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Ultramicroporous material based parallel and extended paraffin nano-trap for benchmark olefin purification

Author

Listed:
  • Peixin Zhang

    (Zhejiang University
    ZJU-Hangzhou Global Scientific and Technological Innovation Center)

  • Lifeng Yang

    (Zhejiang University)

  • Xing Liu

    (Nanchang University)

  • Jun Wang

    (Nanchang University)

  • Xian Suo

    (ZJU-Hangzhou Global Scientific and Technological Innovation Center)

  • Liyuan Chen

    (Zhejiang University)

  • Xili Cui

    (Zhejiang University
    ZJU-Hangzhou Global Scientific and Technological Innovation Center)

  • Huabin Xing

    (Zhejiang University
    ZJU-Hangzhou Global Scientific and Technological Innovation Center)

Abstract

Selective paraffin capture from olefin/paraffin mixtures could afford high-purity olefins directly, but suffers from the issues of low separation selectivity and olefin productivity. Herein, we report an ultramicroporous material (PCP-IPA) with parallel-aligned linearly extending isophthalic acid units along the one-dimensional channel, realizing the efficient production of ultra-high purity C2H4 and C3H6 (99.99%). The periodically expanded and parallel-aligned aromatic-based units served as a paraffin nano-trap to contact with the exposed hydrogen atoms of both C2H6 and C3H8, as demonstrated by the simulation studies. PCP-IPA exhibits record separation selectivity of 2.48 and separation potential of 1.20 mol/L for C3H8/C3H6 (50/50) mixture, meanwhile the excellent C2H6/C2H4 mixture separation performance. Ultra-high purity C3H6 (99.99%) and C2H4 (99.99%) can be directly obtained through fixed-bed column from C3H8/C3H6 and C2H6/C2H4 mixtures, respectively. The record C3H6 productivity is up to 15.23 L/kg from the equimolar of C3H8/C3H6, which is 3.85 times of the previous benchmark material, demonstrating its great potential for those important industrial separations.

Suggested Citation

  • Peixin Zhang & Lifeng Yang & Xing Liu & Jun Wang & Xian Suo & Liyuan Chen & Xili Cui & Huabin Xing, 2022. "Ultramicroporous material based parallel and extended paraffin nano-trap for benchmark olefin purification," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32677-3
    DOI: 10.1038/s41467-022-32677-3
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    References listed on IDEAS

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    1. David S. Sholl & Ryan P. Lively, 2016. "Seven chemical separations to change the world," Nature, Nature, vol. 532(7600), pages 435-437, April.
    2. Jun Wang & Yan Zhang & Yun Su & Xing Liu & Peixin Zhang & Rui-Biao Lin & Shixia Chen & Qiang Deng & Zheling Zeng & Shuguang Deng & Banglin Chen, 2022. "Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Jian-Wei Cao & Soumya Mukherjee & Tony Pham & Yu Wang & Teng Wang & Tao Zhang & Xue Jiang & Hui-Juan Tang & Katherine A. Forrest & Brian Space & Michael J. Zaworotko & Kai-Jie Chen, 2021. "One-step ethylene production from a four-component gas mixture by a single physisorbent," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    4. Hao Wang & Xinglong Dong & Junzhong Lin & Simon J. Teat & Stephanie Jensen & Jeremy Cure & Eugeny V. Alexandrov & Qibin Xia & Kui Tan & Qining Wang & David H. Olson & Davide M. Proserpio & Yves J. Cha, 2018. "Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    5. Heng Zeng & Mo Xie & Ting Wang & Rong-Jia Wei & Xiao-Jing Xie & Yifang Zhao & Weigang Lu & Dan Li, 2021. "Orthogonal-array dynamic molecular sieving of propylene/propane mixtures," Nature, Nature, vol. 595(7868), pages 542-548, July.
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    Cited by:

    1. Yunjia Jiang, & Yongqi Hu, & Binquan Luan, & Lingyao Wang, & Rajamani Krishna, & Haofei Ni, & Xin Hu & Yuanbin Zhang, 2023. "Benchmark single-step ethylene purification from ternary mixtures by a customized fluorinated anion-embedded MOF," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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