes & J. Fleig & D. Rettenwan, 2023. "Effect of pulse-current-based protocols on the lithium dendrite formation and evolution in all-solid-state batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Ziteng Liang & Yuxuan Xiang & Kangjun Wang & Jianping Zhu & Yanting Jin & Hongchun Wang & Bizhu Zheng & Zirong Chen & Mingming Tao & Xiangsi Liu & Yuqi Wu & Riqiang Fu & Chunsheng Wang & Martin Winter, 2023. "Understanding the failure process of sulfide-based all-solid-state lithium batteries via operando nuclear magnetic resonance spectroscopy," Nature Communications, Nature, vol. 14(1), pages 1-15, December.

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