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A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries

Author

Listed:
  • Lv Hu

    (University of Science and Technology of China)

  • Jinzhu Wang

    (University of Science and Technology of China)

  • Kai Wang

    (University of Science and Technology of China)

  • Zhenqi Gu

    (University of Science and Technology of China)

  • Zhiwei Xi

    (University of Science and Technology of China)

  • Hui Li

    (University of Science and Technology of China)

  • Fang Chen

    (University of Science and Technology of China)

  • Youxi Wang

    (University of Science and Technology of China)

  • Zhenyu Li

    (University of Science and Technology of China)

  • Cheng Ma

    (University of Science and Technology of China
    National Synchrotron Radiation Laboratory)

Abstract

To enable the development of all-solid-state batteries, an inorganic solid-state electrolyte should demonstrate high ionic conductivity (i.e., > 1 mS cm−1 at 25 °C), compressibility (e.g., > 90% density under 250−350 MPa), and cost-effectiveness (e.g.,

Suggested Citation

  • Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39522-1
    DOI: 10.1038/s41467-023-39522-1
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    References listed on IDEAS

    as
    1. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    2. Xiaowei Chi & Ye Zhang & Fang Hao & Steven Kmiec & Hui Dong & Rong Xu & Kejie Zhao & Qing Ai & Tanguy Terlier & Liang Wang & Lihong Zhao & Liqun Guo & Jun Lou & Huolin L. Xin & Steve W. Martin & Yan Y, 2022. "An electrochemically stable homogeneous glassy electrolyte formed at room temperature for all-solid-state sodium batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    3. Kai Wang & Qingyong Ren & Zhenqi Gu & Chaomin Duan & Jinzhu Wang & Feng Zhu & Yuanyuan Fu & Jipeng Hao & Jinfeng Zhu & Lunhua He & Chin-Wei Wang & Yingying Lu & Jie Ma & Cheng Ma, 2021. "A cost-effective and humidity-tolerant chloride solid electrolyte for lithium batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Longlong Wang & Ruicong Xie & Bingbing Chen & Xinrun Yu & Jun Ma & Chao Li & Zhiwei Hu & Xingwei Sun & Chengjun Xu & Shanmu Dong & Ting-Shan Chan & Jun Luo & Guanglei Cui & Liquan Chen, 2020. "In-situ visualization of the space-charge-layer effect on interfacial lithium-ion transport in all-solid-state batteries," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    5. Laidong Zhou & Tong-Tong Zuo & Chun Yuen Kwok & Se Young Kim & Abdeljalil Assoud & Qiang Zhang & Jürgen Janek & Linda F. Nazar, 2022. "High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes," Nature Energy, Nature, vol. 7(1), pages 83-93, January.
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    Cited by:

    1. Hui Pan & Lei Wang & Yu Shi & Chuanchao Sheng & Sixie Yang & Ping He & Haoshen Zhou, 2024. "A solid-state lithium-ion battery with micron-sized silicon anode operating free from external pressure," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Murukadas, Deepu & Cho, Yeonhwa & Lee, Woongki & Lee, Sooyong & Kim, Hwajeong & Kim, Youngkyoo, 2024. "Lithium supercapacitors with environmentally-friend water-processable solid-state hybrid electrolytes of zinc oxide/polymer/lithium hydroxide," Energy, Elsevier, vol. 290(C).
    3. Qidi Wang & Yunan Zhou & Xuelong Wang & Hao Guo & Shuiping Gong & Zhenpeng Yao & Fangting Wu & Jianlin Wang & Swapna Ganapathy & Xuedong Bai & Baohua Li & Chenglong Zhao & Jürgen Janek & Marnix Wagema, 2024. "Designing lithium halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Zhenyou Song & Tengrui Wang & Hua Yang & Wang Hay Kan & Yuwei Chen & Qian Yu & Likuo Wang & Yini Zhang & Yiming Dai & Huaican Chen & Wen Yin & Takashi Honda & Maxim Avdeev & Henghui Xu & Jiwei Ma & Yu, 2024. "Promoting high-voltage stability through local lattice distortion of halide solid electrolytes," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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