IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-28869-6.html
   My bibliography  Save this article

Engineered assembly of water-dispersible nanocatalysts enables low-cost and green CO2 capture

Author

Listed:
  • Masood S. Alivand

    (The University of Melbourne)

  • Omid Mazaheri

    (The University of Melbourne
    The University of Melbourne)

  • Yue Wu

    (The University of Melbourne)

  • Ali Zavabeti

    (The University of Melbourne
    RMIT University)

  • Andrew J. Christofferson

    (RMIT University
    RMIT University)

  • Nastaran Meftahi

    (RMIT University)

  • Salvy P. Russo

    (RMIT University)

  • Geoffrey W. Stevens

    (The University of Melbourne)

  • Colin A. Scholes

    (The University of Melbourne)

  • Kathryn A. Mumford

    (The University of Melbourne)

Abstract

Catalytic solvent regeneration has attracted broad interest owing to its potential to reduce energy consumption in CO2 separation, enabling industry to achieve emission reduction targets of the Paris Climate Accord. Despite recent advances, the development of engineered acidic nanocatalysts with unique characteristics remains a challenge. Herein, we establish a strategy to tailor the physicochemical properties of metal-organic frameworks (MOFs) for the synthesis of water-dispersible core-shell nanocatalysts with ease of use. We demonstrate that functionalized nanoclusters (Fe3O4-COOH) effectively induce missing-linker deficiencies and fabricate mesoporosity during the self-assembly of MOFs. Superacid sites are created by introducing chelating sulfates on the uncoordinated metal clusters, providing high proton donation capability. The obtained nanomaterials drastically reduce the energy consumption of CO2 capture by 44.7% using only 0.1 wt.% nanocatalyst, which is a ∽10-fold improvement in efficiency compared to heterogeneous catalysts. This research represents a new avenue for the next generation of advanced nanomaterials in catalytic solvent regeneration.

