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Frenkel-defected monolayer MoS2 catalysts for efficient hydrogen evolution

Author

Listed:
  • Jie Xu

    (Soochow University)

  • Gonglei Shao

    (Hunan University
    Zhengzhou University)

  • Xuan Tang

    (East China University of Science & Technology)

  • Fang Lv

    (Soochow University)

  • Haiyan Xiang

    (Hunan University)

  • Changfei Jing

    (Tianjin University of Technology)

  • Song Liu

    (Hunan University)

  • Sheng Dai

    (East China University of Science & Technology)

  • Yanguang Li

    (Soochow University)

  • Jun Luo

    (Tianjin University of Technology)

  • Zhen Zhou

    (Zhengzhou University)

Abstract

Defect engineering is an effective strategy to improve the activity of two-dimensional molybdenum disulfide base planes toward electrocatalytic hydrogen evolution reaction. Here, we report a Frenkel-defected monolayer MoS2 catalyst, in which a fraction of Mo atoms in MoS2 spontaneously leave their places in the lattice, creating vacancies and becoming interstitials by lodging in nearby locations. Unique charge distributions are introduced in the MoS2 surface planes, and those interstitial Mo atoms are more conducive to H adsorption, thus greatly promoting the HER activity of monolayer MoS2 base planes. At the current density of 10 mA cm−2, the optimal Frenkel-defected monolayer MoS2 exhibits a lower overpotential (164 mV) than either pristine monolayer MoS2 surface plane (358 mV) or Pt-single-atom doped MoS2 (211 mV). This work provides insights into the structure-property relationship of point-defected MoS2 and highlights the advantages of Frenkel defects in tuning the catalytic performance of MoS2 materials.

Suggested Citation

  • Jie Xu & Gonglei Shao & Xuan Tang & Fang Lv & Haiyan Xiang & Changfei Jing & Song Liu & Sheng Dai & Yanguang Li & Jun Luo & Zhen Zhou, 2022. "Frenkel-defected monolayer MoS2 catalysts for efficient hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29929-7
    DOI: 10.1038/s41467-022-29929-7
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    References listed on IDEAS

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    1. Kang Jiang & Min Luo & Zhixiao Liu & Ming Peng & Dechao Chen & Ying-Rui Lu & Ting-Shan Chan & Frank M. F. Groot & Yongwen Tan, 2021. "Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
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    4. Yipeng Zang & Shuwen Niu & Yishang Wu & Xusheng Zheng & Jinyan Cai & Jian Ye & Yufang Xie & Yun Liu & Jianbin Zhou & Junfa Zhu & Xiaojing Liu & Gongming Wang & Yitai Qian, 2019. "Tuning orbital orientation endows molybdenum disulfide with exceptional alkaline hydrogen evolution capability," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
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    Cited by:

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    2. Gonglei Shao & Changfei Jing & Zhinan Ma & Yuanyuan Li & Weiqi Dang & Dong Guo & Manman Wu & Song Liu & Xu Zhang & Kun He & Yifei Yuan & Jun Luo & Sheng Dai & Jie Xu & Zhen Zhou, 2024. "Dynamic coordination engineering of 2D PhenPtCl2 nanosheets for superior hydrogen evolution," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Jie Xu & Xiong-Xiong Xue & Gonglei Shao & Changfei Jing & Sheng Dai & Kun He & Peipei Jia & Shun Wang & Yifei Yuan & Jun Luo & Jun Lu, 2023. "Atomic-level polarization in electric fields of defects for electrocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Hang Xia & Xiaoru Sang & Zhiwen Shu & Zude Shi & Zefen Li & Shasha Guo & Xiuyun An & Caitian Gao & Fucai Liu & Huigao Duan & Zheng Liu & Yongmin He, 2023. "The practice of reaction window in an electrocatalytic on-chip microcell," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Jing-Wen Hsueh & Lai-Hsiang Kuo & Po-Han Chen & Wan-Hsin Chen & Chi-Yao Chuang & Chia-Nung Kuo & Chin-Shan Lue & Yu-Ling Lai & Bo-Hong Liu & Chia-Hsin Wang & Yao-Jane Hsu & Chun-Liang Lin & Jyh-Pin Ch, 2024. "Investigating the role of undercoordinated Pt sites at the surface of layered PtTe2 for methanol decomposition," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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