IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v235y2024ics0960148124013879.html
   My bibliography  Save this article

Holistic approach for sequential transesterification and pyrolysis of microalgal biomass: Kinetic and thermodynamic analysis of pyrolysis using model-free and model-based approaches

Author

Listed:
  • Bharti, Bhawana
  • Kandpal, Saurav
  • Sawarkar, Ashish N.
  • Patle, Dipesh S.

Abstract

Due to the renewability and sustainability, biofuels derived from algae are considered as competitive substitutes for fossil fuels. Present study investigated a holistic approach for sequential transesterification and pyrolysis of microalgal biomass, i.e. Chlorella minutissima. This study explores the complete utilization of algal biomass through sequential chemical (transesterification) and thermochemical (pyrolysis) processes. First, the lipids were extracted and converted to eco-friendly biodiesel using catalytic route. Then lipid-extracted microalgae were pyrolyzed via thermogravimetric analyzer at four heating rates, namely 5, 10, 20 and 30 °C/min. The model-free isoconversional Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (FWO), and Vyazovkin models were used to analyze the kinetics and thermodynamics of algal pyrolysis. The activation energy obtained for the pyrolysis of Chlorella minutissima utilizing KAS, FWO and Vyazovkin were 146.78, 148.86, 147.11 kJ/mol, respectively. Positive ΔH values from KAS, FWO, and Vyazovkin show an endothermic nature of the process. The mean ΔH was found to be 142.81, 143.97, and 142.82 kJ/mol, while the ΔG was 151.9, 152.20, and 161.40 kJ/mol, respectively for KAS, FWO, and Vyazovkin approaches, at 10 °C/min heating rate. Importantly, this study also revealed that the phase interfacial model was the most appropriate model to represent the degradation process using Coats-Redfern method at 5 oC

