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Progress, prospect and challenges in glycerol purification process: A review

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  • Ardi, M.S.
  • Aroua, M.K.
  • Hashim, N. Awanis

Abstract

Glycerol surplus in recent decades due to global increase in biodiesel production has created a new form of challenge in terms of purification for crude glycerol. This review summarizes the progress of crude glycerol purification technologies using various techniques. Critical insights are given regarding the application of suitable techniques for crude glycerol purification which includes chemical pre-treatment, methanol removal, vacuum distillation, ion exchange, activated carbon and membrane separation technology. Extensive discussion is made in relation with stages and processes in the conventional, current and emerging glycerol purification technologies. Lastly, aspects concerning the challenges of glycerol utilization and purification are thoroughly discussed.

Suggested Citation

  • Ardi, M.S. & Aroua, M.K. & Hashim, N. Awanis, 2015. "Progress, prospect and challenges in glycerol purification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1164-1173.
    • Handle: RePEc:eee:rensus:v:42:y:2015:i:c:p:1164-1173
    DOI: 10.1016/j.rser.2014.10.091
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    2. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    3. Zhang, Ming & Xue, Wenfeng & Su, Baogen & Bao, Zongbi & Wen, Guangdong & Xing, Huabin & Ren, Qilong, 2017. "Conversion of glycerol into syngas by rotating DC arc plasma," Energy, Elsevier, vol. 123(C), pages 1-8.
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    5. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    6. Matheus Oliveira & Ana Ramos & Eliseu Monteiro & Abel Rouboa, 2022. "Improvement of the Crude Glycerol Purification Process Derived from Biodiesel Production Waste Sources through Computational Modeling," Sustainability, MDPI, vol. 14(3), pages 1-12, February.
    7. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    8. Zhao, Man & Wang, Yanan & Zhou, Wenting & Zhou, Wei & Gong, Zhiwei, 2023. "Co-valorization of crude glycerol and low-cost substrates via oleaginous yeasts to micro-biodiesel: Status and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
    9. Bumbac, Gheorghe & Banu, Ionut, 2022. "Modeling and simulation process for solketal synthesis from glycerol and acetone by catalytic distillation in a modified structure of a divided wall column," Renewable Energy, Elsevier, vol. 183(C), pages 662-675.
    10. Abel Rodrigues & João Carlos Bordado & Rui Galhano dos Santos, 2017. "Upgrading the Glycerol from Biodiesel Production as a Source of Energy Carriers and Chemicals—A Technological Review for Three Chemical Pathways," Energies, MDPI, vol. 10(11), pages 1-36, November.
    11. Jindapon, Wayu & Ruengyoo, Supapan & Kuchonthara, Prapan & Ngamcharussrivichai, Chawalit & Vitidsant, Tharapong, 2020. "Continuous production of fatty acid methyl esters and high-purity glycerol over a dolomite-derived extrudate catalyst in a countercurrent-flow trickle-bed reactor," Renewable Energy, Elsevier, vol. 157(C), pages 626-636.
    12. Makarevičienė, Violeta & Kazancev, Kiril & Sendžikienė, Eglė & Gumbytė, Milda, 2024. "Application of simultaneous rapeseed oil extraction and interesterification with methyl formate using enzymatic catalyst," Renewable Energy, Elsevier, vol. 227(C).

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