Suggested Citation

  • Masood S. Alivand & Omid Mazaheri & Yue Wu & Ali Zavabeti & Andrew J. Christofferson & Nastaran Meftahi & Salvy P. Russo & Geoffrey W. Stevens & Colin A. Scholes & Kathryn A. Mumford, 2022. "Engineered assembly of water-dispersible nanocatalysts enables low-cost and green CO2 capture," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28869-6
    DOI: 10.1038/s41467-022-28869-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-28869-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-28869-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. G. P. Peters & R. M. Andrew & J. G. Canadell & P. Friedlingstein & R. B. Jackson & J. I. Korsbakken & C. Quéré & A. Peregon, 2020. "Carbon dioxide emissions continue to grow amidst slowly emerging climate policies," Nature Climate Change, Nature, vol. 10(1), pages 3-6, January.
    2. Alivand, Masood S. & Mazaheri, Omid & Wu, Yue & Stevens, Geoffrey W. & Scholes, Colin A. & Mumford, Kathryn A., 2019. "Development of aqueous-based phase change amino acid solvents for energy-efficient CO2 capture: The role of antisolvent," Applied Energy, Elsevier, vol. 256(C).
    3. Yi-Ming Wei & Rong Han & Ce Wang & Biying Yu & Qiao-Mei Liang & Xiao-Chen Yuan & Junjie Chang & Qingyu Zhao & Hua Liao & Baojun Tang & Jinyue Yan & Lijing Cheng & Zili Yang, 2020. "Self-preservation strategy for approaching global warming targets in the post-Paris Agreement era," Nature Communications, Nature, vol. 11(1), pages 1-13, December.
    4. Qinghua Lai & Sam Toan & Mohammed A. Assiri & Huaigang Cheng & Armistead G. Russell & Hertanto Adidharma & Maciej Radosz & Maohong Fan, 2018. "Catalyst-TiO(OH)2 could drastically reduce the energy consumption of CO2 capture," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    5. Yi-Ming Wei & Jia-Ning Kang & Lan-Cui Liu & Qi Li & Peng-Tao Wang & Juan-Juan Hou & Qiao-Mei Liang & Hua Liao & Shi-Feng Huang & Biying Yu, 2021. "A proposed global layout of carbon capture and storage in line with a 2 °C climate target," Nature Climate Change, Nature, vol. 11(2), pages 112-118, February.
    6. Hao Wang & Xinglong Dong & Junzhong Lin & Simon J. Teat & Stephanie Jensen & Jeremy Cure & Eugeny V. Alexandrov & Qibin Xia & Kui Tan & Qining Wang & David H. Olson & Davide M. Proserpio & Yves J. Cha, 2018. "Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    7. B. H. Samset & J. S. Fuglestvedt & M. T. Lund, 2020. "Delayed emergence of a global temperature response after emission mitigation," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    8. Pieter Pauw & Kennedy Mbeva & Harro Asselt, 2019. "Subtle differentiation of countries’ responsibilities under the Paris Agreement," Palgrave Communications, Palgrave Macmillan, vol. 5(1), pages 1-7, December.
    9. Giulia Realmonte & Laurent Drouet & Ajay Gambhir & James Glynn & Adam Hawkes & Alexandre C. Köberle & Massimo Tavoni, 2019. "An inter-model assessment of the role of direct air capture in deep mitigation pathways," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ángel Galán-Martín & Daniel Vázquez & Selene Cobo & Niall Dowell & José Antonio Caballero & Gonzalo Guillén-Gosálbez, 2021. "Delaying carbon dioxide removal in the European Union puts climate targets at risk," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    2. Kang, Jia-Ning & Wei, Yi-Ming & Liu, Lan-cui & Wang, Jin-Wei, 2021. "Observing technology reserves of carbon capture and storage via patent data: Paving the way for carbon neutral," Technological Forecasting and Social Change, Elsevier, vol. 171(C).
    3. Ayomikun Bello & Anastasia Ivanova & Alexey Cheremisin, 2023. "A Comprehensive Review of the Role of CO 2 Foam EOR in the Reduction of Carbon Footprint in the Petroleum Industry," Energies, MDPI, vol. 16(3), pages 1-20, January.
    4. Shi, Changfeng & Zhi, Jiaqi & Yao, Xiao & Zhang, Hong & Yu, Yue & Zeng, Qingshun & Li, Luji & Zhang, Yuxi, 2023. "How can China achieve the 2030 carbon peak goal—a crossover analysis based on low-carbon economics and deep learning," Energy, Elsevier, vol. 269(C).
    5. Ayami Hayashi & Fuminori Sano & Takashi Homma & Keigo Akimoto, 2023. "Mitigating trade-offs between global food access and net-zero emissions: the potential contribution of direct air carbon capture and storage," Climatic Change, Springer, vol. 176(5), pages 1-19, May.
    6. Zhuyuan Wang & Ting Hu & Mike Tebyetekerwa & Xiangkang Zeng & Fan Du & Yuan Kang & Xuefeng Li & Hao Zhang & Huanting Wang & Xiwang Zhang, 2024. "Electricity generation from carbon dioxide adsorption by spatially nanoconfined ion separation," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    7. Jing-Li Fan & Zezheng Li & Xi Huang & Kai Li & Xian Zhang & Xi Lu & Jianzhong Wu & Klaus Hubacek & Bo Shen, 2023. "A net-zero emissions strategy for China’s power sector using carbon-capture utilization and storage," Nature Communications, Nature, vol. 14(1), pages 1-16, December.
    8. Zhou, Yuzhou & Zhao, Jiexing & Zhai, Qiaozhu, 2021. "100% renewable energy: A multi-stage robust scheduling approach for cascade hydropower system with wind and photovoltaic power," Applied Energy, Elsevier, vol. 301(C).
    9. Salman, Muhammad & Long, Xingle & Wang, Guimei & Zha, Donglan, 2022. "Paris climate agreement and global environmental efficiency: New evidence from fuzzy regression discontinuity design," Energy Policy, Elsevier, vol. 168(C).
    10. Michael Mugarura & Wolfgang Stümer & Karsten Dunger & Andreas Bolte & Matt Ramlow & Emmanuel Ackom & Steffi Röhling, 2021. "Ascription of the differences between Germany and Uganda’s Land Use, Land-Use Change, and Forestry sector greenhouse gas methodologies for inventory improvement," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 26(6), pages 1-30, August.
    11. Xu, Liang & Li, Qi & Myers, Matthew & Cao, Xiaomin, 2023. "Investigation of the enhanced oil recovery mechanism of CO2 synergistically with nanofluid in tight glutenite," Energy, Elsevier, vol. 273(C).
    12. Li, Yan & Feng, Tian-tian & Liu, Li-li & Zhang, Meng-xi, 2023. "How do the electricity market and carbon market interact and achieve integrated development?--A bibliometric-based review," Energy, Elsevier, vol. 265(C).
    13. Changwan Gu & Jingjing Xie & Xiaoyu Li & Xu Gao, 2023. "Levelized Cost Analysis for Blast Furnace CO 2 Capture, Utilization, and Storage Retrofit in China’s Blast Furnace–Basic Oxygen Furnace Steel Plants," Energies, MDPI, vol. 16(23), pages 1-20, November.
    14. Kemfert, Claudia & Präger, Fabian & Braunger, Isabell & Hoffart, Franziska M. & Brauers, Hanna, 2022. "The expansion of natural gas infrastructure puts energy transitions at risk," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 7, pages 582-587.
    15. Jin, Gui & Shi, Xin & Zhang, Lei & Hu, Shougeng, 2020. "Measuring the SCCs of different Chinese regions under future scenarios," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    16. Zhang, Hongji & Ding, Tao & Sun, Yuge & Huang, Yuhan & He, Yuankang & Huang, Can & Li, Fangxing & Xue, Chen & Sun, Xiaoqiang, 2023. "How does load-side re-electrification help carbon neutrality in energy systems: Cost competitiveness analysis and life-cycle deduction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    17. Pantelitsa Loizia & Irene Voukkali & Georgia Chatziparaskeva & Jose Navarro-Pedreño & Antonis A. Zorpas, 2021. "Measuring the Level of Environmental Performance on Coastal Environment before and during the COVID-19 Pandemic: A Case Study from Cyprus," Sustainability, MDPI, vol. 13(5), pages 1-24, February.
    18. Duncan McLaren & Olaf Corry, 2021. "Clash of Geofutures and the Remaking of Planetary Order: Faultlines underlying Conflicts over Geoengineering Governance," Global Policy, London School of Economics and Political Science, vol. 12(S1), pages 20-33, April.
    19. Pedro Macedo & Mara Madaleno, 2022. "Global Temperature and Carbon Dioxide Nexus: Evidence from a Maximum Entropy Approach," Energies, MDPI, vol. 16(1), pages 1-13, December.
    20. Jing, Jing & Yang, Yanlin & Cheng, Jianmei & Ding, Zhaojing & Wang, Dandan & Jing, Xianwen, 2023. "Analysis of the effect of formation dip angle and injection pressure on the injectivity and migration of CO2 during storage," Energy, Elsevier, vol. 280(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28869-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.