Suggested Citation

  • Bharti, Bhawana & Kandpal, Saurav & Sawarkar, Ashish N. & Patle, Dipesh S., 2024. "Holistic approach for sequential transesterification and pyrolysis of microalgal biomass: Kinetic and thermodynamic analysis of pyrolysis using model-free and model-based approaches," Renewable Energy, Elsevier, vol. 235(C).
    • Handle: RePEc:eee:renene:v:235:y:2024:i:c:s0960148124013879
    DOI: 10.1016/j.renene.2024.121319
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148124013879
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2024.121319?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Badshah, Syed Lal & Shah, Zahir & Francisco Alves, José Luiz & Gomes da Silva, Jean Constantino & Iqbal, Arshad, 2021. "Pyrolysis of the freshwater macroalgae Spirogyra crassa: Evaluating its bioenergy potential using kinetic triplet and thermodynamic parameters," Renewable Energy, Elsevier, vol. 179(C), pages 1169-1178.
    2. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    3. Malinauskaite, J. & Jouhara, H. & Czajczyńska, D. & Stanchev, P. & Katsou, E. & Rostkowski, P. & Thorne, R.J. & Colón, J. & Ponsá, S. & Al-Mansour, F. & Anguilano, L. & Krzyżyńska, R. & López, I.C. & , 2017. "Municipal solid waste management and waste-to-energy in the context of a circular economy and energy recycling in Europe," Energy, Elsevier, vol. 141(C), pages 2013-2044.
    4. Sharma, Ajay & Aravind Kumar, A. & Mohanty, Bikash & Sawarkar, Ashish N., 2023. "Critical insights into pyrolysis and co-pyrolysis of poplar and eucalyptus wood sawdust: Physico-chemical characterization, kinetic triplets, reaction mechanism, and thermodynamic analysis," Renewable Energy, Elsevier, vol. 210(C), pages 321-334.
    5. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Pyrolysis of three different types of microalgae: Kinetic and evolved gas analysis," Energy, Elsevier, vol. 73(C), pages 33-43.
    6. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    7. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    8. Liang, Yue-gan & Cheng, Beijiu & Si, You-bin & Cao, De-ju & Jiang, Hai-yang & Han, Guo-min & Liu, Xiao-hong, 2014. "Thermal decomposition kinetics and characteristics of Spartina alterniflora via thermogravimetric analysis," Renewable Energy, Elsevier, vol. 68(C), pages 111-117.
    9. Patel, Madhumita & Zhang, Xiaolei & Kumar, Amit, 2016. "Techno-economic and life cycle assessment on lignocellulosic biomass thermochemical conversion technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1486-1499.
    10. Alexandre Tisserant & Stefan Pauliuk & Stefano Merciai & Jannick Schmidt & Jacob Fry & Richard Wood & Arnold Tukker, 2017. "Solid Waste and the Circular Economy: A Global Analysis of Waste Treatment and Waste Footprints," Journal of Industrial Ecology, Yale University, vol. 21(3), pages 628-640, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhai, Jihua & Burke, Ian T. & Stewart, Douglas I., 2021. "Beneficial management of biomass combustion ashes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    2. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    3. Tariq Javed & Fareyha Said & Dalilawati Zainal & Azlina Abdul Jalil, 2024. "Circular Economy Implementation Status of Selected ASEAN Countries," SAGE Open, , vol. 14(1), pages 21582440231, March.
    4. Philip A. Tominac & Victor M. Zavala, 2020. "Economic Properties of Multi-Product Supply Chains," Papers 2006.03467, arXiv.org, revised Jul 2020.
    5. Di Foggia, Giacomo & Beccarello, Massimo, 2021. "Designing waste management systems to meet circular economy goals: The Italian case," SocArXiv qjcuv, Center for Open Science.
    6. Yang, Lan & Wang, Xue-Chao & Dai, Min & Chen, Bin & Qiao, Yuanbo & Deng, Huijing & Zhang, Dingfan & Zhang, Yizhe & Villas Bôas de Almeida, Cecília Maria & Chiu, Anthony S.F. & Klemeš, Jiří Jaromír & W, 2021. "Shifting from fossil-based economy to bio-based economy: Status quo, challenges, and prospects," Energy, Elsevier, vol. 228(C).
    7. Grzegorz Wielgosiński & Justyna Czerwińska & Szymon Szufa, 2021. "Municipal Solid Waste Mass Balance as a Tool for Calculation of the Possibility of Implementing the Circular Economy Concept," Energies, MDPI, vol. 14(7), pages 1-25, March.
    8. Di Foggia, Giacomo & Beccarello, Massimo, 2021. "Designing waste management systems to meet circular economy goals: The Italian case," SocArXiv qjcuv_v1, Center for Open Science.
    9. Anna Rolewicz-Kalińska & Krystyna Lelicińska-Serafin & Piotr Manczarski, 2020. "The Circular Economy and Organic Fraction of Municipal Solid Waste Recycling Strategies," Energies, MDPI, vol. 13(17), pages 1-20, August.
    10. Kamila Klimek & Magdalena Kapłan & Serhiy Syrotyuk & Nikolay Bakach & Nikolay Kapustin & Ryszard Konieczny & Jakub Dobrzyński & Kinga Borek & Dorota Anders & Barbara Dybek & Agnieszka Karwacka & Grzeg, 2021. "Investment Model of Agricultural Biogas Plants for Individual Farms in Poland," Energies, MDPI, vol. 14(21), pages 1-30, November.
    11. Rybaczewska-Błażejowska Magdalena & Mazurek Damian & Mazur Marcin, 2022. "Life Cycle Sustainability Assessment of Decentralised Composting of Bio-Waste: A Case Study of The Łódź Agglomeration (Poland)," Quaestiones Geographicae, Sciendo, vol. 41(4), pages 89-105, December.
    12. Nicola Laurieri & Andrea Lucchese & Antonella Marino & Salvatore Digiesi, 2020. "A Door-to-Door Waste Collection System Case Study: A Survey on its Sustainability and Effectiveness," Sustainability, MDPI, vol. 12(14), pages 1-23, July.
    13. Mao, Guozhu & Zou, Hongyang & Chen, Guanyi & Du, Huibin & Zuo, Jian, 2015. "Past, current and future of biomass energy research: A bibliometric analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1823-1833.
    14. Corina Pelau & Alexandra Catalina Chinie, 2018. "Econometric Model for Measuring the Impact of the Education Level of the Population on the Recycling Rate in a Circular Economy," The AMFITEATRU ECONOMIC journal, Academy of Economic Studies - Bucharest, Romania, vol. 20(48), pages 340-340.
    15. Hossam A. Gabbar & Muhammad Sajjad Ahmad, 2024. "Integrated Waste-to-Energy Process Optimization for Municipal Solid Waste," Energies, MDPI, vol. 17(2), pages 1-20, January.
    16. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    17. Halkos, George & Managi, Shunsuke, 2023. "New developments in the disciplines of environmental and resource economics," Economic Analysis and Policy, Elsevier, vol. 77(C), pages 513-522.
    18. Konrad Siegfried & Susann Günther & Sara Mengato & Fabian Riedel & Daniela Thrän, 2023. "Boosting Biowaste Valorisation—Do We Need an Accelerated Regional Implementation of the European Law for End-of-Waste?," Sustainability, MDPI, vol. 15(17), pages 1-13, September.
    19. López-González, D. & Puig-Gamero, M. & Acién, F.G. & García-Cuadra, F. & Valverde, J.L. & Sanchez-Silva, L., 2015. "Energetic, economic and environmental assessment of the pyrolysis and combustion of microalgae and their oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1752-1770.
    20. Fanta Barry & Marie Sawadogo & Maïmouna Bologo (Traoré) & Igor W. K. Ouédraogo & Thomas Dogot, 2021. "Key Barriers to the Adoption of Biomass Gasification in Burkina Faso," Sustainability, MDPI, vol. 13(13), pages 1-14, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:235:y:2024:i:c:s0960148124013879. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.