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A durable and pH-universal self-standing MoC–Mo2C heterojunction electrode for efficient hydrogen evolution reaction

Author

Listed:
  • Wei Liu

    (Wuhan University
    Wuhan University)

  • Xiting Wang

    (Wuhan University)

  • Fan Wang

    (Wuhan University
    Wuhan University)

  • Kaifa Du

    (Wuhan University
    Wuhan University)

  • Zhaofu Zhang

    (University of Cambridge)

  • Yuzheng Guo

    (Wuhan University)

  • Huayi Yin

    (Wuhan University
    Wuhan University)

  • Dihua Wang

    (Wuhan University
    Wuhan University
    Wuhan University)

Abstract

Efficient water electrolyzers are constrained by the lack of low-cost and earth-abundant hydrogen evolution reaction (HER) catalysts that can operate at industry-level conditions and be prepared with a facile process. Here we report a self-standing MoC–Mo2C catalytic electrode prepared via a one-step electro-carbiding approach using CO2 as the feedstock. The outstanding HER performances of the MoC–Mo2C electrode with low overpotentials at 500 mA cm−2 in both acidic (256 mV) and alkaline electrolytes (292 mV), long-lasting lifetime of over 2400 h (100 d), and high-temperature performance (70 oC) are due to the self-standing hydrophilic porous surface, intrinsic mechanical strength and self-grown MoC (001)–Mo2C (101) heterojunctions that have a ΔGH* value of −0.13 eV in acidic condition, and the energy barrier of 1.15 eV for water dissociation in alkaline solution. The preparation of a large electrode (3 cm × 11.5 cm) demonstrates the possibility of scaling up this process to prepare various carbide electrodes with rationally designed structures, tunable compositions, and favorable properties.

Suggested Citation

  • Wei Liu & Xiting Wang & Fan Wang & Kaifa Du & Zhaofu Zhang & Yuzheng Guo & Huayi Yin & Dihua Wang, 2021. "A durable and pH-universal self-standing MoC–Mo2C heterojunction electrode for efficient hydrogen evolution reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27118-6
    DOI: 10.1038/s41467-021-27118-6
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    References listed on IDEAS

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    1. Yipeng Zang & Shuwen Niu & Yishang Wu & Xusheng Zheng & Jinyan Cai & Jian Ye & Yufang Xie & Yun Liu & Jianbin Zhou & Junfa Zhu & Xiaojing Liu & Gongming Wang & Yitai Qian, 2019. "Tuning orbital orientation endows molybdenum disulfide with exceptional alkaline hydrogen evolution capability," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    2. Yuting Luo & Lei Tang & Usman Khan & Qiangmin Yu & Hui-Ming Cheng & Xiaolong Zou & Bilu Liu, 2019. "Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    3. Jianfeng Huang & Nicolas Hörmann & Emad Oveisi & Anna Loiudice & Gian Luca De Gregorio & Oliviero Andreussi & Nicola Marzari & Raffaella Buonsanti, 2018. "Potential-induced nanoclustering of metallic catalysts during electrochemical CO2 reduction," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
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    Cited by:

    1. Brian C. Wyatt & Matthew G. Boebinger & Zachary D. Hood & Shiba Adhikari & Paweł Piotr Michałowski & Srinivasa Kartik Nemani & Murali Gopal Muraleedharan & Annabelle Bedford & Wyatt J. Highland & Paul, 2024. "Alkali cation stabilization of defects in 2D MXenes at ambient and elevated temperatures," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Jinjie Fang & Haiyong Wang & Qian Dang & Hao Wang & Xingdong Wang & Jiajing Pei & Zhiyuan Xu & Chengjin Chen & Wei Zhu & Hui Li & Yushan Yan & Zhongbin Zhuang, 2024. "Atomically dispersed Iridium on Mo2C as an efficient and stable alkaline hydrogen oxidation reaction catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Zhao, Meng-Jie & Li, Er-Mei & Deng, Ning & Hu, Yingjie & Li, Chao-Xiong & Li, Bing & Li, Fang & Guo, Zhen-Guo & He, Jian-Bo, 2022. "Indirect electrodeposition of a NiMo@Ni(OH)2MoOx composite catalyst for superior hydrogen production in acidic and alkaline electrolytes," Renewable Energy, Elsevier, vol. 191(C), pages 370-379.
    4. Liu, Haobo & Zhang, Yuqi & Ge, Riyue & Cairney, Julie M. & Zheng, Rongkun & Khan, Aslam & Li, Sean & Liu, Bin & Dai, Liming & Li, Wenxian, 2023. "Tailoring the electronic structure of Ni5P4/Ni2P catalyst by Co2P for efficient overall water electrolysis," Applied Energy, Elsevier, vol. 349(C).

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