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A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments

Author

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  • Zhi Chang

    (Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST))

  • Huijun Yang

    (Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
    Graduate School of System and Information Engineering, University of Tsukuba)

  • Xingyu Zhu

    (Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
    Graduate School of System and Information Engineering, University of Tsukuba)

  • Ping He

    (Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University)

  • Haoshen Zhou

    (Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
    Graduate School of System and Information Engineering, University of Tsukuba
    Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Microstructures, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University)

Abstract

Nanoconfined/sub-nanoconfined solvent molecules tend to undergo dramatic changes in their properties and behaviours. In this work, we find that unlike typical bulk liquid electrolytes, electrolytes confined in a sub-nanoscale environment (inside channels of a 6.5 Å metal-organic framework, defined as a quasi-solid electrolyte) exhibits unusual properties and behaviours: higher boiling points, highly aggregated configurations, decent lithium-ion conductivities, extended electrochemical voltage windows (approximately 5.4 volts versus Li/Li+) and nonflammability at high temperatures. We incorporate this interesting electrolyte into lithium-metal batteries (LMBs) and find that LMBs cycled in the quasi-solid electrolyte demonstrate an electrolyte interphase-free (CEI-free) cathode and dendrite-free Li-metal surface. Moreover, high-voltage LiNi0.8Co0.1Mn0.1O2//Li (NCM-811//Li with a high NCM-811 mass loading of 20 mg cm−2) pouch cells assemble with the quasi-solid electrolyte deliver highly stable electrochemical performances even at a high working temperature of 90 °C (171 mAh g−1 after 300 cycles, 89% capacity retention; 164 mAh g−1 after 100 cycles even after being damaged). This strategy for fabricating nonflammable and ultrastable quasi-solid electrolytes is promising for the development of safe and high-energy-density LIBs/LMBs for powering electronic devices under various practical working conditions.

Suggested Citation

  • Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29118-6
    DOI: 10.1038/s41467-022-29118-6
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    References listed on IDEAS

    as
    1. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    2. Jianming Zheng & Mark H. Engelhard & Donghai Mei & Shuhong Jiao & Bryant J. Polzin & Ji-Guang Zhang & Wu Xu, 2017. "Electrolyte additive enabled fast charging and stable cycling lithium metal batteries," Nature Energy, Nature, vol. 2(3), pages 1-8, March.
    3. Yuki Yamada & Kenji Usui & Keitaro Sodeyama & Seongjae Ko & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Hydrate-melt electrolytes for high-energy-density aqueous batteries," Nature Energy, Nature, vol. 1(10), pages 1-9, October.
    4. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    5. Jun Liu & Zhenan Bao & Yi Cui & Eric J. Dufek & John B. Goodenough & Peter Khalifah & Qiuyan Li & Bor Yann Liaw & Ping Liu & Arumugam Manthiram & Y. Shirley Meng & Venkat R. Subramanian & Michael F. T, 2019. "Pathways for practical high-energy long-cycling lithium metal batteries," Nature Energy, Nature, vol. 4(3), pages 180-186, March.
    6. Snehashis Choudhury & Rahul Mangal & Akanksha Agrawal & Lynden A. Archer, 2015. "A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
    7. Luhan Ye & Xin Li, 2021. "A dynamic stability design strategy for lithium metal solid state batteries," Nature, Nature, vol. 593(7858), pages 218-222, May.
    8. Jianhui Wang & Yuki Yamada & Keitaro Sodeyama & Ching Hua Chiang & Yoshitaka Tateyama & Atsuo Yamada, 2016. "Superconcentrated electrolytes for a high-voltage lithium-ion battery," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    9. Qifeng Zheng & Yuki Yamada & Rui Shang & Seongjae Ko & Yun-Yang Lee & Kijae Kim & Eiichi Nakamura & Atsuo Yamada, 2020. "A cyclic phosphate-based battery electrolyte for high voltage and safe operation," Nature Energy, Nature, vol. 5(4), pages 291-298, April.
    10. Shuhong Jiao & Xiaodi Ren & Ruiguo Cao & Mark H. Engelhard & Yuzi Liu & Dehong Hu & Donghai Mei & Jianming Zheng & Wengao Zhao & Qiuyan Li & Ning Liu & Brian D. Adams & Cheng Ma & Jun Liu & Ji-Guang Z, 2018. "Stable cycling of high-voltage lithium metal batteries in ether electrolytes," Nature Energy, Nature, vol. 3(9), pages 739-746, September.
    11. Jiangfeng Qian & Wesley A. Henderson & Wu Xu & Priyanka Bhattacharya & Mark Engelhard & Oleg Borodin & Ji-Guang Zhang, 2015. "High rate and stable cycling of lithium metal anode," Nature Communications, Nature, vol. 6(1), pages 1-9, May.
    12. Jian Feng Li & Yi Fan Huang & Yong Ding & Zhi Lin Yang & Song Bo Li & Xiao Shun Zhou & Feng Ru Fan & Wei Zhang & Zhi You Zhou & De Yin Wu & Bin Ren & Zhong Lin Wang & Zhong Qun Tian, 2010. "Shell-isolated nanoparticle-enhanced Raman spectroscopy," Nature, Nature, vol. 464(7287), pages 392-395, March.
    13. Chaojiang Niu & Hongkyung Lee & Shuru Chen & Qiuyan Li & Jason Du & Wu Xu & Ji-Guang Zhang & M. Stanley Whittingham & Jie Xiao & Jun Liu, 2019. "High-energy lithium metal pouch cells with limited anode swelling and long stable cycles," Nature Energy, Nature, vol. 4(7), pages 551-559, July.
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