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Glycerin, a Biodiesel By-Product with Potentiality to Produce Hydrogen by Steam Gasification

Author

Listed:
  • Silvia Román Suero

    (Department of Applied Physics, University of Extremadura, Avda. Elvas s/n, Badajoz 06006, Spain)

  • Beatriz Ledesma

    (Department of Applied Physics, University of Extremadura, Avda. Elvas s/n, Badajoz 06006, Spain)

  • Andrés Álvarez-Murillo

    (Department of Applied Physics, University of Extremadura, Avda. Elvas s/n, Badajoz 06006, Spain)

  • Awf Al-Kassir

    (Department of Mechanical, Energy and Materials Engineering, University of Extremadura, Avda. Elvas s/n, Badajoz 06006, Spain)

  • Talal Yusaf

    (National Centre for Engineering in Agriculture, University of Southern Queensland, Brisbane, QLD 4350, Australia)

Abstract

This work investigates the possibility of providing a use to one of the major byproducts generated during biodiesel processing: glycerin. In particular, the steam gasification of water/glycerin mixtures is studied, analysing the influence of temperature (range 600–900 °C), inlet flow rate (0.5–3 mL·min − 1 ) and water/glycerin ratio (6–12 wt/wt, %) on the gas composition (H 2 , CO, CH 4 and CO 2 ), higher heating value, and generated power. In general, a more diluted water/glycerin mixture is more interesting in order to provide a higher fraction of hydrogen in the gas produced, although it also involves a decrease in the power obtained. Higher temperatures cause a greater contribution of water gas and water gas shift reactions in all cases, thus increasing the H 2 proportion of the gas. Finally, a greater inlet flow rate increases gas production, but decreases the hydrogen proportion.

Suggested Citation

  • Silvia Román Suero & Beatriz Ledesma & Andrés Álvarez-Murillo & Awf Al-Kassir & Talal Yusaf, 2015. "Glycerin, a Biodiesel By-Product with Potentiality to Produce Hydrogen by Steam Gasification," Energies, MDPI, vol. 8(11), pages 1-11, November.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:11:p:12339-12775:d:58627
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    References listed on IDEAS

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    1. Adhikari, Sushil & Fernando, Sandun D. & Haryanto, Agus, 2008. "Hydrogen production from glycerin by steam reforming over nickel catalysts," Renewable Energy, Elsevier, vol. 33(5), pages 1097-1100.
    2. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2015. "Hydrogen production from supercritical water reforming of glycerol over Ni/Al2O3–SiO2 catalyst," Energy, Elsevier, vol. 84(C), pages 634-642.
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    4. Cao, Leichang & Zhang, Shicheng, 2015. "Production and characterization of biodiesel derived from Hodgsonia macrocarpa seed oil," Applied Energy, Elsevier, vol. 146(C), pages 135-140.
    5. Srivastava, Anjana & Prasad, Ram, 2000. "Triglycerides-based diesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(2), pages 111-133, June.
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    Cited by:

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    2. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.

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