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Holistic approach for sequential transesterification and pyrolysis of microalgal biomass: Kinetic and thermodynamic analysis of pyrolysis using model-free and model-based approaches

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  • Bharti, Bhawana
  • Kandpal, Saurav
  • Sawarkar, Ashish N.
  • Patle, Dipesh S.

Abstract

Due to the renewability and sustainability, biofuels derived from algae are considered as competitive substitutes for fossil fuels. Present study investigated a holistic approach for sequential transesterification and pyrolysis of microalgal biomass, i.e. Chlorella minutissima. This study explores the complete utilization of algal biomass through sequential chemical (transesterification) and thermochemical (pyrolysis) processes. First, the lipids were extracted and converted to eco-friendly biodiesel using catalytic route. Then lipid-extracted microalgae were pyrolyzed via thermogravimetric analyzer at four heating rates, namely 5, 10, 20 and 30 °C/min. The model-free isoconversional Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), and Vyazovkin models were used to analyze the kinetics and thermodynamics of algal pyrolysis. The activation energy obtained for the pyrolysis of Chlorella minutissima utilizing KAS, FWO and Vyazovkin were 146.78, 148.86, 147.11 kJ/mol, respectively. Positive ΔH values from KAS, FWO, and Vyazovkin show an endothermic nature of the process. The mean ΔH was found to be 142.81, 143.97, and 142.82 kJ/mol, while the ΔG was 151.9, 152.20, and 161.40 kJ/mol, respectively for KAS, FWO, and Vyazovkin approaches, at 10 °C/min heating rate. Importantly, this study also revealed that the phase interfacial model was the most appropriate model to represent the degradation process using Coats-Redfern method at 5 oC

Suggested Citation

  • Bharti, Bhawana & Kandpal, Saurav & Sawarkar, Ashish N. & Patle, Dipesh S., 2024. "Holistic approach for sequential transesterification and pyrolysis of microalgal biomass: Kinetic and thermodynamic analysis of pyrolysis using model-free and model-based approaches," Renewable Energy, Elsevier, vol. 235(C).
    • Handle: RePEc:eee:renene:v:235:y:2024:i:c:s0960148124013879
    DOI: 10.1016/j.renene.2024.121319
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    1. Badshah, Syed Lal & Shah, Zahir & Francisco Alves, José Luiz & Gomes da Silva, Jean Constantino & Iqbal, Arshad, 2021. "Pyrolysis of the freshwater macroalgae Spirogyra crassa: Evaluating its bioenergy potential using kinetic triplet and thermodynamic parameters," Renewable Energy, Elsevier, vol. 179(C), pages 1169-1178.
    2. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    3. Malinauskaite, J. & Jouhara, H. & Czajczyńska, D. & Stanchev, P. & Katsou, E. & Rostkowski, P. & Thorne, R.J. & Colón, J. & Ponsá, S. & Al-Mansour, F. & Anguilano, L. & Krzyżyńska, R. & López, I.C. & , 2017. "Municipal solid waste management and waste-to-energy in the context of a circular economy and energy recycling in Europe," Energy, Elsevier, vol. 141(C), pages 2013-2044.
    4. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    5. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    6. Liang, Yue-gan & Cheng, Beijiu & Si, You-bin & Cao, De-ju & Jiang, Hai-yang & Han, Guo-min & Liu, Xiao-hong, 2014. "Thermal decomposition kinetics and characteristics of Spartina alterniflora via thermogravimetric analysis," Renewable Energy, Elsevier, vol. 68(C), pages 111-117.
    7. Sharma, Ajay & Aravind Kumar, A. & Mohanty, Bikash & Sawarkar, Ashish N., 2023. "Critical insights into pyrolysis and co-pyrolysis of poplar and eucalyptus wood sawdust: Physico-chemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis," Renewable Energy, Elsevier, vol. 210(C), pages 321-334.
    8. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Pyrolysis of three different types of microalgae: Kinetic and evolved gas analysis," Energy, Elsevier, vol. 73(C), pages 33-43.
    9. Patel, Madhumita & Zhang, Xiaolei & Kumar, Amit, 2016. "Techno-economic and life cycle assessment on lignocellulosic biomass thermochemical conversion technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1486-1499.
    10. Alexandre Tisserant & Stefan Pauliuk & Stefano Merciai & Jannick Schmidt & Jacob Fry & Richard Wood & Arnold Tukker, 2017. "Solid Waste and the Circular Economy: A Global Analysis of Waste Treatment and Waste Footprints," Journal of Industrial Ecology, Yale University, vol. 21(3), pages 628-640, June.
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